An apparatus for attachment to a tailpipe of a vehicle is disclosed herein. The apparatus includes a filter body, a honeycomb monolith, a locking collar and a removable front cover. The honeycomb monolith is composed of an adsorbent material or an absorbent material. Exhaust from the tailpipe of the vehicle is absorbed by the honeycomb monolith structure.

The present invention relates yolk-shell nanoparticles having both a high stability towards sintering and high H.sub.25 adsorption capacities, the use of the yolk-shell nanoparticles in a method for H.sub.2S removal from gas streams, and a corresponding method for H.sub.2S removal from gas streams also comprising the regeneration of the yolk-shell nanoparticles, wherein the yolk-shell nanoparticles provide for high H.sub.2 adsorption capacities and/or high reusability.

The present invention relates to an adsorbent comprising an alumina support and at least one alkali element, said adsorbent being obtained by introducing at least one alkali element, identical to or different from sodium, onto an alumina support the sodium content of which, expressed as Na.sub.2O equivalent, before the introduction of the alkali element or elements, is comprised between 1000 and 5000 ppm by weight with respect to the total weight of the support. The invention also relates to processes for the preparation of said adsorbent and use thereof in a process for the elimination of acidic molecules such as COS and/or CO.sub.2.

A novel adsorbent and contactor material based on polymer functionalized with amidoxime and alkylamines moieties. Methods of making the material are also described. The material can be easily processed into any desired sorbent geometry such as solid fibers, electrospun fibers, hollow fibers, monoliths, etc. The adsorbent exhibits a very high affinity toward acidic gases such CO.sub.2 and can be used in direct air capture, power plant-based CO.sub.2 capture, and industrial CO.sub.2 capture applications. The material can also serve as a contactor that accommodates other adsorbents within its structure.

The present invention relates to an intensified 5-bed and 6-bed PSA process cycles features, as well as fast rate adsorbents that enable the intensified PSA system to meet cost and performance target are identified. The proposed capital efficient H.sub.2PSA system offers opportunity to reduce PSA capital expenditure by ten percent (10%).

A sorbent composition for the sequestration of mercury from a gas stream, a method for sequestering mercury from a gas stream and a method for the manufacture of a sorbent composition. The sorbent composition includes a highly porous particulate sorbent and at least two additive components, namely a non-halogen metal compound comprising a metal cation and an inorganic sulfur-containing compound, where at least a portion of the sulfur in the sulfur-containing compound has an oxidation state of equal to or less than +4. The method includes injecting the highly porous particulate sorbent and the two additive components into a gas stream, either discretely or as a single sorbent composition, to sequester mercury in the particulate sorbent. The method has a high degree of efficacy for mercury removal without requiring the addition of halogens to the gas stream.

Zinc oxide-based sorbents, and processes for preparing and using them are provided, wherein the sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents contain an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two-phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl.sub.2O.sub.4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 50 nm (500 Angstroms). Preferably the sorbents are prepared by using an alkali metal base to convert a precursor mixture, containing a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component, with the resulting sorbent having a sodium level within a desired range.

A sorbent composition for the sequestration of mercury from a gas stream, a method for sequestering mercury from a gas stream and a method for the manufacture of a sorbent composition. The sorbent composition includes a highly porous particulate sorbent and at least two additive components, namely a non-halogen metal compound comprising a metal cation and an inorganic sulfur-containing compound, where at least a portion of the sulfur in the sulfur-containing compound has an oxidation state of equal to or less than +4. The method includes injecting the highly porous particulate sorbent and the two additive components into a gas stream, either discretely or as a single sorbent composition, to sequester mercury in the particulate sorbent. The method has a high degree of efficacy for mercury removal without requiring the addition of halogens to the gas stream.

An aminated siliceous adsorbent, which is the reaction product of dried acidified rice husk ash having disordered mesopores and an amino silane, wherein amine functional groups are present on an external surface and within the mesopores of the dried acidified rice husk ash, and wherein the aminated siliceous adsorbent has a carbon content of 24 to 30 wt. %, based on a total weight of the aminated siliceous adsorbent. A method of making the aminated siliceous adsorbent and a method of capturing CO.sub.2 from a gas mixture with the aminated siliceous adsorbent.

Described are storage and dispensing systems, and related methods, for storing and selectively dispensing high purity reagent gas from a storage vessel in which the reagent gas is held in sorptive relationship to pyrolyzed carbon adsorption particles.