Yttria containing hybrid organic-inorganic sol-gels may be used in coatings for capillary microextraction, optionally hyphenated to online HPLC analysis. The sol-gel reaction mixture can use an yttrium trialkoxyalkoxide, such as yttrium trimethoxyethoxide, and a [bis(hydroxyalkyl)-amino-alkyl]-terminated polydialkyl/arylsiloxane, such as [bis(hydroxyethyl)-amine] (BHEA)-terminated polydimethylsiloxane, that can undergo hydrolysis and polycondensation, to form coating materials. Capillaries coated with such sol-gels can have improved extraction efficiency compared, e.g., to pure yttria-based coatings. The CME-HPLC can analyze water samples containing analytes of varied polarity, with excellent extraction of amides, phenols, alcohols, ketones, aldehydes, and polyaromatic hydrocarbons and detection limits ranging from 0.18 to 7.35 ng/mL (S/N=3). Such capillaries can exhibit solvent stability at pH 0 to 14, RSD % between 0.6 to 6.8% (n=3), at a preparative reproducibility RSD between 4.1 and 9.9%.

This disclosure relates to new filtration systems, granular substrates, granular media and processes that are highly effective for removing suspended oil, particulates and oily particulates from an oil-water mixture. The new filtration media comprises a microporous granular substrate having a combination of specified micro-porosity, hardness and additional characteristics, the substrate being modified by an infused or coated absorption composition. This resulting filtration media displays excellent filtration performance, including outstanding durability and robustness to sustain its excellent performance over a large number of backwash cycles.

Crosslinked polymers made up of polymerized units of cyclic diaminoalkane, aldehyde and bisphenol-S or melamine. A method for removing heavy metals, such as Pb(II) from an aqueous solution or an industrial wastewater sample with these crosslinked polymers is introduced. A process of synthesizing the crosslinked polymers is also described.

Methods of dewatering viscous materials are provided. The method comprises contacting the viscous material with pressurized carbon dioxide at a temperature and for a time wherein at least a fraction of water is expressed from the viscous material. Then the pressure is released, and the water expressed from the viscous material is removed to yield a dewatered product. Exemplary viscous materials that can be dewatered by the method include black liquor from wood pulping operations, wet lignin, wet super water absorbent polymers and sugar solutions. The pressurized carbon dioxide is present in subcritical or supercritical form. The method provides dewatering at reduced cost.

There is provided a structurally stable monolith substrate, suitable to provide carbon dioxide capture structure for removing carbon dioxide from air, having two major opposed surfaces, and further having a plurality of longitudinal channels extending between and opening through the two major opposed surfaces of the structurally stable monolith substrate; and a macroporous coating, adhered to the interior wall surfaces of the longitudinal channels, comprising an adherent, coating formed of cohered, compact mesoporous particles each being formed of a material that is compatible with the material forming the underlying substrate structure so as to become adherent thereto when coated. The mesoporous particles are capable of supporting in their mesopores a sorbent for CO.sub.2 There is also provided a method for forming the monolith and a system for utilizing the monolith as part of a CO.sub.2 capture structure, within the system, to remove CO.sub.2 from the atmosphere.

The invention relates to strong hydrogen-bond acidic sorbents. The sorbents may be provided in a form that limits or eliminates intramolecular bonding of the hydrogen-bond acidic site between neighboring sorbent molecules, for example, by providing steric groups adjacent to the hydrogen-bond acidic site. The hydrogen bond site may be a phenolic structure based on a bisphenol architecture. The sorbents of the invention may be used in methods for trapping or detecting hazardous chemicals or explosives.

Provided is a method for recycling a water-absorbing resin which contains absorbed liquid, with consideration for a resource aspect and an energy aspect. The method for recycling a water-absorbing resin which contains absorbed liquid includes: discharging the absorbed liquid from the water-absorbing resin which contains the absorbed liquid; and recovering a water-absorbing power of the water-absorbing resin.

This invention relates to a method of using MOF adsorbents to remove elemental impurities from feed streams comprising active pharmaceutical ingredients (API). The process involves contacting the feed stream comprising API and elemental impurities with the MOF at purification conditions to obtain a purified stream with provides an API which has a concentration of the elemental impurity below its permitted daily exposure. The process can be carried in a batch mode where the MOF and feed stream are admixed in a vessel for a given amount of time or continuously by flowing the feed stream through a column or adsorbent bed containing the MOF adsorbent.

Crosslinked polymers made up of polymerized units of cyclic diaminoalkane, aldehyde and bisphenol-S or melamine. A method for removing heavy metals, such as Pb(II) from an aqueous solution or an industrial wastewater sample with these crosslinked polymers is introduced. A process of synthesizing the crosslinked polymers is also described.

The present invention relates to a method for preparing a macromolecular composition comprising indene-derivatives. The invention also relates to the macromolecular compositions per se, and to methods of using the macromolecular compositions. The macromolecular compositions are useful for undergoing subsequent reactions with small molecules.