Patent classifications
B01D2253/308
Method to provide pipeline quality natural gas
The present invention relates to a method of separating and recovering NGLs from a natural gas feedstream. Specifically, the present method allows for the separation of ethane and heavier hydrocarbons and/or propane and heavier hydrocarbons from a raw natural gas feedstream to provide pipeline quality natural gas. One embodiment of this method provides for the use of a regenerable adsorbent media which is regenerated by a microwave heating system. Said regeneration step may be operated as a batch process, a semi-continuous process, or a continuous process.
Composite material, its manufacture and use in gas purification
The invention provides a composite material formed from an inorganic mesoporous, or mesoporous-like, material that is dispersed throughout a polymeric matrix formed by a crosslinked polymer that has acidic- or basic-residues and which may also optionally have further acidic- or basic-residues grafted onto the inorganic mesoporous material. The resulting composite material may be used to remove acidic or basic impurities from a gas in need thereof and can be easily regenerated.
OLEFIN POLYMERIZATION CATALYST SYSTEM COMPRISING MESOPOROUS ORGANOSILICA SUPPORT
A catalyst system comprising a combination of: 1) one or more catalyst compounds comprising at least one nitrogen linkage; 2) a support comprising an organosilica material, which is a mesoporous organosilica material; and 3) an optional activator. Useful catalysts include pyridyldiamido transition metal complexes, HN5 compounds, and bis(imino)pyridyl complexes. The organosilica material is a polymer of at least one monomer of Formula [Z.sup.1OZ.sup.2SiCH.sub.2].sub.3(1), where Z.sup.1 represents a hydrogen atom, a C.sub.1-C.sub.4alkyl group, or a bond to a silicon atom of another monomer and Z.sup.2 represents a hydroxyl group, a C1-C.sub.4alkoxy group, a C.sub.1-C.sub.6 alkyl group, or an oxygen atom bonded to a silicon atom of another monomer. This invention further relates to processes to polymerize olefins comprising contacting one or more olefins with the above catalyst system.
Catalytic adsorbents obtained from municipal sludges, industrial sludges, compost and tobacco waste and process for their production
Industrial waste derived adsorbents were obtained by pyrolysis of sewage sludge, metal sludge, waste oil sludge and tobacco waste in some combination. The materials were used as media to remove hydrogen sulfide at room temperature in the presence of moisture. The initial and exhausted adsorbents after the breakthrough tests were characterized using sorption of nitrogen, thermal analysis, XRD, ICP, and surface pH measurements. Mixing tobacco and sludges result in a strong synergy enhancing the catalytic properties of adsorbents. During pyrolysis new mineral phases are formed as a result of solid state reaction between the components of the sludges. High temperature of pyrolysis is beneficial for the adsorbents due to the enhanced activation of carbonaceous phase and chemical stabilization of inorganic phase. Samples obtained at low temperature are sensitive to water, which deactivates their catalytic centers.
Gas purification filter unit
This gas purification filter unit (10) is provided with: a first elimination unit (11) that eliminates gas component impurities among the impurities contained in ozone generated from an ozone generating device; and a second elimination unit (12) that is disposed at a later stage than the first elimination unit and that further eliminates solid particulate impurities from among the impurities from which the gas component has been eliminated. Ozone containing impurities are caused to flow in from the inflow end (10a) of such a gas purification filter unit (10) and is passed through the first elimination unit (11) and second elimination unit (12), and thus ozone from which impurities have been eliminated is discharged from an outflow end (10b).
MULTICAPILLARY PACKING CHROMATOGRAPHY METHOD
Chromatography method in which a gaseous, liquid or supercritical mobile phase containing species to be separated is circulated through a packing, said packing being characterized in that: it comprises a plurality of capillary ducts extending in the packing between an upstream face through which the mobile phase enters the packing and a downstream face through which the mobile phase leaves the packing—the material of the walls comprises a first population of connected pores, providing passages from one duct to the next enabling molecular diffusion to take place between adjacent ducts, pores having a mean diameter (d.sub.pore) of greater than 2 times the molecular diameter of at least one species to be separated—the diameter of the ducts is less than 50 μm.
ADSORBENT, CANISTER, AND METHOD FOR PRODUCING ADSORBENT
An object of the present invention is to provide an adsorbent and a canister which can improve adsorption performance and purge performance. An adsorbent 10 to be packed in a canister includes: a cylindrical outer wall 10A, and a plurality of ribs 10B for partitioning along an axis of the outer wall 10A into a plurality of cells, wherein the thickness da of the outer wall 10A and the thickness dβ of the ribs 10B is less than 0.6 mm, the thickness of at least either of the outer wall 10A and the ribs 10B exceeds 0.4 mm, the outer diameter D of the outer wall 10A is 3.5 mm or more and 40 mm or less, a BWC exceeds 3.0 g/dL, and
purge efficiency((amount of butane adsorbed−amount of butane retained)/amount of butane adsorbed) is more than 0.86 or more.
Mixtures for the adsorption of acidic gases
The invention relates to mixtures containing basic anion exchangers and flow regulators, the use thereof for the adsorption of acidic gases and of carbon dioxide in particular, a process for continuous gas adsorption, and heat exchangers that contain the mixtures containing basic anion exchangers and flow regulators.
HYDROCARBON REMOVAL SYSTEM
A hydrocarbon removal system according an embodiment of the present invention includes: a first area including a first hydrocarbon adsorption catalyst having a first pore size; and a second area including a second hydrocarbon adsorption catalyst having a second pore size, wherein the first pore size may be smaller than the second pore size, the first hydrocarbon adsorption catalyst may include CHA zeolite, and the second hydrocarbon adsorption catalyst may include ZSM-5 zeolite.
GAS TREATMENT METHOD AND GAS TREATMENT DEVICE
Provided are a gas treatment method and a gas treatment device capable of efficiently removing a bromofluoroethylene. A gas containing a bromofluoroethylene is brought into contact with an adsorbent (7) having pores with an average pore diameter of 0.4 nm or more and 4 nm or less in a temperature environment of not less than 0° C. and less than 120° C. to allow the adsorbent (7) to adsorb the bromofluoroethylene, and thus the bromofluoroethylene is separated from the gas.