An adsorption material is disclosed that comprises a metal-organic framework and a plurality of ligands. The metal-organic framework comprising a plurality of metal ions. Each respective ligand in the plurality of ligands is amine appended to a respective metal ion in the plurality of metal ions of the metal-organic framework. Each respective ligand in the plurality of ligands comprises a substituted 1,3-propanediamine. The adsorbent has a CO.sub.2 adsorption capacity of greater than 2.50 mmol/g at 150 mbar CO.sub.2 at 40° C. Moreover, the adsorbent is configured to regenerate at less than 120° C. An example ligand is diamine 2,2-dimethyl-1,3-propanediamine. An example of the metal-organic framework is Mg.sub.2(dobpdc), where dobpdc.sup.4− is 4,4′-dioxidobiphenyl-3,3′-dicarboxylate. Example applications for the adsorption material are removal of carbon dioxide from flue gas and biogasses.

Disclosed are metal organic frameworks (MOFs) for adsorbing guest species, methods for the separation of gases using the MOFs, and systems comprising the MOFs. The MOFs comprise a plurality of secondary building units (SBUs), each SBU comprising a repeating unit of one metal cation connected to another metal cation via a first moiety of an organic linker; a layer of connected adjacent SBUs in which a second moiety of the linker in a first SBU is connected to a metal cation of an adjacent SBU, and wherein adjacent layers are connected to each other via linker-to-linker bonding interactions

The present invention relates to a device for the reversible adsorption of carbon dioxide from a gas mixture, comprising at least one adsorbent vessel comprising one or a plurality of gas permeable cartridge vessels of an inert and dimensionally stable material, and each cartridge comprising a suitable polymeric particular adsorbent having a primary amino functionality; to an arrangement including the device, and to a method for adand desorption of carbon dioxide.

A method and apparatus for removing water from compressed air is disclosed. The method includes the steps of passing a stream of compressed air through a pressure swing adsorption (PSA) dryer. The dryer includes at least one vessel containing a desiccant material bound into pieces, for example tubes, using a polymer binder. The PSA dryer also has a control system for controlling the flow of the compressed air and switching between drying and purging modes. In particular the vessel and desiccant material contained therein are sized to produce a dew point suppression of less than 50° C.

Provided is an oxygen concentration device which, as an oxygen concentration device having a reduced difference in flow rates of gas which flows through a pressure equalization valve of a pressure equalization path during a purge step and a pressure equalization step, is provided at at least one end side of the pressure equalization valve with a pressure control member having a difference in pressure loss due to the direction of gas flow so that pressure loss of the gas which flows through the pressure equalization path in one direction becomes nearly equal to that of the gas which flows therethrough in the opposite direction.

The rate of recovery of a purification target gas from a gas purification apparatus that uses a PSA device is improved, and both a high purity and a high recovery rate are achieved with good power efficiency. The present invention is directed to a gas purification method using the PSA method, in which a carbon molecular sieve having a pore volume, at a pore diameter of 0.38 nm or more, of not exceeding 0.05 cm.sup.3/g and a pore volume, at a pore diameter of 0.34 nm, of 0.15 cm.sup.3/g or more, in a pore diameter distribution measured by the MP method is used as an adsorbent, and, in an adsorption step, a miscellaneous gas is adsorbed from a source gas by bringing the source gas into contact with the adsorbent for 10 seconds or more and 6000 seconds or less so as to obtain a concentrated methane.

The present invention relates to an adsorbent comprising an alumina support and at least one alkali element, said adsorbent being obtained by introducing at least one alkali element, identical to or different from sodium, onto an alumina support the sodium content of which, expressed as Na.sub.2O equivalent, before the introduction of the alkali element or elements, is comprised between 1000 and 5000 ppm by weight with respect to the total weight of the support. The invention also relates to processes for the preparation of said adsorbent and use thereof in a process for the elimination of acidic molecules such as COS and/or CO.sub.2.

The present invention relates to a process for purification of a carbon dioxide feedstock, for example from a production well, which comprises carbon dioxide and gaseous and liquid C.sub.1+ hydrocarbons. Specifically, a carbon dioxide feedstream is passed through one or more separation unit wherein each separation unit removes one or more C.sub.1+ hydrocarbon from the carbon dioxide feedstream to provide a richer carbon dioxide gas stream. The process comprises one or more separation unit which employs an adsorption media and has an adsorption step and a media regeneration step wherein the regeneration step may be operated as a batch process, a semi-continuous process, or a continuous process. One embodiment of this method provides for the use of a different regenerable adsorbent media in two or more separation units.

Composite materials and methods of preparing C0.sub.2 capture include: (1) a porous solid support comprising a plurality of porous channels; and (2) a nucleophilic source associated with the porous channels of the porous solid support. The nucleophilic source is capable of converting the captured C0.sub.2 to poly(C0.sub.2). Methods of capturing C0.sub.2 from an environment include associating the environment with the aforementioned composite materials to lead to the capture of C0.sub.2 from the environment. Such methods may also include a step of releasing the captured C0.sub.2 from the composite material. The associating step comprises a conversion of the captured C0.sub.2 to poly(C0.sub.2) in the composite material. A releasing step may also include a depolymerization of the formed poly(C0.sub.2).

A mixed salt composition adapted for use as a sorbent for carbon dioxide removal from a gaseous stream is provided, the composition being in solid form and including magnesium oxide, an alkali metal carbonate, and an alkali metal nitrate, wherein the composition has a molar excess of magnesium characterized by a Mg:X atomic ratio of at least about 3:1, wherein X is the alkali metal. A process for preparing the mixed salt is also provided, the process including mixing a magnesium salt with a solution comprising alkali metal ions, carbonate ions, and nitrate ions to form a slurry or colloid including a solid mixed salt including magnesium carbonate; separating the solid mixed salt from the slurry or colloid to form a wet cake; drying the wet cake to form a dry cake including the solid mixed salt; and calcining the dry cake to form a mixed salt sorbent.