Use of poly(alkylamine)-derived (PAD) self-supported cross-linked polymeric ammonium salts and ionomer hydrogels for adsorbing and desorbing organic contaminants, specifically per and polyfluoro alkyl substances (PFAS) from water.

A regeneration solvent comprised of one or more ethylene amines may contact an adsorbent bed that has been used to remove sulfur compounds from a hydrocarbon stream to extract adsorbed sulfur compounds from the adsorbent material in the bed to regenerate it. The one or more ethyleneamines may have structure (I), (II), or (III): ##STR00001##
where R.sup.1, R.sup.2, R.sup.5 and R.sup.6 are, to the extent chemically possible, independently H, C.sub.1-C.sub.4 linear or branched alkyl, amido (RRNC═O), or hydroxyalkyl, where each R in the amido group is independently H or C.sub.1 alkyl, where R.sup.3 and R.sup.4 are alkylene of from 1 to 4 carbon atoms, where x ranges from 0 to 3, y ranges from 1 to 6. The regenerated adsorbent bed may be reused, either alone or in combination with a liquid-liquid extraction column, to remove sulfur compounds from a hydrocarbon stream.

A method for producing a nanocomposite sorbent comprising carbon nanotube-grafted acrylic acid/acrylamide copolymer which involves copolymerization of acrylic acid and acrylamide in the presence of an aqueous dispersion of carbon nanotubes. The method yields a nanocomposite sorbent material having a reversible adsorption capacity phenol of 5 to 2500 μg of phenol per mg of nanocomposite sorbent. Also disclosed is a method for removing organic pollutants from water using the nanocomposite sorbent.

The invention provides methods and systems for sanitizing and/or regenerating porous filter media using dissolved ozone in the filter backwash under fluidized conditions.

Method and plant for treating water implementing a contact vessel (21) for putting water into contact with a granular adsorbent material and a clarification, granular adsorbent material is constituted by agglomerates of active carbon particles, said agglomerates having an average size of 200 μm to 600 μm and a specific surface area of 800 to 1000 m.sup.2/g, a screen (9) being provided in the upper part of the contact vessel (21) comprising a layer of porous material having a thickness of 1 to 5 mm and a cut-off threshold of 100 μm to 200 μm, said contact vessel (21) having a hopper-shaped lower part (21a), purging means (21b) and stirring means (22) to stir the content of the upper part of this contact vessel (21) without stirring the content of the lower hopper-shaped part.

The invention pertains to a process for in-situ regeneration of activated carbon loaded with trihalomethane (THM). Based on the invention, this is achieved with alkaline hydrolysis of the THM with increased temperatures within the activated carbon in halogen-free, good water-soluble, or gaseous compounds. After completion of the chemical hydrolysis treatment, the activated carbon is cleared of reagents and reaction products by rinsing with water and diluted acids, and is then available for reloading in the untreated water flow. During the entire cleaning process, the activated carbon bed must not be moved.

There is provided a system and a method for regenerating a material that reduce the incidence of scaling due to scale forming contaminants. The method may include reducing a temperature of a treated material exiting a wet air oxidation unit in a scale reducing heat exchanger prior to delivery of the treated material to a second heat exchanger which heats a source waste material comprising a scale forming contaminant therein with heat from the first treated material to form a heated waste material comprising the scale forming contaminant.

Disclosed is an improved process for recovering condensable components from a gas stream, in particular, hydrocarbons from a gas stream such as natural gas. The present process uses solid adsorbent media to remove said hydrocarbons wherein the adsorbent media is regenerated in a continuous fashion in a heated continuous counter-current regeneration system, wherein said heated regenerated adsorbent media is cooled prior to reuse.

Method for manufacturing an inert solid support with optionally functionalised carbon nanotubes (CNTs), comprising the steps of: i) providing an inert solid support and at least one catalytic metal associated with, or absorbed in, or adsorbed/deposited on, said support, said metal being optionally selected from among the group consisting of iron, cobalt, nickel, molybdenum and combinations thereof; ii) supplying a source of gaseous, liquid or solid carbon to the catalytic metal; iii) through chemical vapor deposition (CVD), depositing at least part of the carbon source at the catalytic metal as CNTs, stably connected to the inert solid support. The present invention further regards an inert solid support and a separation method.

A device for treating a gas laden with pollutants, includes at least one adsorption module for adsorbing the pollutants, which is utilized in an adsorption apparatus. The adsorption module includes at least one electrically conductive layer of an activated carbon fiber mat, an electric current circuit for heating the activated carbon fiber mat for the desorption of the adsorbed pollutants, and distributing conduit which is routed into the center of the adsorption module and has outlet openings for a flush gas for inertizing and rinsing the activated carbon fiber mat.