Industrial waste derived adsorbents were obtained by pyrolysis of sewage sludge, metal sludge, waste oil sludge and tobacco waste in some combination. The materials were used as media to remove hydrogen sulfide at room temperature in the presence of moisture. The initial and exhausted adsorbents after the breakthrough tests were characterized using sorption of nitrogen, thermal analysis, XRD, ICP, and surface pH measurements. Mixing tobacco and sludges result in a strong synergy enhancing the catalytic properties of adsorbents. During pyrolysis new mineral phases are formed as a result of solid state reaction between the components of the sludges. High temperature of pyrolysis is beneficial for the adsorbents due to the enhanced activation of carbonaceous phase and chemical stabilization of inorganic phase. Samples obtained at low temperature are sensitive to water, which deactivates their catalytic centers.

A carbon dioxide adsorbent including silica gel and an amine compound carried by the silica gel. The silica gel has a spherical shape, a particle size ranging from 1 mm to 5 mm inclusive, an average pore diameter ranging from 10 nm to 100 nm inclusive, a pore volume ranging from 0.1 cm.sup.3/g to 1.3 cm.sup.3/g inclusive, and a waterproof property N that is defined by an expression (1) and that is not lower than 45%,

N=(W/W.sub.0)×100  (1) where N is the waterproof property in percentage (%) of the silica gel, W.sub.0 is a total number of particles of the silica gel immersed in water, W is a number of particles of the silica gel not subjected to breakage out of W.sub.0.

Provided is a method for recovering, by pressure swing adsorption, unreacted olefins from a stream of a chemical reaction process in which an olefin is used as a material, the method enables desorption of gas at a relatively high desorption operation pressure, more preferably at a pressure not lower than the atmospheric pressure, and enables reuse of a separation agent. As the separation agent, a metal complex is used, in which pressure P3 at which a local maximum of dA/dP is obtained during adsorption and pressure P4 at which a local maximum of dA/dP is obtained during desorption are located between an adsorption operation pressure P1 and a desorption operation pressure P2, where dA/dP represents a value obtained by differentiating A by P, assuming that an olefin adsorption amount (A) is a function of an adsorption pressure (P), i.e., A=f(P), on an adsorption isotherm indicating the pressure (P) and the adsorption amount (A).

Hydrogel-based sorbents and methods for their use in collecting, concentrating, and removing environmental per- and poly-fluoroalkyl substances. In one aspect, the invention provides hydrogel-based sorbents that are effective for collecting, concentrating, and removing PFASs from an environment in which the sorbent is placed; an environment in which the sorbent is in contact with (e.g., liquid communication).

Primary, secondary (1°,2°) alkylethylenediamine- and alkylpropylenediamine-appended variants of metal-organic framework are provided for CO.sub.2 capture applications. Increasing the size of the alkyl group on the secondary amine enhances the stability to diamine volatilization from the metal sites. Two-step adsorption/desorption profiles are overcome by minimzing steric interactions between adjacent ammonium carbamate chains. For instance, the isoreticularly expanded framework Mg.sub.2(dotpdc) (dotpdc.sup.4−=4,4″-dioxido-[1,1′:4′,1″-terphenyl]-3,3″-dicarboxylate), yields diamine-appended adsorbents displaying a single CO.sub.2 adsorption step. Further, use of the isomeric framework Mg-IRMOF-74-II or Mg.sub.2(pc-dobpdc) (pc-dobpdc.sup.4−=3,3-dioxidobiphenyl-4,4-dicarboxylate, pc=para-carboxylate) also leads to a single CO.sub.2 adsorption step with bulky diamines. By relieving steric interactions between adjacent ammonium carbamate chains, these frameworks enable step-shaped CO.sub.2 adsorption, decreased water co-adsorption, and increased stability to diamine loss. Variants of Mg.sub.2(dotpdc) and Mg.sub.2(pc-dobpdc) functionalized with large diamines such as N-(n-heptyl)ethylenediamine have utility as adsorbents for carbon capture applications.

A porous aluminum-based metal-organic framework (MOF) comprises inorganic aluminum chains linked via carboxylate groups of 1H-pyrazole-3,5-dicarboxylate (HPDC) linkers, and of formula: [Al(OH)(C.sub.5H.sub.2O.sub.4N.sub.2)(H.sub.2O)].

An organic polymer composition (OPC) comprising guanidinium-containing A units interconnected with B units of the formula *—R*).sub.r, wherein each asterisk (*) in A units denotes a connection point with an asterisk in B units; R is a hydrocarbon linking group containing at least one carbon atom; r is an integer of 1, 2, or 3; and the composition necessarily includes an anionic species X.sup.m− with a magnitude of charge m of at least 1, wherein the sum of negative charge provided by anionic species X.sup.m− counterbalances the total positive charge provided by the A units. Also described herein is a method for removing one or more oxoanions from an aqueous source by (i) contacting the aqueous source with the above described OPC to result in absorption of the oxoanion into the OPC to produce an oxoanion-containing OPC; and (ii) removing the oxoanion-containing OPC from the aqueous source.

A method of recycling superabsorbent polymers derived from a used absorbent article, the method including: treating the superabsorbent polymers with ozone water after inactivation; reactivating, with an alkaline aqueous solution, the superabsorbent polymers treated with the ozone water; and adding hydrophilic fine particles to the superabsorbent polymers reactivated with the alkaline aqueous solution and then drying the superabsorbent polymers.

An apparatus for capturing a water content from a water containing gas, the apparatus comprising: a housing having an inlet into which the water containing gas can flow; a water adsorbent located in the housing, the water adsorbent comprising at least one water adsorbent metal organic framework composite capable of adsorbing a water content from the water containing gas; and a water desorption arrangement in contact with and/or surrounding the water adsorbent, the water desorption arrangement being selectively operable between (i) a deactivated state, and (ii) an activated state in which the arrangement is configured to apply heat, a reduced pressure or a combination thereof to the water adsorbent to desorb a water content from the water adsorbent.

The present disclosure relates to molecularly imprinted polymers that target cannabinoid(s), including THC and CBD, as well as methods of making molecularly imprinted polymers that target cannabinoid(s), including THC and CBD and uses thereof.