The present disclosure provides processes and systems for dehydrating a byproduct stream in ethanol production. In one embodiment, a feed mixture is distilled with one or more distillation units to remove at least a portion of the water, and form a first byproduct stream. The first byproduct stream is contacted with a molecular sieve unit, thereby forming a product stream. The molecular sieve unit is cyclically contacted with at least a portion of the product stream to regenerate the molecular sieve unit and form one or more regenerate streams. A second byproduct stream including at least one of (1) the regenerate streams and (2) at least a portion of the fusel oil stream is contacted with a separation system, thereby forming a permeate and a retentate. At least a portion of the retentate is forwarded into the product stream.

A system and process for the recovery of at least one halogenated hydrocarbon from a gas stream. The recovery includes adsorption by exposing the gas stream to an adsorbent with a lattice structure having pore diameters with an average pore opening of between about 5 and about 50 angstroms. The adsorbent is then regenerated by exposing the adsorbent to a purge gas under conditions which efficiently desorb the at least one adsorbed halogenated hydrocarbon from the adsorbent. The at least one halogenated hydrocarbon (and impurities or reaction products) can be condensed from the purge gas and subjected to fractional distillation to provide a recovered halogenated hydrocarbon.

The present disclosure provides a method for generating higher hydrocarbon(s) from a stream comprising compounds with two or more carbon atoms (C.sub.2+), comprising introducing methane and an oxidant (e.g., O.sub.2) into an oxidative coupling of methane (OCM) reactor. The OCM reactor reacts the methane with the oxidant to generate a first product stream comprising the C.sub.2+ compounds. The first product stream can then be directed to a separations unit that recovers at least a portion of the C.sub.2+ compounds from the first product stream to yield a second product stream comprising the at least the portion of the C.sub.2+ compounds.

As an improvement to processes for desulfurization of natural gas and synthetic natural gas streams that employ conventional zeolitic materials (absorbents), including copper-containing zeolites, pre-treatment methods and post-treatment methods are provided that lower the level of leachable benzene following desulfurization with the absorbents to <0.5 mg benzene/L leachate, while retaining within the absorbents a majority of sulfur adsorbed from a gas stream.

A method and system for manufacturing and using a self-supporting structure in processing unit for adsorption or catalytic processes. The self-supporting structure has greater than 50% by weight of the active material in the self-supporting structure to provide a foam-geometry structure providing access to the active material. The self-supporting structures, which may be disposed in a processing unit, may be used in swing adsorption processes and other processes to enhance the recovery of hydrocarbons.

A process is provided for removing contaminants from olefin containing C.sub.4 streams. The streams are contacted with an X based zeolite adsorbent comprising greater than 88% X zeolite at a SiO.sub.2/Al.sub.2O.sub.3 ratio of less than 2.5 and an alkali metal salt present in excess of an amount required to achieve full exchange of cation sites on the X based zeolite. The resulting alkali oxide on a volatile free basis is less than 1% (by mass) of the X based adsorbent. The contaminants that are removed include sulfur, oxygenate, and nitrogen based contaminants.

The invention provides methods and systems for washing adsorptive media with minimal water consumption. More specifically, the invention provides methods and systems for in situ regeneration and/or sanitization of adsorptive media, such as activated carbon, using back-and-forth washing.

The present disclosure provides processes and systems for dehydrating a byproduct stream in ethanol production. In one embodiment, a feed mixture is distilled with one or more distillation units to remove at least a portion of the water, and form a first byproduct stream. The first byproduct stream is contacted with a molecular sieve unit, thereby forming a product stream. The molecular sieve unit is cyclically contacted with at least a portion of the product stream to regenerate the molecular sieve unit and form one or more regenerate streams. A second byproduct stream including at least one of (1) the regenerate streams and (2) at least a portion of the fusel oil stream is contacted with a separation system, thereby forming a permeate and a retentate. At least a portion of the retentate is forwarded into the product stream.

Disclosed herein are systems and methods for regenerating media in a siloxane removal system. In particular, the present disclosure relates to a method for regenerating an adsorption medium, comprising receiving a source gas stream comprising at least one hydrocarbon and carbon dioxide; separating the source gas stream into a carbon dioxide-rich gas stream, and a substantially carbon dioxide-free gas stream; directing the carbon dioxide-rich gas stream into a regeneration vessel containing an adsorption medium having one or more adsorbed impurities on the adsorption medium; desorbing impurities from the adsorption medium by contacting the adsorption medium with the carbon dioxide-rich gas stream to generate a carbon dioxide-rich gas containing desorbed impurities and a regenerated adsorption medium; and directing the carbon dioxide-rich gas stream containing desorbed impurities out of the regeneration vessel.

A method for continuously treating a regeneration gas stream used to regenerate a molecular sieve adsorption vessel is disclosed. The regeneration gas stream is cooled in a cooler to a temperature suitable to condense liquids therein. A separator removes liquids condensed in the regeneration gas stream. The regeneration gas stream is compressed in a compressor. The regeneration gas stream is flowed through the cooler, the separator, and the compressor when the compressor is operational. The regeneration gas stream is flowed through the second cooler and the second separator but not the compressor when the compressor is not operational, thereby enabling continuous treatment of the regeneration gas stream.