Oxidative dehydrogenation catalysts comprising MoVNbTeO having improved consistency of composition and a 25% conversion of ethylene at less than 420° C. and a selectivity to ethylene above 95% are prepared by treating the catalyst precursor with H.sub.2O.sub.2 in an amount equivalent to 0.30-2.8 mL H.sub.2O.sub.2 of a 30% solution per gram of catalyst precursor prior to calcining and treating the resulting catalyst with the equivalent amount of peroxide after calcining.

Oxidative dehydrogenation catalysts comprising MoVNbTeO having improved consistency of composition and a 25% conversion of ethylene at less than 420° C. and a selectivity to ethylene above 95% are prepared by treating the catalyst precursor with H.sub.2O.sub.2 in an amount equivalent to 0.30-2.8 mL H.sub.2O.sub.2 of a 30% solution per gram of catalyst precursor prior to calcining and treating the resulting catalyst with the equivalent amount of peroxide after calcining.

Disclosed are a bifunctional catalyst and a preparation method therefor, the bifunctional catalyst being suitable to produce high-value aromatic hydrocarbons by subjecting alkylaromatic hydrocarbons to a disproportionation/transalkylation/dealkylation reaction while suppressing aromatic loss or subjecting C8 aromatic hydrocarbons to an isomerization reaction while suppressing xylene loss.

Provided is a molybdenum sulfide that is ribbon-shaped and particularly suitable for a hydrogen generation catalyst. Disclosed are a ribbon-shaped molybdenum sulfide, in which 50 particles as measured by observation with a scanning electron microscope (SEM) have a shape of, on average, 500 to 10000 nm in length, 10 to 1000 nm in width, and 3 to 200 nm in thickness; a method for producing the ribbon-shaped molybdenum sulfide, including: (1) heating a molybdenum oxide at a temperature of 200 to 1000° C. in the presence of a sulfur source; or (2) heating a molybdenum oxide at a temperature of 100 to 800° C. in the absence of a sulfur source, and then heating the molybdenum oxide at a temperature of 200 to 1000° C. in the presence of a sulfur source; and a hydrogen generation catalyst including the ribbon-shaped molybdenum sulfide.

A process and catalyst are provided for the non-oxidative dehydrogenation of propane for the production of propylene as petrochemical building blocks. The process provides a direct single-step gas-phase dehydration of propane mixed with nitrogen in the presence and absence of steam/hydrogen over supported bimetallic alumina-silicates zeolites. The catalyst contains no precious metal entities and may contain one metal from group VIB in combination with another metal from group IIIA or IVA supported on FAU, MFI, KFI, BEA type alumina-silicates zeolites. The process provides a propane conversion of 18% to 52% with a propylene yield of 10% to 25%.

A process and catalyst are provided for the non-oxidative dehydrogenation of propane for the production of propylene as petrochemical building blocks. The process provides a direct single-step gas-phase dehydration of propane mixed with nitrogen in the presence and absence of steam/hydrogen over supported bimetallic alumina-silicates zeolites. The catalyst contains no precious metal entities and may contain one metal from group VIB in combination with another metal from group IIIA or IVA supported on FAU, MFI, KFI, BEA type alumina-silicates zeolites. The process provides a propane conversion of 18% to 52% with a propylene yield of 10% to 25%.

A process for producing an unsupported molybdenum sulfide nanocatalyst comprising atomizing a molybdenum oxide solution to form a molybdenum oxide aerosol, pyrolyzing the molybdenum oxide aerosol with a laser beam to form the unsupported molybdenum-based nanocatalyst, and pre-sulfiding at least a portion of the unsupported molybdenum-based nanocatalyst to form an unsupported molybdenum sulfide nanocatalyst, wherein the unsupported molybdenum-based nanocatalyst, the unsupported molybdenum sulfide catalyst or both are in the form of nanoparticles with a diameter of 1-10 nm and in a distorted rutile crystalline structure. A method of selective deep hydrodesulfurization whereby a hydrocarbon feedstock having at least one sulfur-containing component and at least one hydrocarbon is contacted with the unsupported molybdenum sulfide nanocatalyst.

A process for producing a polyetheramine by reacting a polyether alcohol, previously synthesized in the presence of a basic potassium or sodium compound as catalyst, with ammonia in the presence of hydrogen and a catalyst in one reactor or a plurality of reactors, wherein the employed polyether alcohol when previously synthesized in the presence of a basic potassium compound as catalyst has a content of potassium ions of less than 50 wppm and when previously synthesized in the presence of a basic sodium compound as catalyst has a content of sodium ions of less than 50 wppm.

A process for producing a polyetheramine by reacting a polyether alcohol, previously synthesized in the presence of a basic potassium or sodium compound as catalyst, with ammonia in the presence of hydrogen and a catalyst in one reactor or a plurality of reactors, wherein the employed polyether alcohol when previously synthesized in the presence of a basic potassium compound as catalyst has a content of potassium ions of less than 50 wppm and when previously synthesized in the presence of a basic sodium compound as catalyst has a content of sodium ions of less than 50 wppm.

The invention concerns a process for the preparation of a catalyst for carrying out hydrogenation reactions in hydrotreatment and hydrocracking processes. Said catalyst is prepared from at least one mononuclear precursor based on molybdenum (Mo), in its monomeric or dimeric form, having at least one Mo═O or Mo—OR bond or at least one Mo═S or Mo—SR bond where [R=C.sub.xH.sub.y where x≧1 and (x−1)≦y≦(2x+1) or R=Si(OR′).sub.3 or R=Si(R′).sub.3 where R′=C.sub.x′H.sub.y′ where x′≧1 and (x′−1)≦y′≦(2x′+1)], and optionally from at least one promoter element from group VIII. Said precursors are deposited onto an oxide support which is suitable for the process in which it is used, said catalyst being dried at a temperature of less than 200° C. then advantageously being sulphurized before being deployed in said process.