Disclosed herein are methods of producing E-CF.sub.3CHCHCF.sub.3 in a liquid phase. Also disclosed are methods of preparing CF.sub.3CH.sub.2CHClCF.sub.3 and CF.sub.3CHClCH.sub.2CCl.sub.3.

Disclosed herein are methods of producing E-CF.sub.3CHCHCF.sub.3 in a liquid phase. Also disclosed are methods of preparing CF.sub.3CH.sub.2CHClCF.sub.3 and CF.sub.3CHClCH.sub.2CCl.sub.3.

Catalysts are disclosed having metal oxide support structures and acidic reaction sites. Those reaction sites may have multiple bromine atoms bound to an aluminum atom with that aluminum-bromine group having an associated hydrogen ion. Additional structural features of the reaction sites are dictated by the aluminum oxide based catalysts and a silicon oxide based catalyst selected.

A high-efficiency visible-light catalytic material, a preparation method and an application thereof are provided by the present application, relating to the technical field of photocatalytic materials. The present application prepares photocatalytic material Ag@AgCl/CA by compounding Ag@AgCl and calcium alginate gel, and the prepared photocatalytic material is shaped as small particles. The photocatalytic material Ag@AgCl/CA is used to degrade tetracycline antibiotics.

A high-efficiency visible-light catalytic material, a preparation method and an application thereof are provided by the present application, relating to the technical field of photocatalytic materials. The present application prepares photocatalytic material Ag@AgCl/CA by compounding Ag@AgCl and calcium alginate gel, and the prepared photocatalytic material is shaped as small particles. The photocatalytic material Ag@AgCl/CA is used to degrade tetracycline antibiotics.

The present invention relates, at least in part, to a process for making chlorotrifluoroethylene (CFO-1113) from 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a). In certain aspects, the process includes dehydrochlorinating 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a) in the presence of a catalyst selected from the group consisting of (i) one or more metal halides; (ii) one or more halogenated metal oxides; (iii) one or more zero-valent metals or metal alloys; (iv) combinations thereof.

The present invention relates, at least in part, to a process for making chlorotrifluoroethylene (CFO-1113) from 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a). In certain aspects, the process includes dehydrochlorinating 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a) in the presence of a catalyst selected from the group consisting of (i) one or more metal halides; (ii) one or more halogenated metal oxides; (iii) one or more zero-valent metals or metal alloys; (iv) combinations thereof.

The present invention relates, at least in part, to a process for making chlorotrifluoroethylene (CFO-1113) from 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a). In certain aspects, the process includes dehydrochlorinating 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a) in the presence of a catalyst selected from the group consisting of (i) one or more metal halides; (ii) one or more halogenated metal oxides; (iii) one or more zero-valent metals or metal alloys; (iv) combinations thereof.

The present invention relates, at least in part, to a process for making chlorotrifluoroethylene (CFO-1113) from 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a). In certain aspects, the process includes dehydrochlorinating 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a) in the presence of a catalyst selected from the group consisting of (i) one or more metal halides; (ii) one or more halogenated metal oxides; (iii) one or more zero-valent metals or metal alloys; (iv) combinations thereof.

The present application provides a process of preparing 3,3,3-trifluoroprop-1-ene, comprising reacting 3-chloro-1,1,1-trifluoropropane with a base in an aqueous solvent component in the absence of a phase transfer catalyst.