Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H.sub.2S, H.sub.2O, and CO.sub.2. Methods include capturing one or more of H.sub.2S, H.sub.2O, and CO.sub.2 from fluid compositions, such as natural gas.

A permanently porous vanadium(II)-containing metal-organic framework (MOF) withvanadium(II) centers and methods for synthesis of such MOF frameworks are provided. Methods for using such compounds to selectively react with N.sup.2 over CH.sub.4 are provided. In the synthetic methods, a vanadium source, such as VY.sub.2(tmeda).sub.2, where Y is a halogen and tmeda is N,N,N,N-tetramethylethane-1,2-diamine and a H.sub.2(ligand) are reacted in the presence of acid in a solvent at between 110 C. and 130 C. to form an intermediate product. The intermediate product is collected and washed with a washing agent, such as DMF and acetonitrile, and the vanadium(II) based MOF is activated by heating the washed intermediate product to at least 160 C. under dynamic vacuum.

The present invention relates to an adsorption process for xenon recovery from a cryogenic liquid or gas stream wherein a bed of adsorbent is contacted with a xenon-containing liquid or gas stream selectively adsorbing the xenon from said stream. The adsorption bed is operated to at least near full breakthrough with xenon to enable a deep rejection of other stream components, prior to regeneration using the temperature swing method. After the stripping step, the xenon adsorbent bed is drained to clear out the liquid residue left in the nonselective void space and the xenon molecules in those void spaces is recycled upstream to the ASU distillation column for increasing xenon recovery. The xenon adsorbent bed is optionally purged with oxygen, followed by purging with gaseous argon at cryogenic temperature (160 K) to displace the oxygen co-adsorbed on the AgX adsorbent due to higher selectivity of argon over oxygen on the AgX adsorbent. By the end of this step, the xenon adsorbent bed is filled with argon and xenon. Then the entire adsorbent bed is heated indirectly without utilizing any of the purge gas for direct heating. Operating the adsorption bed to near full breakthrough with xenon and displacing the adsorbed oxygen and other residues with argon, prior to regeneration, along with indirect heating of the bed, enables production of a high purity product 40 vol % xenon from the adsorption bed and further enables safely heating without any purge gas and ease for downstream product collection, even in cases where hydrocarbons are co-present in the feed stream.

A method is disclosed for removing ozone from a gas. According to this method, the gas is contacted with an adsorbent that includes a transition metal oxide or metal organic framework to form a treated gas. The treated gas is contacted with a noble metal catalyst to catalytically decompose ozone in the treated gas, thereby forming an ozone-depleted treated gas.

A system and method for synthesizing a nanoparticle material includes dissolving a metal nitrate in deionized water, adding a hydrogel precursor in the deionized water containing the dissolved metal nitrate to create an aqueous solution, heating the aqueous solution, cooling the aqueous solution to create a solid gel, and calcinating the solid gel to create a metal oxide nanoparticle material. The metal oxide nanoparticle material may include a zinc oxide-based nanoparticle material. The hydrogel precursor may include an agarose gel. The solid gel may be calcinated at approximately 600 C. The solid gel may be calcinated for approximately five hours in the presence of air. The aqueous solution may be heated to a boil. The aqueous solution may be heated at a temperature of 100 C.

Methods of drying streams that include propylene oxide. The methods may include contacting a stream that includes propylene oxide with molecular sieves. The molecular sieves may be in a drying unit, and may be regenerated. The streams that include propylene oxide may include one or more other organic compounds.

An apparatus for capturing a water content from a water containing gas, the apparatus comprising: a housing having an inlet into which the water containing gas can flow; a water adsorbent located in the housing, the water adsorbent comprising at least one water adsorbent metal organic framework composite capable of adsorbing a water content from the water containing gas; and a water desorption arrangement in contact with and/or surrounding the water adsorbent, the water desorption arrangement being selectively operable between (i) a deactivated state, and (ii) an activated state in which the arrangement is configured to apply heat, a reduced pressure or a combination thereof to the water adsorbent to desorb a water content from the water adsorbent.

A hydrocarbon adsorbent, according to one embodiment of the present invention, comprises a copper-containing ZSM-5 zeolite, wherein a Si/Al molar ratio of the ZSM-5 zeolite may be 11.5 to 40, and the amount of the copper included is 1 wt % to 10 wt %.

The present disclosure relates to systems and methods of making ammonia using stable ammonia absorbents. The system and method for producing ammonia, comprises a reactor comprising a catalyst that converts at least a portion of nitrogen feed gas and at least a portion of hydrogen feed gas to ammonia (NH3) forming a reaction mixture comprising the ammonia, unreacted nitrogen, and unreacted hydrogen. An absorber configured to selectively absorb ammonia from the reaction mixture at a temperature of about 180 deg. C. to 330 deg. C. and a pressure of about 1-20 bar, the absorber comprising a solid absorbent. Preferably the solid absorbent is at least one metal halide and a solid support. The unabsorbed ammonium, the unreacted nitrogen, and unreacted hydrogen gas are recycled to the reactor.

The present invention relates to a porous material in which at least the pores of the porous material are lined with nanoparticles capable of treating fluids or fluid mixtures that pass through the pores of the porous material and whose treating properties can be fully reinstated through heating the porous material.