Patent classifications
B01J20/3416
BORON REMOVAL AND MEASUREMENT IN AQUEOUS SOLUTIONS
In one embodiment, the invention relates to a carbon-based boron removal medium with hydroxyl groups and amine group, and in particular, to a method for forming the carbon-based boron removal medium. In a specific embodiment, nitrogen-doped (N-doped) graphene oxide is synthesized by a simple two-step process: (1) oxidation of graphite to graphene oxide, and (2) nitrogen-doping (N-doping) the graphene oxide to form the amine group. The resultant N-doped graphene oxide can efficiently remove boron from aqueous solutions. In another embodiment, a method of sensing or detecting the presence of boron in an aqueous solution by using a boron sensing medium comprises at least two hydroxyl groups and at least one pyridinic nitrogen or pyrrolic nitrogen or quaternary nitrogen (i.e. pyridoxine, in particular vitamin B6). The boron ions in the solution would form a highly ionized complex, which can cause significant increase in electrical conductivity of the solution, which can then be used to measure the concentration of boron in said solution.
Device and method for treating a gas laden with pollutants
A device for treating a gas laden with pollutants, includes at least one adsorption module for adsorbing the pollutants, which is utilized in an adsorption apparatus. The adsorption module includes at least one electrically conductive layer of an activated carbon fiber mat, an electric current circuit for heating the activated carbon fiber mat for the desorption of the adsorbed pollutants, and distributing conduit which is routed into the center of the adsorption module and has outlet openings for a flush gas for inertizing and rinsing the activated carbon fiber mat.
NON-SCALING WET AIR OXIDATION SYSTEM AND PROCESS
There is provided a system and a method for regenerating a material that reduce the incidence of scaling due to scale forming contaminants. The method may include reducing a temperature of a treated material exiting a wet air oxidation unit in a scale reducing heat exchanger prior to delivery of the treated material to a second heat exchanger which heats a source waste material comprising a scale forming contaminant therein with heat from the first treated material to form a heated waste material comprising the scale forming contaminant.
PROCESSES FOR RECOVERING PFAS FROM SOLID SORBENTS
A solvent extraction process for removing poly- and perfluoroalkyl substances (PFAS) from a PFAS laden adsorbent is disclosed. The process comprises introducing a substantially pure solvent at an elevated temperature to a bed of the PFAS laden adsorbent and continuously removing PFAS laden solvent from the adsorbent, wherein the introducing and removing are carried out simultaneously and continuously until a desired amount of PFAS is removed from the adsorbent. Also disclosed is a process for degrading poly- and perfluoroalkyl substances (PFAS) to environmentally benign products. The process comprises providing an aqueous solution containing PFAS at a concentration of greater than 50 ppm; and subjecting the aqueous solution to ultrasound using at least one ultrasonic transducer at a frequency and power and for a time sufficient to degrade substantially all of the PFAS in the solution to carbon dioxide and fluoride.
Treating sulfuric acid
Provided is a method for treating sulfuric acid comprising the step (I) of bringing said sulfuric acid into contact with a collection of solid particles (B) having BET surface area of 50 m.sup.2/g to 5,000 m.sup.2/g and having volume-average particle diameter of 200 m or less.
EMISSIONS CONTROL SYSTEM WITH CZTS SORBENTS, CZTS-BASED ALLOY SORBENTS, AND/OR CARBON-BASED SORBENTS AND METHOD OF USE
An emissions control system including a fluidized bed apparatus containing a reactive sorbent material is disclosed for gaseous and non-gaseous contaminated emissions. The reactive sorbent material may be CZTS, CZTS-Alloy, or a carbon-based sorbent material. The fluidized bed apparatus is configured with one or more closed loop sorbent recycling subsystems. The sorbent recycling subsystems include the capability to separate sorbents from each other, separate contaminates from sorbents for disposal and/or recycling, clean and/or rejuvenate sorbents for return to the fluidized bed apparatus, dispose of spent and exhausted sorbents, and replace the spent and exhausted sorbents with new sorbent to maintain consistent sorbent function in the fluidized bed apparatus. Monitoring sensors provide information useful in a method for establishing and maintaining consistent process parameter controls.
METHOD FOR REMOVAL OF FLUORINATED ORGANICS FROM BYPRODUCT ANHYDROUS OR AQUEOUS HYDROCHLORIC ACID IN THE 1234YF VIA 1230XA PROCESS
Disclosed is a process to separate halogenated organic contaminants such as 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), 2,3,3,3-tetrafluoropropene (HFO-1234yf), trifluoropropyne (TFPY) from hydrochloric acid (HCl) with an adsorbent selected from an activated carbon, an MFI molecular sieve, a carbon molecular sieve, silica, and combinations thereof.
Non-scaling wet air oxidation system
There is provided a system and a method for regenerating a material that reduce the incidence of scaling due to scale forming contaminants. The method may include reducing a temperature of a treated material exiting a wet air oxidation unit in a scale reducing heat exchanger prior to delivery of the treated material to a second heat exchanger which heats a source waste material comprising a scale forming contaminant therein with heat from the first treated material to form a heated waste material comprising the scale forming contaminant.
Temperature controlled adsorption process for recovering condensable components from a gas stream
Disclosed is an improved process for recovering condensable components from a gas stream, in particular, hydrocarbons from a gas stream such as natural gas. The present process uses solid adsorbent media to remove said hydrocarbons wherein the adsorbent media is regenerated in a continuous fashion in a heated continuous counter-current regeneration system, wherein said heated regenerated adsorbent media is cooled prior to reuse.
SORBENTS FOR THE OXIDATION AND REMOVAL OF MERCURY
A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.