The present invention relates to the field of solid materials for adsorption of lithium. In particular, the present invention relates to a novel method for preparing a crystallized and shaped solid material, preferably as extrudates, of formula LiX.sub.x.2Al(OH).sub.3, nH.sub.2O with n being comprised between 0.01 and 10, x being equal to 1 when X is an anion selected from among chloride, hydroxide and nitrate anions, and x being equal to 0.5 when X is an anion selected from among sulfate and carbonate anions, comprising a step a) for precipitation of boehmite under specific temperature and pH conditions, at least one shaping step, preferably by extrusion, said method also comprising a final hydrothermal treatment step, the whole giving the possibility of increasing the adsorption capacity for lithium as well as the adsorption kinetics of the materials obtained as compared with the materials of the prior art when the latter is used in a method for extracting the lithium from saline solutions.

The present invention discloses methods of regenerating apatite surfaces, for example after purification of a target analyte.

The invention relates to a process for the regeneration of an adsorber. For the regeneration a liquid stream (S2) comprising at least one alkane is converted from liquid phase into gaseous phase. Then the adsorber is regenerated and heated by contact with gaseous stream (S2) up to 230 to 270 C. Subsequently, the adsorber is cooled first by contact with gaseous stream (S2) to a temperature of 90 to 150 C. followed by cooling with liquid stream (S2) to a temperature below 80 C. The outflow of the adsorber (S2*) during the cooling with gaseous stream (S2) and optionally the outflow of the adsorber (S2*) during cooling with liquid stream (S2) is recycled in at least one of these steps.

An emissions control system including a fluidized bed apparatus containing a reactive sorbent material is disclosed for gaseous and non-gaseous contaminated emissions. The reactive sorbent material may be CZTS, CZTS-Alloy, or a carbon-based sorbent material. The fluidized bed apparatus is configured with one or more closed loop sorbent recycling subsystems. The sorbent recycling subsystems include the capability to separate sorbents from each other, separate contaminates from sorbents for disposal and/or recycling, clean and/or rejuvenate sorbents for return to the fluidized bed apparatus, dispose of spent and exhausted sorbents, and replace the spent and exhausted sorbents with new sorbent to maintain consistent sorbent function in the fluidized bed apparatus. Monitoring sensors provide information useful in a method for establishing and maintaining consistent process parameter controls.

An example method of removing hydrogen sulfide from an input gas includes exposing an adsorbent material to an input gas to obtain an output gas. A concentration of hydrogen sulfide of the output gas is less than a concentration of hydrogen sulfide of the input gas. The adsorbent material includes copper oxide, magnesium oxide, and aluminum oxide. An atomic ratio of copper to magnesium to aluminum of the adsorbent material is X:Y:Z, where X is greater than or equal to 0.6 and less than or equal to 0.9, where Y is greater than or equal to 0 and less than or equal to 0.2, where Z is greater than or equal to 0 and less than or equal to 0.2, and where X+Y+Z is equal to 1.

The disclosure relates to copper oxide-based sorbents, and processes for preparing and using them. The sorbents are preferably used to remove one or more sulfur species from gas streams. The sorbents comprise a porous silica support material impregnated with CuO nanoparticles. The nanoparticles are uniformly distributed throughout the porous silica support and sulfur compounds are adsorbed on the nanoparticles.

The present invention relates to a stabilized inorganic oxide support for capturing carbon dioxide from gases having high regeneration capacities over many cycles. The method for preparing the stabilized inorganic oxide support includes stabilizing an alumina-containing precursor by either calcining or steaming, impregnating an alkali or alkaline earth compound into the stabilized alumina-and drying the alkali or alkaline earth compound-impregnated stabilized alumina. The stabilized inorganic oxide support can be regenerated at lower temperatures between 100 and 150 C. The carbon dioxide adsorption capacity of the regenerated support is between 70 and 90% of the theoretical carbon dioxide adsorption capacity.

An oxygen adsorbent which can be manufactured at a low cost, and an oxygen manufacturing equipment and an oxygen manufacturing method which are capable of producing oxygen-enriched gas at a low cost by using the oxygen adsorbent are provided. The oxygen adsorbent comprises at least an oxide of a perovskite structure. The oxide is represented by a compositional formula of Sr.sub.1xCa.sub.xFeO.sub.3, wherein 0.12x0.40, 00.5. Since this oxide does not include La and Co included in a conventional oxygen adsorbent, it can be manufactured at a low cost.

A method for preparing a sorbent composition includes the steps of: applying, from a solution or a slurry, a layer of a copper compound on the surface of a support material, and drying the coated support material, wherein the thickness of the copper compound layer on the dried support is in the range 1-200 m.
The precursor may be converted to a sorbent suitable for removing heavy metals from liquids or gases by applying one or more sulphur compounds to sulphide the copper compound and form CuS.

Disclosed are compositions and methods for regenerating or reducing the deterioration of an apatite solid surface during, or subsequent to, a chromatographic procedure for purifying a target molecule from a sample, by treating the apatite solid surface with a buffered calcium solution, followed by a phosphate buffered solution, followed by an alkaline hydroxide. The buffered calcium solution, phosphate buffered solution, and alkaline hydroxide can be applied subsequent to a bind and elute or flow through purification procedure. The methods provide an increase in resin mass and/or particle strength compared to prior methods.