A primary amine polymer aerogel comprising greater than 5 wt. % of primary amine monomers covalently bound to cross-linking monomers, wherein the primary amine monomers are selected from vinyl amine. A secondary amine polymer aerogel comprising secondary amine monomers covalently bound to cross-linking monomers, the secondary amine monomers being a result of substituting a hydrogen atom from a primary amine polymer aerogel, the primary amine polymer aerogel comprising vinyl amine monomers covalently bound to the cross-linking monomers. A tertiary amine polymer aerogel comprising tertiary amine monomers covalently bound to cross-linking monomers, the tertiary amine monomers being a result of substituting hydrogen atoms from a primary amine polymer aerogel, the primary amine polymer aerogel comprising vinyl amine monomers covalently bound to the cross-linking monomers.

A filter apparatus for removing small molecule chemotherapy agents from blood is provided. The filter apparatus comprises a housing with an extraction media comprised of polymer coated carbon cores. Also provided are methods of treating a subject with cancer of an organ or region comprising administering a chemotherapeutic agent to the organ or region, collecting blood laded with chemotherapeutic agent from the isolated organ, filtering the blood laden with chemotherapeutic agent to reduce the chemotherapeutic agent in the blood and returning the blood to the subject.

A solid fiber is described, where the solid fiber is characterized by (a) a modification degree Do/Di, in a cross section of the solid fiber of 1.20 to 8.50 where the inscribed circle diameter is denoted by Di and the circumscribed circle diameter is denoted by Do; and (b) a porous specific surface area of not less than 30 m.sup.2/g.

Chromatography devices contain chromatography media and methods of making and methods of using chromatography devices. Chromatography devices enable a more efficient, productive and/or environmentally friendly chromatographic operation due to one or more of the following advantages over conventional chromatographic operations: elimination of a device packing step by the user; elimination of clean-in-place (CIP) steps; elimination of clean-in-place (CIP) steps utilizing sodium hydroxide solution; elimination of any validation steps by the user; and use of a chromatography device comprising biodegradable material. The chromatography media includes porous inorganic particles having a functionalized surface and having a median pore size of at least about 300 Angstroms (A), or at least about 300 A up to about 3000 A. The inorganic particles may have a BET surface area of at least about 20 m2/g, or at least about 25 m2/g, or about 30 m2/g, up to about 2000 m2/g.

Mesoporous poly (aryl ether ketone) articles are formed from blends of poly (aryl ether ketones) with pore forming additives by melt processing, and can be in the form of a monofilament, disc, film, microcapillary or other complex shapes. The method of formation provides for preparation of poly (aryl ether ketone) articles with high degree of surface area and uniform nanometer pore size. The preferred poly (aryl ether ketone)s are poly (ether ketone) and poly (ether ether ketone). The mesoporous articles formed by the method of the present invention are useful for a broad range of applications, including molecular separations and organic solvent filtration.

A system and process for the recovery of at least one halogenated hydrocarbon from a gas stream. The recovery includes adsorption by exposing the gas stream to an adsorbent with a lattice structure having pore diameters with an average pore opening of between about 5 and about 50 angstroms. The adsorbent is then regenerated by exposing the adsorbent to a purge gas under conditions which efficiently desorb the at least one adsorbed halogenated hydrocarbon from the adsorbent. The at least one halogenated hydrocarbon (and impurities or reaction products) can be condensed from the purge gas and subjected to fractional distillation to provide a recovered halogenated hydrocarbon.

A monolithic organic porous ion exchanger having a continuous skeleton and continuous pores, wherein the continuous skeleton is formed of an organic polymer being a hydrolysate of a crosslinked polymer of a (meth)acrylic acid ester and divinylbenzene, the organic polymer having any one or both of a —COOH group and a —COONa group as ion-exchange groups, the continuous skeleton has a thickness of 0.1 to 100 μm, the continuous pores have an average diameter of 1.0 to 1000 μm, the monolithic organic porous ion exchanger has a total pore volume of 0.5 to 50.0 mL/g, and has a total ion-exchange capacity of the —COOH group and the —COONa group per weight in a dry state of 4.0 mg equivalent/g or more.

Solid material having an open multiple and at least partially interconnected porosity, comprising an inorganic matrix made of a microporous and mesoporous geopolymer, in which at least partially interconnected open macropores delimited by sides or walls made of microporous and mesoporous geopolymer are defined, and particles of at least one solid compound different from the geopolymer being distributed in the macropores and/or in the sides or walls. Method for preparing said material. Method for separating at least one metal or metalloid cation from a liquid medium containing it, wherein said liquid medium is placed in contact with the material.

The present invention relates, in general terms, to methods of forming activated carbon. The method of forming activated carbon comprises mixing carbon black with an activation catalyst and heating the carbon black in order to form the activated carbon. The present invention also relates to applications of activated carbon as disclosed herein. In a preferred embodiment, the activation catalyst is selected from ammonium persulfate, sodium persulfate, potassium persulfate or a combination thereof.

A method of fabrication of a porous polymer aerogel amine material includes preparing a solution comprising at least a solvent, amine monomers having protecting groups, one or more crosslinkers, and one or more radical initiators, heating the solution to promote polymerization and to produce a polymerized material, performing solvent exchange with the polymerized material, causing a deprotection reaction in the polymerized material to remove the protecting groups to produce a deprotected material, soaking and rinsing the deprotected material to remove excess reagents and any byproducts of the deprotection reaction, and drying the deprotecting material to produce the amine sorbent. A system to separate CO.sub.2 from other gases has a polymer porous aerogel sorbent having greater than 5 wt % of amine containing vinyl monomers integrated into a polymer backbone, and the amine containing vinyl monomers may have a molecular weight of less than 100 g/mol.