The present invention provides a process for capturing CO.sub.2 from a gas stream, the process at least comprising the steps of: (a) providing a CO.sub.2-containing gas stream; (b) contacting the gas stream as provided in step (a) in an adsorption zone with solid adsorbent particles thereby obtaining CO.sub.2-enriched solid adsorbent particles (c) passing CO.sub.2-enriched solid adsorbent particles as obtained in step (b) from the bottom of the adsorption zone to the bottom of a first desorption zone; (d) removing a part of the CO.sub.2 from the CO.sub.2-enriched solid adsorbent particles in the first desorption zone, thereby obtaining partly CO.sub.2-depleted solid adsorbent particles and a first CO.sub.2-enriched gas stream; (e) passing the partly CO.sub.2-depleted solid adsorbent particles as obtained in step (d) via a riser to a second desorption zone; (f) removing a further part of the CO.sub.2 from the partly CO.sub.2-depleted solid adsorbent particles in the second desorption zone thereby obtaining regenerated solid adsorbent particles and a second CO.sub.2-enriched gas stream; and (g) recycling regenerated solid adsorbent particles as obtained in step (f) to the adsorption zone of step (b); wherein the second desorption zone is located above the adsorption zone.

The invention relates to strong hydrogen-bond acidic sorbents. The sorbents may be provided in a form that limits or eliminates intramolecular bonding of the hydrogen-bond acidic site between neighboring sorbent molecules, for example, by providing steric groups adjacent to the hydrogen-bond acidic site. The hydrogen bond site may be a phenolic structure based on a bisphenol architecture. The sorbents of the invention may be used in methods for trapping or detecting hazardous chemicals or explosives.

An apparatus for capturing a water content from a water containing gas, the apparatus comprising: a housing having an inlet into which the water containing gas can flow; a water adsorbent located in the housing, the water adsorbent comprising at least one water adsorbent metal organic framework composite capable of adsorbing a water content from the water containing gas; and a water desorption arrangement in contact with and/or surrounding the water adsorbent, the water desorption arrangement being selectively operable between (i) a deactivated state, and (ii) an activated state in which the arrangement is configured to apply heat, a reduced pressure or a combination thereof to the water adsorbent to desorb a water content from the water adsorbent.

Solid absorbent compositions and methods for the removal of mercaptan sulfur compounds from hydrocarbon streams are provided. The compositions may include porous granulated activated carbon particles with internal pore surfaces containing bound trinuclear basic iron (III) acetate complex containing the [Fe.sub.3(μ.sup.3−O)] core structure.

The invention relates to a process, catalysts, materials for conversion of renewable electricity, air, and water to low or zero carbon fuels and chemicals by the direct capture of carbon dioxide from the atmosphere and the conversion of the carbon dioxide to fuels and chemicals using hydrogen produced by the electrolysis of water.

A method of capturing water from a composition comprising water or water vapour using a hybrid ultramicroporous material. The method comprises the steps of: (a) providing a hybrid ultramicroporous material of formula [M(L)a(X)b]; and (b) contacting the hybrid ultramicroporous material with the composition comprising water to capture water into the hybrid ultramicroporous material; The hybrid ultramicroporous materials used in the method of the present invention have fast kinetics of water uptake and high working capacity compared to known commercial sorbent materials. The method of the present invention may be used in water capture and purification processes to provide fresh water suitable for drinking or for use in agriculture. The method of the present invention may also be used to remove water as a contaminant or for use in dehumidification processes. A use of such a hybrid ultramicroporous material and a device for capturing water are also disclosed.

A carbon dioxide recovery system, which is configured to separate and recover carbon dioxide from a carbon dioxide containing gas, includes an adsorption unit that includes an adsorbent material that is configured to adsorb and desorb the carbon dioxide. The adsorbent material is configured to radiate heat in response to adsorption of the carbon dioxide and is configured to absorb the heat in response to desorption of the carbon dioxide. The adsorption unit is one of a plurality of adsorption units, and adjacent two adsorption units among the plurality of adsorption units contact with each other. When one of the adjacent two adsorption units adsorbs the carbon dioxide, another one of the adjacent two adsorption units desorbs the carbon dioxide.

Provided is the use of a carboxylate compound as an absorbent for capturing carbon dioxide and/or in the preparation of an absorbent for capturing carbon dioxide. In the carboxylate compound, the carboxylate anion is a carboxylate radical with a carbon chain having a carbon atom number of more than 3, or a branched-chain carboxylate radical having a carbon atom number of more than 6; and the cation is a substituted quaternary ammonium ion, quaternary phosphorus ion, pyridinium ion, pyrrolium ion, piperidinium ion, imidazolium ion or metal ion. In the present invention, a method which can capture carbon dioxide in an efficient and energy-saving manner by using a carboxylate compound and has water stability is involved, and the method comprises the following step: putting an aqueous solution of a carboxylate compound in a carbon dioxide atmosphere to absorb carbon dioxide, thereby obtaining a carboxylate and carbon dioxide conjugate precipitated from water.

Crosslinked polymers made up of polymerized units of cyclic diaminoalkane, aldehyde and bisphenol-S or melamine. A method for removing heavy metals, such as Pb(II) from an aqueous solution or an industrial wastewater sample with these crosslinked polymers is introduced. A process of synthesizing the crosslinked polymers is also described.

A variety of compositions and materials are provided for water purification and remediation. The compositions including multiple functionalities for treating a variety of pollutants or contaminants. The compositions can include a porous organic polymer with one or more of a variety of functional groups for binding the contaminants and with a hierarchical pore size distribution over a range of pore sizes to facilitate enhanced removal of the contaminants. Functional groups can include one, two, or more different functional groups such as amines, halides, ammoniums, pyridiuiums, thiols, imidazoliums, salts thereof, or others. The range of pore sizes can be about 1 nm to 10 nm or more. Contaminants can include antimony, arsenic, barium, beryllium, cadmium, chromium, copper, lead, mercury, selenium, technetium, thallium, uranium, radium, urea, and phosphate. Methods of removing the contaminants from water using the compositions are also provided.