A catalyst article including a substrate with an inlet side and an outlet side, a first zone and a second zone, where the first zone includes an ammonia slip catalyst (ASC) comprising a platinum group metal on a support and a first SCR catalyst; where the second zone includes a catalyst selected from the group consisting of a diesel oxidation catalyst (DOC) and a diesel exotherm catalyst (DEC); and where the first zone is located upstream of the second zone. The first zone may include a bottom layer with a blend of: (1) the platinum group metal on a support and (2) the first SCR catalyst; and a top layer comprising a second SCR catalyst, the top layer located over the bottom layer.

Provided are catalyst articles, methods of manufacturing catalyst articles, and methods for controlling emissions in diesel engine exhaust streams with catalyst articles, where the emission treatment system of various embodiments effectively treats diesel engine exhaust with a catalyst article. In one or more embodiments, the catalyst articles have a platinum group metal end coating covering an outlet end surface of the catalytic article. In one or more embodiments, a method is provided where an applicator transfers a platinum group metal coating to an outlet end face of a catalytic article.

Methods and systems are featured for reducing harmful exhaust gas components of combustion devices such as gasoline-powered combustion engines (e.g., predominately stoichiometric running engines). The methods and systems include an underbody combination of a hydrocarbon trap (HCT), suited for cold start hydrocarbon adsorption, as well as an associated NOx trap. The system is inclusive of a control unit for extending a lean exhaust condition reaching the desorbing HCT as to avoid a deficiency in oxygen during the time period of HCT desorption. The system is also inclusive of one or more TWCs as in one associated with the underbody HCT-NOx-trap combination and/or one positioned in a close coupled position. Platinum group metals as in Pd, Rh and Pt are also featured on one, two or all three of the HCT, NOx-trap, and TWC when present.

The invention relates to a diesel oxidation catalyst which has a support body with a length L extending between a first end face a and a second end face b and catalytically active material zones A, B, and C arranged on the support body, whereinmaterial zone A contains palladium or platinum and palladium in a weight ratio of Pt:Pd of 1 and an alkaline earth metal and extends over 20 to 80% of the length L starting from the end face a, material zone B contains ceroxide, is free of platinum, and extends over 20 to 80% of the length L starting from the end face b, material zone C contains platinum or platinum and palladium in a weight ratio of Pt:Pd of 5, and neither material zone A nor material zone C is arranged over material zone B.

An automotive catalytic converter includes a three-way catalyst having Rh as the only precious metal configured as a front zone and a three-way catalyst having a mixture of Rh and Pd, Pt, or both configured as a rear zone, such that an exhaust gas from an internal combustion engine passes through the front zone before passing through the rear zone to minimize sulfur poisoning of the catalytic converter.

The present invention relates to a honeycomb catalytic converter, including: a honeycomb structured body in which multiple through-holes are arranged longitudinally in parallel with one another with a partition wall therebetween; and Pd and Rh supported on the partition walls of the honeycomb structured body, wherein the honeycomb structured body is an extrudate containing a ceria-zirconia complex oxide and alumina, a Pd-carrying region where only Pd is supported is formed on the partition walls within a predetermined width from one end of the honeycomb structured body, and a Rh-carrying region where only Rh is supported is formed on the partition walls within a predetermined width from the other end of the honeycomb structured body, and the Pd-carrying region extends to at least 50% of the length of the honeycomb structured body, and the Rh-carrying region extends to at least 20% of the length of the honeycomb structured body.

A catalytic article for treating an exhaust gas stream containing particulate matter, hydrocarbons, CO, and ammonia, the article may include: (a) a substrate having an inlet end and an outlet end defining an axial length; (b) a first catalyst coating including: 1) a platinum group metal distributed on a molecular sieve, and 2) a base metal distributed on a molecular sieve; and (c) a second catalyst coating including: 1) a platinum group metal distributed on a molecular sieve, and 2) a base metal distributed on a molecular sieve.

The present invention provides exhaust gas purification catalyst for an internal combustion engine, and exhaust gas purification method using the catalyst. The present invention provides the exhaust gas purification catalyst including a support, a first catalyst layer on an upstream side, a second catalyst layer on a downstream side, and a third catalyst layer. In the exhaust gas purification catalyst, the upstream portion of the third catalyst layer is present on the first catalyst layer, the downstream portion of the third catalyst layer is present on the second catalyst layer, and in the middle portion between the upstream portion and the downstream portion of the third catalyst layer is present between the first catalyst layer and the second catalyst layer.

An exhaust gas purification catalyst having a substrate having a wall flow structure, and a catalyst layer. The catalyst layer has: an A section provided in the interior of the partition wall, along an extension direction X of the partition wall, from an exhaust gas inflow end section; a C section provided in the interior of the partition wall, along the extension direction X of the partition wall, from an exhaust gas outflow end section; and a B section disposed between the A section and the C section in the extension direction X of the partition wall, and provided over the surface of the partition wall on the side in contact with the inlet cell, the interior of the partition wall, and the surface of the partition wall on the side in contact with the outlet cell.

A catalyst composition for treating an exhaust gas, the catalyst composition comprising a molecular sieve, the molecular sieve comprising exchanged copper and exchanged manganese.