A stationary phase for solid-phase microextraction (SPME) devices is based on nickel and titanium alloy nuclei and a metal-organic framework (MOF) exterior, which may be used for chromatographic analysis in environmental, food, etc. applications. The method of preparation of the stationary phases includes a number of steps which provide a covalent adhesion of the MOF to the nickel/titanium alloy. In these stationary phases, the metal-organic framework is the only component that comes into contact with the sample to be analysed. The interior of the stationary phase is executed in nitinol and endows the system with thermal and mechanical stability this being the first time that it is used to support a metal-organic framework, and presenting extractive advantages in comparison with commercial SPME stationary phases.

A filtration material including a silica base material having a group represented by the following general formula (a0-1) [in formula (a0-1), Ya.sup.01 represents a divalent linking group; Ra.sup.01 represents a hydrocarbon group which may have a substituent; Ra.sup.02 represents a hydroxyl group or a hydrocarbon group having 1 to 6 carbon atoms which may have a substituent; n.sup.01 represents an integer of 0 to 5; and the symbol “*” represents a valence bond with respect to the silica base material].

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[OBJECT] To provide an activated carbon for adsorbing per- and polyfluoroalkyl compounds in a water sample, the activated carbon having a high collection rate of per- and polyfluoroalkyl compounds in a water sample, and a filter body using the same.

[ACHIEVING MEANS] An activated carbon for adsorbing per- and polyfluoroalkyl compounds in a water sample to desorbably adsorb per- and polyfluoroalkyl compounds in a water sample, wherein the activated carbon is composed of an activated carbon adsorbent having a BET specific surface area of 800 m.sup.2/g or more or a surface oxide amount of 0.20 meq/g or less, or alternatively, a BET specific surface area of 800 m.sup.2/g or more and a surface oxide amount of 0.50 meq/g or less, and wherein a sum (V.sub.mic) of a volume of micropores of 1 nm or less of the activated carbon adsorbent is 0.30 cm.sup.3/g or more.

An aggregate includes a polymeric foam present in a range of about 80 vol % to about 85 vol % of the aggregate. A cementitious matrix is present in a range of about 10 vol % to about 13 vol % of the aggregate. One or more resins are present in an amount of less than about 2 vol % of the aggregate, and one or more reinforcing fibers are present in an amount of less than about 1 vol % of the aggregate.

A fiber useful in the absorption of metal ions from aqueous solutions, the fiber comprising a polyolefin backbone having a diameter of at least 1 micron and having covalently appended on its surface halogen atoms and vinyl-addition polymeric grafts functionalized with metal-binding groups, such as at least one functional group selected from carboxylate, keto, aldo, amino, imino, nitrile, amido, oxime, amidoxime, imide dioxime, and hydroxamate groups. The vinyl-addition polymeric grafts may also be further functionalized with hydrophilic groups different from the metal-binding groups, wherein the hydrophilic groups may be selected from carboxylate, sulfone, sulfonate, phosphonate, alkylammonium, iminium, amide, pyrrolidone, and polyalkyleneglycol groups. Also described are methods for producing the functionalized fibers, and methods for using the functionalized fiber, particularly in extracting metal ions from metal-containing solutions.

A gas separation unit for the separation of carbon dioxide from air is proposed for use in a cyclic adsorption/desorption process and using a loose particulate sorbent material. Sorbent material is arranged in at least two stacked layers, and each layer comprises two sheets of a flexible fabric material which is gas permeable but impermeable to the loose sorbent material. The sheets are arranged parallel defining an inlet face and an outlet face, are arranged with a distance in the range of 0.5-2.5 cm, and are enclosing a cavity in which the sorbent material is located. Said layers are arranged in the unit such that the inflow passes through the inlet face, subsequently through the particular sorbent material located in the cavity of the respective layer, subsequently to exit the layer through the outlet face to form the gas outflow.

Adsorptive media for chromatography, particularly ion-exchange chromatography, derived from a shaped fiber. In certain embodiments, the functionalized shaped fiber presents a fibrillated or ridged structure which greatly increases the surface area of the fibers when compared to ordinary fibers. Also disclosed herein is a method to add surface pendant functional groups that provides cation-exchange or anion-exchange functionality to the high surface area fibers. This pendant functionality is useful for the ion-exchange chromatographic purification of biomolecules, such as monoclonal antibodies (mAbs).

Provided is a dehumidification system including an air directing device and an adsorbent hollow fiber module. The air directing device is used for conveying air. The adsorbent hollow fiber module can adsorb the moisture in the air as the air passes through the adsorbent hollow fiber module. The adsorbent hollow fiber module includes at least one adsorbent hollow fiber. The adsorbent hollow fiber has a tubular body having a first end and a second end and a channel disposed in the tubular body and extending from the first end to the second end.

A metals-adsorbent PAN fiber comprising a carbon chain backbone and amidoxime, carboxylate, and nitrile pendant groups. No ester groups are present. The inventive fiber is used for removing metals, including toxic metals, from fresh water, including rivers, streams, lakes, ponds, drinking water from wells and other sources, and industrial discharge waste waters, in a pH range of 3-10, and preferably at slightly acidic conditions in the range of pH 5-6. Metals that can be removed include heavy and toxic metals, such as Sc, V, Mn, Fe, Co, Ni, Cu, Sr, Yb, Cd, Cs, Pb, La, Ce, Nd, Eu, Zn, Tb and U. The adsorbed metals can be removed from the fiber by acidic elution and recovered. The fiber can be rinsed and reused.

A moisture permeable device and refrigerator having the same; the moisture permeable device comprises a corresponding first surface (110) and second surface (111); at least parts of the first surface (110) and the second surface (111) of the moisture permeable device define a hollow cavity (301); through-holes are provided at regions of the first surface (110) and the second surface (111) of the moisture permeable device defining the cavity (301); and regenerated cellulose is accommodated in the cavity (301). A manufacturing method of the moisture permeable device comprises pouring a regenerated cellulose slurry with a tackifier added thereto into the cavity (301). By providing the cavity (301), the regenerated cellulose can be directly poured into the cavity (301) to form a moisture permeable film, thus allowing omission of an assembling procedure and a non-woven support.