A detachable module for optionally recharging sorbent materials, including zirconium phosphate, with an optional bypass and conduits for a sorbent cartridge. The sorbent cartridge can have one or more modules contained therein having connectors connecting each of the modules. One or more of the modules can be reusable and the sorbent materials therein recharged.

An adsorbent having a microwave absorption property is provided. The adsorbent having an improved microwave absorption property, which has a core-shell structure including a silicon carbide bead disposed therein, and an adsorbing material disposed outside the silicon carbide bead, can be provided. Also, the adsorbent may further include a plurality of silicon carbide particles dispersed and disposed therein and having a diameter of 1 m to 10 m, and the adsorbing material may be ion-exchanged with a cation. Therefore, the adsorbent can be useful in improving desorption efficiency since the adsorbent may be rapidly heated by microwaves to reach the desorption temperature due to high reactivity to microwaves. Also, the adsorbent can be useful in maintaining full adsorption capacity without having an influence on adsorption quantity since the silicon carbide bead is disposed in the inner core of the adsorbent. Further, when the adsorbent is applied to conventional systems for removing organic compounds using microwaves or dehumidification systems, the adsorbent can be semi-permanently used, and may also have an effect of enhancing the energy efficiency by 30% or more, compared to adsorbents used in the conventional systems.

A process for the providing a regenerant gas stream for a regenerable adsorbent used to remove water and hydrogen sulfide from a reactor effluent in a catalytic dehydrogenation process is described. The reactor effluent is compressed in a compressor to provide a compressed effluent. The compressed effluent may be treated to remove chlorides, and then passed to a dryer zone having a regenerable adsorbent. A regenerant gas stream is used to desorb the water and hydrogen sulfide and the spent regenerant stream may be passed to a cleaning zone having a sorbent configured to remove hydrogen sulfide from the spent regenerant stream. The cleaned regenerant gas stream may be recycled to the dryer zone to desorb and/or regenerate the regenerable adsorbent.

An apparatus for removing contaminants from emissions is provided with a reverse venturi shaped fluidized bed device integrated into the system. The system includes numerous component devices such as, but not limited to, an influent source, a fluidized bed device, a post filter device, and an effluent discharge. The system may also include one or more application specific pre-filter and/or post filter devices. The fluidized bed is constructed with a specific length to diameter ratio for optimum restrictive flow through a specialized filter media. The filter media is a mass of reactive material disposed within the fluidized bed which is in intimate contact with the emissions, as the emissions pass through the fluidized bed. The mass of reactive material contains an amalgam forming metal which chemically binds with the emissions that are passing through the system. Methods for removing contaminants from gaseous and non-gaseous emissions are also provided.

The invention relates to a process for regeneration of an adsorber (A) by contact with a stream (S1), wherein the stream (S1) is heated in advance by at least two heat exchange units (HEU1) and (HEU2). As outflow of the adsorber (A) a stream (S2) is obtained, which is passed through at least two heat exchange units (HEU1) and (HEU2) traversed by stream (S1), wherein the temperature of stream (S2) fed into each heat exchange unit is higher than the temperature of stream (S1) fed into the heat exchange units (HEU1) and (HEU2), in order to directly transfer heat from stream (S2) to stream (S1).

Adsorption towers are filled with adsorbents that adsorb methane gas in coal mine gas and perform a PSA cycle. For each of adsorption towers, a plurality of different pressure states of the internal pressure of the adsorption tower are set as an intermediate pressure state. As a pressure equalization step, an initial pressure equalization step of transferring the gas in one of the adsorption towers that is in a high pressure state to another one of the adsorption towers that is in an intermediate pressure state, and a final pressure equalization step of transferring the gas in one of the adsorption towers that is in the high pressure-side intermediate pressure state to another one of the adsorption towers that is in the low pressure state are performed.

A module for optionally recharging sorbent materials in-line, including zirconium phosphate, with an optional bypass and conduits for a sorbent cartridge. The sorbent cartridge can have one or more modules contained therein having connectors connecting each of the modules. One or more of the modules can be reusable and the sorbent materials therein recharged.

Provided herein are water harvesting systems, as well as methods of making and using such systems, for capturing water from surrounding air using a design that reduces overall energy costs of the systems and improve water harvesting cycle efficiency. The systems and methods use sorbent materials, such as metal-organic frameworks, to adsorb water from the air. The systems and methods desorb this water in the form of water vapor, and the water vapor is condensed into liquid water and collected. The liquid water is suitable for use as drinking water.

The present disclosure relates to the recovery of an alkoxide catalyst used in a process depolymerizing a polyester to form a diacid or diester and a diol. The present disclosure also relates to the recovery of an alkoxide catalyst used in a process depolymerizing polyethylene terephthalate to form dimethyl terephthalate and mono ethylene glycol.

The present disclosure provides a process for recycling sorbent used in a process for extracting lithium from an aqueous solution containing lithium. The process may comprise bringing an aqueous solution containing lithium into contact with a hydrogen manganese oxide sorbent to absorb the lithium to produce a lithium loaded sorbent and lithium depleted solution, separating the lithium loaded sorbent and the lithium depleted solution, bringing the lithium loaded sorbent into contact with an acid to produce a lithium rich liquor and regenerated sorbent, separating the lithium rich liquor and the regenerated sorbent, treating the separated lithium rich liquor with a carbonate and/or hydroxide to precipitate manganese carbonate and/or manganese hydroxide, separating precipitated manganese carbonate and/or manganese hydroxide from the lithium rich liquor, and heating the manganese carbonate and/or manganese hydroxide with a source of lithium to produce a regenerated lithium loaded sorbent which is reused in the process. The disclosure also provides a system for recycling sorbent used in a process for extracting lithium from an aqueous solution containing lithium.