Systems, apparatuses, and processes for controlling free ammonia in wet flue gas desulfurization processes in which an ammonia-containing scrubbing solution is used to produce ammonium sulfate. Such an apparatus includes an absorber having a contactor region through which a flue gas comprising sulfur dioxide is able to flow and a reaction tank containing a scrubbing solution containing ammonium sulfate. The tank has a sidewall and bottom wall that define the perimeter and bottom of the tank. Lance-agitator units are distributed around the perimeter of the tank, each having a lance that injects a mixture of oxygen and a dilute ammonia-containing fluid toward the bottom of the tank and an agitator that agitates the mixture and propels the mixture toward the bottom of the tank. The apparatus includes a source of the mixture of oxygen and dilute ammonia-containing fluid, and recirculates the scrubbing solution from the tank to the contactor region.

An improved process for deacidizing a gaseous mixture with reduced overall energy costs is described. The process involves contacting the gaseous mixture with at least one of a vaporizing compound, a vaporized compound, a vaporizing solution of compound and a vaporized solution of compound, and forming a liquid or solid reaction product that can be easily separated from the gaseous mixture.

Disclosed is a process for treating a gas stream containing hydrochloric acid, hydrofluoric acid, a fluorinated compound and halogenated organic compounds, wherein the gas stream is subjected to: (a) a step of washing with an acid solution to obtain a washed gas stream; (b) a step of adiabatic absorption in an aqueous solution of the hydrochloric acid contained in said washed gas stream, to collect a solution of hydrochloric acid; (c) a step of adsorption on activated carbon of the impurities present in said hydrochloric acid solution, to obtain a purified hydrochloric acid solution and a gas stream containing said fluorinated compound; and (d) a step of bringing said purified hydrochloric acid solution into contact with a silica gel. Also disclosed is a plant for the implementation of this process, and also a process for preparing a fluorinated compound comprising the catalytic pyrolysis of an organofluorine compound.

An agent for removing a halogen gas, such as chlorine, in a waste gas by means of reduction; a method for producing this agent; a method for removing a halogen gas by use of this agent; and a system for removing a halogen gas. The agent for removing the halogen gas contains at least pseudo-boehmite, that serves as a host material, and a sulfur-containing reducing agent, that serves as a guest material. 1-8% by weight of the reducing agent, in terms of elemental sulfur, based on the total amount of the pseudo-boehmite and sulfur-containing reducing agent is present in the agent. At least one inorganic compound selected from among oxides, carbonates salts and hydrocarbon salts of alkaline earth metal elements, transition metal elements and zinc group elements is additionally contained in the agent as a third component.

The invention relates to a method for increasing the absorbency of a material containing alkaline-earth carbonate and alkaline-earth hydroxide with regard to sulfur oxides and/or other pollutants, in particular in flue gas, wherein the material containing alkaline-earth carbonate and alkaline-earth hydroxide is activated by heating said material to approximately 250 C. to approximately 750 C. for a time period of 1 minute to 12 hours.

A process and a device for treating a flow of furnace gas with a pressure of more than 1 bar flowing through a channel. A powder agent, such as a powder comprising alkali reagents, such as lime, and/or absorbents, such as activated coal, is injected under an overpressure into the furnace gas flow via an injector which is positioned centrally within the channel. The powder agent may be fluidized. The pressure for injecting the powder may be adjusted by controlling the volume of fluidization gas vented via a venting outlet.

Systems and methods for reducing the capital and operating costs of a smelting process system and improving the environmental impact of the smelting process using an IGT system to remove and filter undesirable and environmentally hazardous gases and particulates from each electrolytic cell in the smelting process system.

The present invention removes, by a preprocessing unit, harmful chemical materials and radioactive materials supplied to a positive pressure chamber and a negative pressure chamber and supplies same, removes contaminants discharged to the outside from the negative pressure chamber and sterilizes bacteria and floating viruses and discharges same, and adjusts, by a control circuit of a control panel, the rotating speed (RPM) of an air supply/discharge fan and adjusts the opening rate of an electric damper according to data that is measured in a pressure sensor provided in a space in which the positive pressure and the negative pressure are to be maintained and is transmitted in real time.

Technologies for combusting hazardous compounds such as chemical warfare agents and related compounds are disclosed. In embodiments, the technologies include systems and methods for combusting such compounds in an internal combustion engine, such as a spark ignition internal combustion engine, a diesel engine, or the like. The technologies described herein further include components for treating an exhaust gas stream produced by combustion of hazardous compounds. In embodiments such components include a scrubber that utilizes a scrubbing media such as soil to removing acid gases from the exhaust stream.

The present disclosure provides separation processes for removing heavy organics that are formed in various production processes of HCFO-1233zd(E). Such separation processes allow for the recovery and/or separation of the heavy organics from reactants that are used to form HCFO-1233zd(E), including HF. Such separation or recovery processes may utilize various separation techniques (e.g., decanting, liquid-liquid separation, distillation, and flash distillation) and may also utilize the unique properties of azeotropic or azeotrope-like compositions. Recovery of the heavy organic that is substantially free from HF may allow for their use in subsequent manufacture processes or disposal.