Disclosed is an exhaust gas purification catalyst carrier which includes a phosphate salt represented by formula: MPO.sub.4 (wherein M represents Y, La, or Al) or a zirconium phosphate represented by formula ZrP.sub.2O.sub.7; an exhaust gas purification catalyst containing a noble metal at least containing Rh and supported on the carrier; and an exhaust gas purification catalyst product having a catalyst support made of a ceramic or metallic material, and a layer of the exhaust gas purification catalyst, the layer being supported on the catalyst support.

The present invention relates to a selective catalytic reduction catalyst for the treatment of an exhaust gas of a combustion engine, the catalyst comprising a substrate comprising an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end and a plurality of passages defined by internal walls of the substrate extending therethrough; a coating disposed on the substrate (i), the coating comprising a first non-zeolitic oxidic material comprising aluminum, an 8-membered ring pore zeolitic material comprising one or more of copper and iron, and a second non-zeolitic oxidic material comprising cerium and one or more of zirconium, aluminum, silicon, lanthanum, niobium, iron, manganese, titanium, tungsten, copper, molybdenum, neodymium, cobalt, chromium, tin and praseodymium; wherein at least 65 weight-% of the coating consist of the 8-membered ring pore zeolitic material comprising one or more of copper and iron.

The disclosure provides a system and a method for reducing hazardous gases, including PHGs, through one or more photocatalysts in a filter system. A microstructure of the photocatalytic filter can be formed using biological systems as a template for the photocatalysts to be deposited thereon. The biological system can be removed by heat, oxidation, or by chemical processes to leave the photocatalytic template as a filter for the gases. In various embodiments, multiple photocatalysts can be activated at different wavelengths to filter different gases, or multiple photocatalysts can be activated at the same wavelength to filter different gases, or a photocatalyst can be activated at different wavelengths to filter different gases, or some combination thereof. The activation can be sequential or concurrent. For multiple layers of photocatalysts, the sequence of the photocatalysts can be arranged to reduce damaging output from an upstream photocatalyst to one or more downstream photocatalysts.

A catalyst for decomposing perfluorinated compounds includes an alumina carrier, at least one metal carried on the alumina carrier and selected from the group consisting of Zn, Ni, W, Zr, Ti, Ga, Nb, Co, Mo, V, Cr, Mn, Fe, and Cu, S carried on the alumina carrier, and rare-earth metals carried on the alumina carrier.

Synergized platinum group metals (SPGM) with ultra-low PGM loadings employed as close-coupled (CC) three-way catalysts (TWC) systems with varied material compositions and configurations are disclosed. SPGM CC catalysts in which ZPGM compositions of binary or ternary spinel structures supported onto support oxides are coupled with commercialized PGM UF catalysts and tested under Federal Test Procedure FTP-75 within TGDI and PI engines. The performance of the TWC systems including SPGM CC (with ultra-low PGM loadings) catalyst and commercialized PGM UF catalyst is compared to the performance of commercialized PGM CC and PGM UF catalysts. The disclosed TWC systems indicate that SPGM CC TWC catalytic performance is comparable or even exceeds high PGM-based conventional TWC catalysts, with reduced tailpipe emissions.

A lean gasoline exhaust treatment catalyst article is provided, the article comprising a catalytic material applied on a substrate, wherein the catalytic material comprises a first composition and a second composition, wherein the first and second compositions are present in a layered or zoned configuration, the first composition comprising palladium impregnated onto a porous refractory metal oxide material and rhodium impregnated onto a porous refractory metal oxide material; and the second composition comprising platinum impregnated onto a porous refractory metal oxide material. Methods of making and using such catalyst articles and the associated compositions and systems employing such catalyst articles are also described.

A composition for exhaust gas purification including first alumina including alumina containing lanthanum and second alumina including alumina containing lanthanum. The first alumina has a higher lanthanum content than the second alumina. The second alumina has a larger particle size than the first alumina. The lanthanum content of the first alumina is preferably 2 to 12 mass %, in terms of oxide, based on the total mass of alumina and lanthanum oxide of the first alumina. The lanthanum content of the second alumina is preferably 9 mass % or less, in terms of oxide, based on the total mass of alumina and lanthanum oxide of the second alumina.

Phosphorus tolerant or resistant three-way catalysts (TWC) are disclosed. The TWC may include a substrate defining a plurality of channels. It may include front and rear washcoat portions overlying the substrate and having respective first and second washcoat loadings, the first washcoat loading being at most 2.0 g/in.sup.3 and less than the second washcoat loading. The front washcoat portion may include a catalyst material supported on a support material comprising a cerium oxide, such as ceria or CZO, or a pre-phosphated material, such as AlPO.sub.4, or CePO.sub.4. In one embodiment, the support material may comprise at least 85 wt. % of a cerium oxide or at least 85 wt. % of a phosphate-containing material. The front portion and the underlying substrate may comprise from 3 to 25 vol. % of the three-way catalyst or the front portion may overly up to an initial 15% of an axial length of the substrate.

A noble metal-free lanthanum transition metal perovskite catalyst material. The noble metal-free lanthanum transition metal perovskite catalyst material may include a two phase mixture of a lanthanum transition metal perovskite with an alkali or alkaline earth metal carbonate, a lanthanum transition metal perovskite doped with an alkali or alkaline earth metal, or a combination thereof. The lanthanum transition metal perovskite catalyst material provides direct decomposition of NOx into N.sub.2 and O.sub.2 without the presence of a noble metal and in the presence of excess O.sub.2.

Catalyst compositions, articles, systems and methods related to a three-way-catalyst composition comprising alumina doped with a transition metal.