The present invention relates to an organic-inorganic hybrid nanoporous material, maintaining a nanoporous skeleton structure formed by coordination of an organic ligand containing an aromatic compound to a trivalent central metal ion, and further having an intramolecular acid anhydride functional group modified on the aromatic compound of the nanoporous skeleton structure, and thereby exhibits selectivity for olefins, and an adsorbent comprising the same. Specifically, the organic-inorganic hybrid nanoporous material of the present invention exhibits an excellent olefin-selective adsorption capacity through differences in adsorption equilibrium and adsorption rate, and thus can be usefully employed in the separation of C2-C4 hydrocarbons. Further, the olefins adsorbed to the organic-inorganic hybrid nanoporous material can be desorbed by purging of an inert gas which is not liquefied by way of mild vacuum conditions or compression, and thus, the organic-inorganic hybrid nanoporous material can be used to prepare olefins by separating C2-C4 hydrocarbon mixtures.

Embodiments of the present disclosure describe a method of capturing chemical species from a fluid composition comprising providing a metal-organic framework characterized by the formula M.sub.aM.sub.bF.sub.5(O/H.sub.2O)(pyrazine).sub.2.x(solv), wherein M.sub.a is Ni.sup.2+; M.sub.b is Nb.sup.5+, Al.sup.3+, or Fe.sup.3+; x is from 0 to 10 and solv is one or more of H.sub.2O, CO.sub.2, DMF, EtOH, NMP, MeOH; contacting the metal-organic framework with a fluid composition including H.sub.2O, CO.sub.2, and one or more other chemical species; and capturing H.sub.2O and CO.sub.2 simultaneously from the fluid composition.

A solid sorbent composition including calcium oxide, calcium aluminate, and a mixed metal oxide characterized by a perovskite crystalline structure, for example, lanthanum aluminate. The solid sorbent finds utility in capturing carbon dioxide from a gaseous stream containing carbon dioxide, such as emissions streams produced in combustion processes or streams derived from closed environments including airplanes, spaceships, and submarines. A reversible carbon dioxide process is disclosed involving (a) contacting a carbon dioxide-containing gaseous stream with the solid sorbent composition in a carbonator to produce a solid mixture containing calcium carbonate and a gaseous product stream reduced in carbon dioxide concentration; and (b) heating the solid mixture containing calcium carbonate in a calcinator (decarbonator) to regenerate the solid sorbent composition and produce a gaseous stream enriched in carbon dioxide.

Systems and methods for an atmospheric carbon dioxide removal system that includes a plurality of carbon capture containers, a plurality of fans, an air diverter, and a velocity stack. Each of the carbon capture containers has an outwardly facing side and an inwardly facing side with the inwardly facing side facing an enclosed space. The fans are disposed adjacent to the carbon capture containers. The fans are arranged to move air through the carbon capture containers in a first direction from the outwardly facing side into the enclosed space. The air diverter is disposed within the enclosed space and receives the air flowing in the first direction and redirects the air to flow in a second direction that is angled upwardly from the first direction. The velocity stack is disposed on top of the enclosed space and is configured to accelerate the flow of the air in the second direction.

A use of organofunctionalized mesoporous silica for the production of recycled paper; the organofunctionalized mesoporous silica comprises a base mesoporous silica having, on its surface, groups having the following general formula (I), wherein Si.sup.1 is a silicon atom of the base mesoporous silica, R.sup.1 is a C.sub.1-C.sub.5 aliphatic; R.sup.2 is chosen in the group consisting of: a C.sub.1-C.sub.5 aliphatic and an oxygen atom bound with a silicon atom of the base mesoporous silica; and R.sup.3 is chosen in the group consisting of: a hydroxyl, a C.sub.1-C.sub.5 aliphatic and an oxygen atom bound with a silicon atom of the base mesoporous silica (I). ##STR00001##

The present disclosure includes a process for pelletizing a spent bleach earth (SBE) into a clay-biocarbon composite including classifying the SBE based on at least one parameter of the SBE, selecting at least one filler compound and mixing the at least one filler compound with the SBE to make a mixture, forming a plurality of pellets out of the mixture, and pyrolyzing the pellets to produce the clay-biocarbon composite. Pyrolyzing a pelleted spent bleach earth (SBE) may include advancing the pelleted SBE with a distributer to a first thermal chamber for providing even thermal processing, releasing the pelleted SBE to a second auger to cool to room temperature, and condensing at least one volatile compound emitted from the pelleted SBE during thermal processing to produce a condensate for reuse.

The invention relates to a gas treatment monolith article, said gas treatment article comprising: a full body porous material comprising a porous substrate and an aluminium oxide coating homogeneously distributed throughout said porous substrate, wherein said porous substrate is a fibrous material; and at least one acid gas absorption active component or a precursor thereof impregnated into said porous aluminium oxide coated substrate. The invention further relates to uses of the gas treatment monolith article of the invention.

The present invention relates to methods for the preparation of pellets of sorbent suitable for carbon dioxide capture, to said pellets of sorbent, and to the use of said pellets of sorbent in carbon dioxide capture.

A method of controlling an apparatus that removes specified substances from a process gaseous stream can control at least one fan and a rotary wheel that removes the specified substances. The method includes measuring a pressure difference of the process gaseous stream across upstream and downstream sides of the rotary wheel, comparing the measured pressure difference to a predetermined pressure range, and controlling the at least one fan to increase or decrease its speed if the measured pressure difference is outside of the predetermined pressure range so as to change the pressure difference so as to be within the predetermined pressure range.

Metal-organic frameworks for capturing one or more of SO.sub.2, CO.sub.2, and H.sub.2O are disclosed herein. Non-limiting examples of metal-organic frameworks include NbOFFIVE-1-Ni and AlFFIVE-1-Ni, among others. The metal-organic frameworks can be used in applications for removing and/or sensing one or more of SO.sub.2, CO.sub.2, and H.sub.2O from a fluid composition or an environment, either of which can proceed under dry or humid conditions and/or at room temperature.