A sample is stored in a container (125) disposed upstream of a back-pressure control valve (140). A mixed fluid of carbon dioxide in a supercritical state and a modifier is introduced into the container, and a component contained in the sample is extracted. The extracted component is introduced into a trap column (135) together with the carbon dioxide and the modifier and collected in the trap column. The trap column is loaded with polymer beads as a filler.

An adsorption device for compressed gas, is provided with a vessel with an inlet for the supply of a compressed gas to be treated, and an outlet for treated gas and an adsorption element is affixed in the vessel. The adsorption element extends along the flow direction of the compressed gas to be treated, between the inlet and the outlet. The adsorption element has a monolithic supporting structure that is at least partially provided with a coating that contains an adsorbent.

A porous material structure and device are described and shown to enhance the mass transfer and/or heat transfer at low pressure drops for removal of certain molecular species from a fluid by adsorption and/or catalytic reaction. The porous structure of active materials comprising packed fine particles of adsorbents or catalysts is encapsulated with a thin membrane to provide large interfacing area with the fluid per unit volume for rapid mass transfer between the porous structure and fluid. The thin membrane also blocks particulate from getting into the porous structure of the active material. For the process involving significant heat of adsorption and/or reaction, the another surface of the porous structure of the active material is encapsulated with a thin non-permeable sheet to interface with a thermal fluid for rapid heat transfer between the porous structure and the thermal fluid. The device can be used for removal of CO.sub.2, moisture, and hydrocarbon molecules from a gas stream with rapid in-situ regeneration. The device can be used for removal of water from water-containing liquid fluids, such as solvents and oils. The device can be used for removal of bacteria, virus, salts, and molecular contaminants from one water simultaneously.

An air filter including a filter support that supports polymeric sorbent particles. The polymeric sorbent is the reaction product of a divinylbenzene/maleic anhydride precursor polymeric material with a nitrogen-containing compound. The air filter may be used for capturing e.g. reactive gases.

A method for producing a chromatography medium by: a) exposing a nanoweb sheet having mean flow pore size from 0.1 to 5 m and a porosity from 40 to 90 volume % to a gaseous phase comprising a vinyl monomer to produce a functionalized nanoweb sheet; b) layering a plurality of functionalized nanoweb sheets to form a functionalized nanoweb stack; c) cutting the functionalized nanoweb stack with a die to form die-cut functionalized nanoweb stacks having regular shapes; and d) exposing the die-cut functionalized nanoweb stacks in an aqueous medium to a ligand such as a protein which is capable of forming covalent bonds.

Certain embodiments described herein are directed to systems and methods that can be used to analyze species in a fluid stream. In some configurations, a sorbent tube effective to directly sample aromatics and/or polyaromatics in a fluid stream is described.

A crescent PLOT column is disclosed, including a capillary column having an inlet, an outlet, a bore, and an inner surface surrounding the bore and extending between the inlet and the outlet. A layer of particles is localized on a radial portion of the inner surface. The layer of the particles includes a radial thickness decreasing from a center of the radial portion to a periphery of the radial portion, forming a crescent shape in a radial frame of reference. A method for preparing the crescent PLOT column is disclosed, including loading the capillary column with a fluid including a carrier and particles such that the fluid is contained within the capillary column. The capillary column and the fluid contained within the capillary column are subjected to a centrifugal force. The carrier is removed, and a layer of the particles is localized on the radial portion of the inner surface.

A sorbent cartridge device includes an ion-exchange material containing zirconium phosphate and no more than about 0.1 mg of leachable phosphate ions per about 1 g of the ion-exchange material. In one example, the cartridge also includes a phosphate-adsorbing material containing zirconium oxide. In this example, the weight ratio between zirconium phosphate and zirconium oxide in the cartridge is from about 10:1 to about 40:1. The zirconium phosphate may be alkaline zirconium phosphate prepared by a process including the following steps: (i) drying acid zirconium phosphate to obtain a dry acid zirconium phosphate; (ii) combining the dry acid zirconium phosphate with an aqueous solution to obtain an aqueous slurry; and (iii) combining the slurry with an alkali hydroxide to obtain the alkaline zirconium phosphate. During step (ii), any free phosphate ions in the dry acid zirconium phosphate leach out into the aqueous phase of the slurry.

The present disclosure relates to hollow fiber tangential flow filters, including hollow fiber tangential flow depth filters, for various applications, including bioprocessing and pharmaceutical applications, systems employing such filters, and methods of filtration using the same.

Methods and systems directed to the separation of tritium from an aqueous stream are described. The separation method is a multistage method that includes a purification stage during which tritium of a tritium-contaminated aqueous stream is adsorbed onto a cooled and wet separation phase, a regeneration stage during which the adsorbed tritium is exchanged with hydrogen in a gaseous stream to regenerate the separation phase and provide a gaseous stream with a high tritium concentration, and a third stage during which the tritium of the gaseous stream is separated from the gaseous stream as a gaseous tritium product.