An apparatus for capturing a water content from a water containing gas, the apparatus comprising: a housing having an inlet into which the water containing gas can flow; a water adsorbent enclosed within the housing, the water adsorbent comprising at least one water adsorbent metal organic framework composite capable of adsorbing a water content from the water containing gas, the metal organic framework composite comprising: at least 50 wt % water adsorbent metal organic framework; from 0.2 to 10 wt % magnetic particles having a mean particle diameter of less than 200 nm; and at least 0.1 wt % hydrophilic binder comprising a hydrophilic cellulose derivative; and a water desorption arrangement in contact with and/or surrounding the water adsorbent, the water desorption arrangement being selectively operable between (i) a deactivated state, and (ii) an activated state in which the arrangement is configured to apply heat to the water adsorbent to desorb a water content from the water adsorbent, wherein the water desorption arrangement comprises an alternating current (AC) magnetic field generator located within and/or around the water adsorbent configured to apply an AC magnetic field to the water adsorbent.

The invention relates to regenerative, solid sorbents for adsorbing carbon dioxide from a gas mixture, including air, with the sorbent including a modified polyamine and a solid support. The modified polyamine is the reaction product of an amine and an epoxide. The sorbent provides structural integrity, as well as high selectivity and increased capacity for efficiently capturing carbon dioxide from gas mixtures, including the air. The sorbent is regenerative, and can be used through multiple cycles of adsorption-desorption.

The present disclosure relates to charge-bearing polymeric materials and methods of their use for purifying fluid samples from micropollutants, such as anionic micropollutants.

A fuel tank inerting system is disclosed. The system includes a fuel tank and a catalytic reactor with an inlet, an outlet, a reactive flow path between the inlet and the outlet, and a catalyst on the reactive flow path. The catalytic reactor is arranged to receive fuel from a fuel flow path in operative communication with the fuel tank and oxygen from an oxygen source, and to catalytically react a mixture of the fuel and oxygen along the reactive flow path to generate an inert gas. An inert gas flow path provides inert gas from the catalytic reactor to the fuel tank. An adsorbent is disposed along the fuel flow path or along the reactive flow path.

Metal-binding proteins, such as metallothionein proteins, are disclosed for removing metals from substrates in need of having such metals removed therefrom. Specifically, metallothionein proteins according to SEQ ID NO:1, 2, or 9-20 are disclosed for removing metals from liquid substrates. Associated methods for removing metals from substrates using metallothionein proteins are also disclosed.

The present invention relates to a device for the reversible adsorption of carbon dioxide from a gas mixture, comprising at least one adsorbent vessel comprising one or a plurality of gas permeable cartridge vessels of an inert and dimensionally stable material, and each cartridge comprising a suitable polymeric particular adsorbent having a primary amino functionality; to an arrangement including the device, and to a method for ad- and desorption of carbon dioxide.

A carbon dioxide absorbent of an embodiment includes a solid resin compound containing a structural unit expressed by the following formula (1). X in the formula (1) is a halogen element.

A system and method for acid gas separations using porous frameworks of metal atoms coordinatively bound to polytopic linkers that are functionalized with basic nitrogen ligands that expose nitrogen atoms to the pore volumes forming adsorption sites. Adjacent basic nitrogen ligands on the metal-organic framework can form an ammonium from one ligand and a carbamate from the other. The formation of one ammonium carbamate pair influences the formation of ammonium carbamate on adjacent adsorption sites. Adsorption of acid gas at the adsorption sites form covalently linked aggregates of more than one ammonium carbamate ion pair. The acid gas adsorption isotherm can be tuned to match the step position with the partial pressure of acid gas in the gas mixture stream through manipulation of the metal-ligand bond strength by selection of the ligand, metal and polytopic linker materials.

Yttria containing hybrid organic-inorganic sol-gels may be used in coatings for capillary microextraction, optionally hyphenated to online HPLC analysis. The sol-gel reaction mixture can use an yttrium trialkoxyalkoxide, such as yttrium trimethoxyethoxide, and a [bis(hydroxyalkyl)-amino-alkyl]-terminated polydialkyl/arylsiloxane, such as [bis(hydroxyethyl)-amine] (BHEA)-terminated polydimethylsiloxane, that can undergo hydrolysis and polycondensation, to form coating materials. Capillaries coated with such sol-gels can have improved extraction efficiency compared, e.g., to pure yttria-based coatings. The CME-HPLC can analyze water samples containing analytes of varied polarity, with excellent extraction of amides, phenols, alcohols, ketones, aldehydes, and polyaromatic hydrocarbons and detection limits ranging from 0.18 to 7.35 ng/mL (S/N=3). Such capillaries can exhibit solvent stability at pH 0 to 14, RSD % between 0.6 to 6.8% (n=3), at a preparative reproducibility RSD between 4.1 and 9.9%.

Porous materials (such as organic polyamine cage compounds) and methods of stabilising porous materials which are otherwise prone to pore-collapse are described. Such stabilisation is accomplished through the use of molecular ties to create bridges between reactive groups of a (potentially) porous material to thereby strengthen and stabilise the porous structure. The chemistry involved in, and the results of, the stabilisation of porous materials to provide a new sorption composition comprising the very materials which are generally prone to pore-collapse are also described.