A polymer/activated carbon composite made up of a branched polyethylenimine and magnetic cores involving Fe.sub.3O.sub.4 disposed activated carbon. The magnetic cores have activated carbonyl groups on the surface. A process for removing organic dyes, such as methyl red, as well as heavy metal ions from a polluted aqueous solution or an industrial wastewater utilizing the composite is introduced. A method of synthesizing the polymer/activated carbon composites is also specified.

A polymer/activated carbon composite made up of a branched polyethylenimine and magnetic cores involving Fe.sub.3O.sub.4 disposed activated carbon. The magnetic cores have activated carbonyl groups on the surface. A process for removing organic dyes, such as methyl red, as well as heavy metal ions from a polluted aqueous solution or an industrial wastewater utilizing the composite is introduced. A method of synthesizing the polymer/activated carbon composites is also specified.

The present disclosure relates to water purification compositions and the method of producing the same. Specifically, the present disclosure relates to a method of producing a water purification composition including providing a substrate having one or more functional groups that has hydroxyl, thiol, carboxyl, and/or amino group; depositing a solution of a metal salt on the substrate; depositing a solution of carboxylic acid compound on the substrate; forming a mixture wherein the metal cross-links the hydroxyl, thiol, carboxyl and/or amino groups on the surface of the substrate, and the carboxylic acid compound; and heating the mixture till the product is dry.

The invention discloses a core-shell structure polymer magnetic nanosphere with a high Cr (VI) adsorption capacity and its preparation method and application. The preparation method includes: adding Fe.sub.3O.sub.4 powder into a mixed solution of water and ethanol, dispersing Fe.sub.3O.sub.4 powder in the solution evenly by ultrasound, sequentially adding resorcinol and formaldehyde into the suspension to adjust a pH, stirring and reacting to obtain Fe.sub.3O.sub.4@RF evenly dispersed in a chitosan solution, dropwise adding the prepared suspension into a mixed solution of paraffin and span 80, stirring for a period of time, adding a glutaraldehyde aqueous solution, stirring and reacting to obtain a magnetic chitosan nanosphere. The magnetic chitosan nanosphere prepared may be applied to adsorbing Cr (VI) in a water solution. Not only the magnetic chitosan nanospheres prepared has a high adsorption capacity for Cr (VI), but also can be quickly separated by an external magnetic field after adsorption.

The method and materials of this invention make possible substantially faster techniques for organic-aqueous extractions and routine chemical reactions work-ups. The inventive material uses silicone elastomer-coated glass powders, magnetic powders, and sponges as absorbents to extract organic products from an aqueous mixture. After separation from the mixture, these different forms now loaded with organic products can serve as a convenient input for flash chromatographic separations or other processing. With these techniques, tedious liquid-liquid extractions are replaced by a simple solid filtration or transfer and emulsion formation is eliminated. These versatile sorbents can also be used for larger scale work-ups, various extractions of organics from an aqueous solution (e.g., water purification) or gas phase and various analytical or other applications.

Biogenic activated carbon compositions disclosed herein comprise at least 55 wt % carbon, some of which may be present as graphene, and have high surface areas, such as Iodine Numbers of greater than 2000. Some embodiments provide biogenic activated carbon that is responsive to a magnetic field. A continuous process for producing biogenic activated carbon comprises countercurrently contacting, by mechanical means, a feedstock with a vapor stream comprising an activation agent including water and/or carbon dioxide; removing vapor from the reaction zone; recycling at least some of the separated vapor stream, or a thermally treated form thereof, to an inlet of the reaction zone(s) and/or to the feedstock; and recovering solids from the reaction zone(s) as biogenic activated carbon. Methods of using the biogenic activated carbon are disclosed.

A carrier for adsorption a compound, comprising a support; and a shrink-fitted monolithic body attached to and surrounding at least a portion of the support. The monolithic body can be porous and configured to bind compounds in a solution either for the isolation or depletion of the compounds from the solution.

Multi-functional materials for use in reversible, high-capacity hydrogen separation and/or storage are described. Also described are systems incorporating the materials. The multi-functional materials combine a hydrogen-absorbing material with a high-efficiency and a non-contact energy-absorbing material in a composite nanoparticle. The non-contact energy-absorbing material include magnetic and/or plasmonic materials. The magnetic or plasmonic materials of the composite nanoparticles can provide localized heating to promote release of hydrogen from the hydrogen storage component of the composite nanoparticles.

A method and reactor are disclosed for separating and removing heavy metals from wastewater using a sulfhydryl-modified nano-magnetized activated carbon. The method includes the steps of preparing a sulfhydryl-modified nano-magnetized activated carbon first; introducing heavy-metal-containing wastewater into a reactor which is equipped with a stirrer and keeping stirring, and then adding the sulfhydryl-modified nano-magnetized activated carbon, continuously stirring for a reaction; after reacting for a period, precipitating under a magnetic field generated by a magnet separator, discharging the resulting supernate, and then discharging the precipitated sludge.

Coated iron oxide (10) nanocrystal structures, superparamagnetic 10 nanoparticles, methods for synthesizing coated 10 nanocrystal structures, and methods for synthesizing superparamagnetic 10 nanoparticles are described herein. A coated 10 nanocrystal structure may comprise an iron oxide core, a manganese ferrite shell layer surrounding the core, and a bilayer coating surrounding the shell layer. The bilayer coating may include an inner oleic acid layer surrounding the shell layer and an outer layer surrounding the inner oleic acid layer.