Provided is a method of producing a catalyst-bearing support that produces a catalyst-bearing support used in production of a fibrous carbon nanostructure. The production method includes: a stirring step of rotating an approximately circular tube-shaped rotary drum around a central axis so as to stir a particulate support; a spraying step of spraying a catalyst solution against the particulate support inside of the rotary drum; and a drying step causing a drying gas to flow to inside of the rotary drum from outside of the rotary drum so as to dry catalyst solution attached to the particulate support. In this production method, at least part of an implementation period of the stirring step and at least part of an implementation period of the spraying step overlap with each other.

Provided is a method of producing a catalyst-bearing support that produces a catalyst-bearing support used in production of a fibrous carbon nanostructure. The production method includes: a stirring step of rotating an approximately circular tube-shaped rotary drum around a central axis so as to stir a particulate support; a spraying step of spraying a catalyst solution against the particulate support inside of the rotary drum; and a drying step causing a drying gas to flow to inside of the rotary drum from outside of the rotary drum so as to dry catalyst solution attached to the particulate support. In this production method, at least part of an implementation period of the stirring step and at least part of an implementation period of the spraying step overlap with each other.

A method for preparing a transition metal electrochemical catalyst according to an embodiment of the present disclosure includes dissolving a nitrogen precursor and a transition metal precursor in a polyol-based solvent so as to prepare a solution in which transition metal ions and free anions are coordinated, and mixing same with a support so as to prepare a mixture, igniting the mixture so as to carbonize the polyol-based solvent, thereby forming transition metal nanoparticles encompassed by carbon, performing heat treatment in order to carbonize remaining organic matter contained in the mixture, and removing, through acid treatment, impurities and transition metal nanoparticles not encompassed by carbon, and then removing remaining acid through washing and additional heat treatment, thereby a nanocatalyst having a structure in which a single-atom transition metal-nitrogen bonding structure and/or transition metal nanoparticles encompassed by carbon exist is synthesized.

This invention is related to an additive composition comprising metal-based quantum clusters (QCs) dispersed in a hydrocarbon medium. The additive composition is useful as a fuel additive, as it acts as a combustion improver for liquid and gaseous fuels. The invention describes a process for the synthesis of the additive composition comprising metal-based materials in atomic cluster form in hydrocarbon dispersible medium. The stable liquid dispersion of the QC has been doped into the hydrocarbon fuels at required concentrations. The measurable flame temperature of the fuels, e.g., commercial LPG on burner has been observed to increase by at least 60-80° C. The flame with high heat through put can be used for efficient cooking, heating, annealing and other high thermal applications. The additive composition may also be used to improve the fuel economy of the liquid hydrocarbon fuels.

A method of fabricating a carbon nanotube (“CNT”) array includes providing a substrate with a CNT catalyst disposed on a surface of the substrate, heating the CNT catalyst to an annealing temperature, exposing the CNT catalyst to a CNT precursor for an exposure period to pre-load the CNT catalyst, and exposing the pre-loaded CNT catalyst to a carbon source for a growth period to form the CNT array. The formed CNT array comprises a plurality of CNT bundles that are aligned with one another in an alignment direction. At least one of the plurality of bundles comprises an average structural factor of 1.5 or less along an entirety of the length thereof.

A method of fabricating a carbon nanotube (“CNT”) array includes providing a substrate with a CNT catalyst disposed on a surface of the substrate, heating the CNT catalyst to an annealing temperature, exposing the CNT catalyst to a CNT precursor for an exposure period to pre-load the CNT catalyst, and exposing the pre-loaded CNT catalyst to a carbon source for a growth period to form the CNT array. The formed CNT array comprises a plurality of CNT bundles that are aligned with one another in an alignment direction. At least one of the plurality of bundles comprises an average structural factor of 1.5 or less along an entirety of the length thereof.

Aspects of the present disclosure generally relate to copper-containing bimetallic structures, to processes for producing the copper-containing bimetallic structure, and to uses of the copper-containing bimetallic structures as, e.g., catalysts. In an aspect, a process for forming a bimetallic structure is provided. The process includes forming a mixture comprising a first precursor and a second precursor, the first precursor comprising copper, the second precursor comprising a phosphine. The process further includes introducing a third precursor with the mixture to form the bimetallic structure, the third precursor comprising a Group 8-10 metal, the bimetallic structure comprising copper (Cu), the Group 8-10 metal (M), phosphorous (P), and nitrogen (N), the bimetallic structure having the formula (Cu).sub.a(M).sub.b(P).sub.c(N).sub.d, wherein a molar ratio of a:b is from about 1:99 to about 99:1, and a molar ratio of a:(c+d) is from about 500:1 to about 1:1.

A method for preparing a silicate/carbon composite from attapulgite, and use of the silicate/carbon composite are disclosed. The preparation method includes: (1) with attapulgite as a raw material, preparing SiO.sub.2 with a special structure; (2) dispersing the prepared SiO.sub.2 in water to obtain a suspension, and subjecting the suspension to ultrasonic dispersion; dissolving a metal nitrate in the suspension, adding NH.sub.4Cl, and adding ammonia water dropwise to the suspension; and adding sucrose to obtain a suspension; (3) subjecting the suspension to microwave hydrothermal reaction; after the reaction is completed, centrifuging a resulting system; and separating a resulting solid; and (4) subjecting the solid to high-temperature calcination in a muffle furnace, and grinding a resulting product to obtain the silicate/carbon composite, which can be used in photocatalytic ammonia synthesis.

An ionic liquid catalyst and a method for manufacturing the same are provided. The ionic liquid catalyst includes a carrier. The carrier contains nickel ferrite as a component, and an outer surface of the carrier is modified to have a decolorant and a degradation agent. The decolorant is grafted onto nickel atoms of the carrier, and the degradation agent is grafted onto iron atoms of the carrier. The method includes: providing the carrier that contains nickel ferrite as a component; and modifying the carrier, so that the nickel atoms of the carrier are grafted with the decolorant and the iron atoms of the carrier are grafted with the degradation agent. Accordingly, the ionic liquid catalyst is obtained.

The present disclosure belongs to the field of single-atom catalytic degradation of refractory organic pollutants, and provides a single-atom catalyst for activation of persulfate to generate pure singlet oxygen (1O2) as well as a preparation method and an application thereof. The single-atom catalyst of the present disclosure includes supports and single iron atoms loaded on the support; the supports are graphitic carbon nitride nanosheets; the single iron atoms are bound to the supports in the form of a Fe—N4 coordination structure. The present disclosure employs graphitic carbon nitride nanosheets as the supports, so that the single iron atoms have a uniform surrounding environment and the persulfate is only converted into 1O2 when being activated; 1O2 has good selectivity and anti-interference ability, so the single-atom catalyst provided in the present disclosure may have excellent selectivity and anti-interference performance in the degradation of organic pollutants.