Disclosed are air-stable small-molecule adsorbents trimeric [Cu—Br].sub.3 and [Cu—H].sub.3 that undergo a reversible solid-state molecular rearrangements to [Cu—Br.(alkene)].sub.2 and [Cu—H.(alkene)].sub.2 dimers. The reversible solid-state rearrangement allows one to break adsorbent design trade-offs and achieve low heat of adsorption while retaining high selectivity and uptake.

An ammonia chemical species desorption process desorbs ammonia chemical species adsorbed onto a Prussian blue derivative more simply at lower cost under milder conditions as compared with using an aqueous solution of a salt or strong acid, and only water. This ammonia chemical species desorption process includes an ammonia chemical desorption step of bringing carbon dioxide and water into contact with a Prussian blue derivative represented by the following general formula (1), thereby desorbing an ammonia chemical species.

A.sub.xM[M′(CN).sub.6].sub.y.zH.sub.2O  (1)

where x is 0 to 3, y is 0.1 to 1.5, z is 0 to 6, A is at least one cation of hydrogen, ammonium, an alkaline metal, and an alkaline earth metal, and M and M′ are each independently at least one cation of at least one of atoms having atomic numbers 3 to 83 except for ammonium, an alkali metal, and an alkaline earth metal.

The disclosure generally relates to CCS sorbents, particularly for CO.sub.2/H.sub.2O displacement desorption process. The sorbents include an aluminum oxide support that includes two alkali metal salts impregnated on the support. The two alkali metals include a potassium metal salts and a second alkali metal salt which is not potassium. The second metal salt disrupts poisoning effects that degrade sorbent lifetime. The sorbents demonstrate improved CO.sub.2 loadings and better H.sub.2O/CO.sub.2 ratios, as well as improved stability. Compositions and methods of making are disclosed.

An adsorbent includes a porous substrate and a carboxylic acid dimer loaded onto the porous substrate. The carboxylic acid dimer is loaded on the surface or in the plurality of holes of the porous substrate. The average pore size of the porous substrate is not smaller than 2 nm. The carboxylic acid dimer is loaded onto the porous substrate by at least one of the following manners: a) the carboxylic acid dimer is loaded onto the porous substrate through a Si—OH bond; b) the carboxylic acid dimer is loaded onto the porous substrate through the exchange between a carboxyl group and chlorine; c) the carboxylic acid dimer is loaded onto the porous substrate through the exchange between a carboxyl group and a hydroxyl group; and d) the carboxylic acid dimer is loaded onto the porous substrate through the coordination of a carboxyl group and aluminum or silicon.

Described are gas storage medium and methods of storing source gases in the gas storage medium, particularly relating to using hydroxylated metal oxides or hydroxylated metalloid oxides as a storage medium for storing diborane.

A method for processing a nitrogen-containing starting gas mixture by vacuum pressure swing adsorption, in which the starting gas mixture is temporarily guided under pressure in a main flow direction through an adsorption unit filled with an adsorbent material. The adsorbent material is provided, in a first region along the main flow direction, predominantly or exclusively in the form of first adsorption bodies; the adsorbent material is provided, in a second region along the main flow direction and downstream of the first region in the form of second adsorption bodies; that at least the second adsorption bodies are provided as composite bodies that have an inner core of a non-porous, non-adsorbent material and an outer layer formed from the adsorbent material; and that the second adsorption bodies have a lower proportion of the adsorbent material, in the body volume, than the first adsorption bodies.

An apparatus for capturing a water content from a water containing gas, the apparatus comprising: a housing having an inlet into which the water containing gas can flow; a water adsorbent located in the housing, the water adsorbent comprising at least one water adsorbent metal organic framework composite capable of adsorbing a water content from the water containing gas; and a water desorption arrangement in contact with and/or surrounding the water adsorbent, the water desorption arrangement being selectively operable between (i) a deactivated state, and (ii) an activated state in which the arrangement is configured to apply heat, a reduced pressure or a combination thereof to the water adsorbent to desorb a water content from the water adsorbent.

The invention is directed to ion capture devices and methods for ion capture.

Disclosed in certain embodiments are sorbents for capturing heavy hydrocarbons via thermal swing adsorption processes.

The invention relates to a non-corrosive process for cleaning a recyclable material comprising the following steps: (a) providing a contaminated recyclable material; (b) treating the contaminated recyclable material at a temperature in the range of from 45-30° C. with a solution that contains one or more polyols to remove contaminants from the contaminated recyclable material, wherein the one or more polyols is (are) present in an amount of at least 15 wt. %, based on the total weight of the solution, thereby forming a liquid 10 mixture which comprises one or more polyols, contaminants removed from the recyclable material, and treated recyclable material; (c) separating at a temperature in the range 10-55° C. at least part of the recyclable material as obtained in step (b) from the liquid mixture as obtained in step (b); (d) allowing at least part of the remaining liquid mixture as obtained in step (c) to phase-1 separate into a polyol phase and a phase which contains contaminants removed from the contaminated recyclable material; (e) recovering the polyol phase as obtained in step (d); (f) recovering the phase which contains contaminants removed from the recyclable material as obtained in step (d); and 20 (g) recovering the separated recyclable material as obtained in step (c).