A device for extraction of analytes with aromatic cycles, preferably analytes with aromatic cycles for which the octanol-water partition coefficient is more than 10.sup.3, the analytes being contained in a liquid phase, the extraction device including a support and an adsorption layer at least partially covering the support, the adsorption layer being porous SiOxCyHz.

A heat transfer fluid can be used as part of a multi-phase adsorption environment to allow for improved separations of gas components using a solid adsorbent. The heat transfer fluid can reduce or minimize the temperature increase of the solid adsorbent that occurs during an adsorption cycle. Reducing or minimizing such a temperature increase can enhance the working capacity for an adsorbent and/or enable the use of adsorbents that are not practical for commercial scale adsorption using conventional adsorption methods. The multi-phase adsorption environment can correspond to a trickle bed environment, a slurry environment, or another convenient environment where at least a partial liquid phase of a heat transfer fluid is present during gas adsorption by a solid adsorbent.

A methane microporous carbon adsorbent comprising a thermally-treated CVD carbon having a shape in the form of a negative replica of a crystalline zeolite has a BET specific surface area, a micropore volume, a micropore to mesopore volume ratio, a stored methane value and a methane delivered value and a sequential carbon synthesis method for forming the methane microporous carbon adsorbent. Introducing an organic precursor gas for a chemical vapor deposition (CVD) period to a crystalline zeolite that is maintained at a CVD temperature forms the carbon-zeolite composite. Introducing a non-reactive gas for a thermal treatment period to the carbon-zeolite composite maintained at a thermal treatment temperature forms the thermally-treated carbon-zeolite composite. Introducing an aqueous strong mineral acid mixture to the thermally-treated carbon-zeolite composite forms the methane microporous carbon adsorbent.

A method of operating an evaporation pump system in a chamber at partial vacuum is provided. The method includes heating a getter source to form a getter vapour; depositing the getter vapour onto a first target surface arranged within the chamber to form a getter layer; and providing a replenished target surface within the chamber, and onto which the getter vapour can be deposited, by at least partially removing, from the first target surface, the getter layer and any chemisorbed, and/or physisorbed products present within the getter layer, said step being carried out within the chamber; and/or arranging a second target surface within the chamber, wherein, the getter source comprises lithium.

The invention describes a mass for scavenging mercaptans which is particularly suitable for the treatment of olefinic gasoline cuts containing sulfur such as gasolines resulting from catalytic cracking. The scavenging mass comprises an active phase based on group VIII, IB or IIB metal particles which is prepared by a step of bringing a porous support into contact with a metal salt of said group VIII, IB or IIB metal and a step heating the resulting mixture to a temperature above the melting point of said metal salt. The invention also relates to a process for using said scavenging mass for the adsorption of mercaptans.

Oleophilic-hydrophobic-magnetic (OHM) porous materials are provided. In embodiments, an OHM porous material comprises a porous substrate having a solid matrix defining a plurality of pores distributed through the solid matrix, the OHM porous material further comprising a coating of a nanocomposite on surfaces of the solid matrix. The nanocomposite comprises a multilayer stack of a plurality of layers of a two-dimensional, layered material having nucleation sites interleaved between a plurality of layers of magnetic nanoparticles, wherein individual layers of magnetic nanoparticles in the plurality of layers of magnetic nanoparticles are each directly anchored on a surface of a layer of the plurality of layers of the two-dimensional, layered material via the nucleation sites, and are each separated by multiple layers of the plurality of layers of the two-dimensional, layered material. Methods of making and using the OHM porous materials are also provided.

A process for reducing coke formation during hydrocarbon upgrading reactions using a double-wall reactor comprising the steps of feeding a heated feed water to a shell-side volume of the double-wall reactor to produce a heat transfer stream, the double-wall reactor comprising an exterior wall and an interior wall, a reaction section volume, a heating element configured to heat the heat transfer stream, wherein heat is transferred from the heat transfer stream to the reaction section volume, feeding the hot water return exiting the shell-side volume through a filter; mixing the filtered water stream with a heated hydrocarbon feedstock; feeding the mixed stream to the reaction section volume in a configuration counter-current to the heat transfer stream; reacting the reaction flow stream at a reaction temperature, wherein the heat transferred to the reaction section volume is operable to maintain the reaction temperature above the critical temperature of water.

The invention in its various embodiments is directed to methods and equipment for generating an activated sorbent from a sorbent precursor with the addition of certain chemicals that enhance the effectiveness of the activated sorbent. The invention in its various embodiments is also directed to the methods and equipment for generating some of the chemicals that are added to the raw carbonaceous material or activated sorbent to enhance its effectiveness. The invention in its various embodiments is also directed to methods and equipment for generating certain chemicals that can be added to a gas stream to convert a given gaseous pollutant to a form that is more easily removed from the gas stream.

Disclosed herein are methods, and compositions produced using the methods, including introducing porous substrate particles and a first reagent comprising a polymer to a solvent to provide a plurality of coated particles; and introducing a second reagent comprising a polymeric amine and a third reagent comprising a silane moiety and an amine moiety to the coated particles, thereby providing a plurality of functionalized, coated particles.

Provided is a method for producing a water-absorbing resin composition, the method imparting high gel stability, suppressing an increase in the amount of water-absorbing resin particles that are dissolved by a sulfite-based compound, and suppressing yellowing that could occur under a high temperature and high humidity. This method for producing a water-absorbing resin composition comprises a step for spraying an aqueous solution of a sulfite-based compound on surface-crosslinked water-absorbing resin particles, and a step for spraying an aqueous solution of an organic antioxidant on the surface-crosslinked water-absorbing resin particles.