Summary

The present application relates to a catalyst for hydrogen evolution reaction (HER) including a transition metal matrix and noble metal atoms formed in the transition metal matrix, in which the noble metal atoms have oxygen adsorbed thereto, and oxygen is derived from the transition metal matrix.

Proposed are a photocatalyst, including titanium dioxide particles including titanium dioxide (TiO.sub.2), a carbon material located on all or part of the surface of the titanium dioxide particles and including at least one selected from the group consisting of graphene, reduced graphene oxide (rGO), and carbon nanotubes (CNTs), and bimetallic nanoparticles supported on the carbon material and including first metal nanoparticles and second metal nanoparticles, and a water treatment method using the same. In the photocatalyst and the water treatment method using the same, the photocatalyst including bimetallic nanoparticles and graphene oxide is prepared, thereby exhibiting high reduction efficiency and high selectivity to nitrogen gas even without the use of an external electron donor.

The invention is directed to a CO to CO.sub.2 combustion promoter comprising microsphere sized porous silica and/or alumina comprising particles further comprising on or more Group VIII noble metals wherein the noble metal is distributed in the particle as an eggshell such that a higher content of noble metal is present in the outer region of the particle as compared to the content of noble metal in the center of the particle.

The present invention provides a cerium dioxide-supported low-dose PtCu ultrafine alloy catalyst, a preparation method and an application thereof, which belongs to the fields of environmental catalysis and preparation of catalyst materials. Metal-state PtCu ultrafine alloy particles are prepared by an oleylamine method, and then a cerium dioxide support is immersed into an n-butylamine solution of PtCu ultrafine alloy, centrifuged, washed with alcohol, and dried to obtain the cerium dioxide-supported low-dose PtCu ultrafine alloy catalyst. The catalyst obtained has excellent activity and stability in simultaneously degrading atmospheric VOCs and soot under a photothermocatalytic condition. There are the characteristics of simple preparation process method, very low Pt dosage, high utilization rate, and excellent photothermocatalytic performance.

In some aspects and embodiments, the present application provides a wide range of porous 1-D polymeric graphitic carbon-nitride materials that are atomically doped with binary metals in different morphologies. In some embodiments, the graphitic carbon-nitride materials can be prepared with high mass production from inexpensive and natural abundant precursors. In some embodiments, the materials were used successfully for the oxidation of CO to CO.sub.2 under ambient reaction temperature in addition to the reduction of CO.sub.2 into hydrocarbons. In some embodiments, the materials can be used for practical and large-scale gas conversion for household or industrial applications.

A copper-palladium-loaded mesoporous silicon carbide-based catalyst, a preparation method, and an application thereof are provided. First, a mesoporous silicon carbide material is prepared by using mesoporous silica as a hard template; subsequently, the mesoporous silicon carbide material is mixed with a copper-palladium precursor mixed solution, and dried after the solvent is completely volatilized. The dried powder is successively subjected to calcination with N.sub.2 and reduction with H.sub.2 to finally obtain the copper-palladium-loaded mesoporous silicon carbide-based catalyst. The catalyst is made into an electrode, and the nitrate in water body is catalytically reduced by electrochemical method. The preparation method of the catalyst of the present invention is simple. The catalyst can realize high-efficiency catalytic denitrification at a low metal loading amount, with high selectivity of nitrogen. Moreover, the catalyst has the advantages of high activity, good stability, wide application range and low cost.

Disclosed is a catalyst useful for producing organic amines by catalytic amination, its preparation and application thereof, wherein the catalyst comprises an inorganic porous carrier containing aluminum and/or silicon and an active metal component supported on the carrier, the active metal component comprises at least one metal selected from the group consisting of Group VIII and Group IB metals, and the carrier has an ammonia adsorption capacity of 0.25 to 0.65 mmol/g, as measured by NH.sub.3-TPD test. The catalyst has an improved performance, when used for producing organic amines by catalytic amination.

In relation to a Cu-based delafossite-type oxide that is effective as an exhaust gas purification catalyst, Cu is placed in a high catalytic activity low-valence state, whereby a novel Cu-based delafossite-type oxide having higher activity than in the past is provided. Proposed is a delafossite-type oxide for an exhaust gas purification catalyst that is represented by a general formula ABO.sub.2, wherein Cu and Ag are contained in the A site of the general formula, one or two or more elements selected from the group consisting of Mn, Al, Cr, Ga, Fe, Co, Ni, In, La, Nd, Sm, Eu, Y, V, and Ti are contained in the B site of the general formula, and Ag is contained at a ratio of 0.001 at. % or more and less than 20 at. % in the A site of the general formula.

The present invention relates in part to a method of fabricating multimetallic nanoparticles, the method comprising the steps of providing a substrate; activating the substrate surface; adsorbing a cationic transition metal complex onto the substrate surface to form a substrate-supported cationic transition metal complex; adsorbing an anionic transition metal complex onto the substrate-supported cationic transition metal complex to form a substrate-supported multimetallic complex salt; and reducing the substrate-supported multimetallic complex salt to provide a plurality of multimetallic nanoparticles. The invention also relates in part to a composition of multimetallic nanoparticles comprising at least two metals M.sub.a and M.sub.b; wherein the ratio of M.sub.a to M.sub.b is between about 2:1 and about 1:2.

A catalyst for producing light aromatics with heavy aromatics, a method for preparing the catalyst, and a use thereof are disclosed. The catalyst comprises a carrier, component (1), and component (2), wherein component (1) comprises one metal element or more metal elements selected from a group consisting of Pt, Pd, Ir, and Rh, and component (2) comprises one metal element or more metal elements selected from a group consisting of IA group, IIA group, IIIA group, IVA group, IB group, IIB group, IIIB group, IVB group, VB group, VIB group, VIIB group, La group, and VIII group other than Pt, Pd, Ir, and Rh. The catalyst can be used for producing light aromatics with heavy aromatics, whereby heavy aromatics hydrogenation selectivity and light aromatics yield can be improved.