Patent classifications
B01J27/13
Hollow porous carbon nitride nanospheres composite loaded with AgBr nanoparticles, preparation method thereof, and its application in dye degradation
A hollow porous carbon nitride nanospheres composite loaded with AgBr nanoparticles, preparation method thereof, and its application in dye degradation are disclosed. Using silica nanosphere with core-shell structure as a template and hydrogen cyanamide as precursor, melting to enter the pores of mesoporous silica, after calcination, the silica template is etched with ammonium bifluoride to obtain hollow porous carbon nitride nanospheres; dispersing hollow porous carbon nitride nanospheres in deionized water, adding silver nitrate and sodium bromide in sequence, and obtaining silver bromide nanoparticles by in-situ ion exchange method, stirring, washing and centrifuging to obtain the hollow porous carbon nitride nanospheres composite. The hollow porous carbon nitride prepared by the template method has good photocatalytic effect on dye degradation after composite with silver bromide; and it has the advantages of easy production of raw materials, good stability, reusability, etc. It has application prospects in the treatment of dyes.
Hollow porous carbon nitride nanospheres composite loaded with AgBr nanoparticles, preparation method thereof, and its application in dye degradation
A hollow porous carbon nitride nanospheres composite loaded with AgBr nanoparticles, preparation method thereof, and its application in dye degradation are disclosed. Using silica nanosphere with core-shell structure as a template and hydrogen cyanamide as precursor, melting to enter the pores of mesoporous silica, after calcination, the silica template is etched with ammonium bifluoride to obtain hollow porous carbon nitride nanospheres; dispersing hollow porous carbon nitride nanospheres in deionized water, adding silver nitrate and sodium bromide in sequence, and obtaining silver bromide nanoparticles by in-situ ion exchange method, stirring, washing and centrifuging to obtain the hollow porous carbon nitride nanospheres composite. The hollow porous carbon nitride prepared by the template method has good photocatalytic effect on dye degradation after composite with silver bromide; and it has the advantages of easy production of raw materials, good stability, reusability, etc. It has application prospects in the treatment of dyes.
BI-MODAL RADIAL FLOW REACTOR
A bi-modal radial flow reactor comprising: a cylindrical outer housing surrounding at least five cylindrical, concentric zones, including at least three annulus vapor zones including an outer annulus vapor zone, a middle annulus vapor zone, and a central annulus vapor zone, and at least two catalyst zones, including an outer catalyst zone and an inner catalyst zone, wherein the outer catalyst zone is intercalated with the outer annulus vapor zone and the middle annulus vapor zone, and wherein the inner catalyst zone is intercalated with the middle annulus vapor zone and the central annulus vapor zone; and a manifold configured to introduce a feed vertically into a bottom end of each of one or two of the at least three annulus vapor zones, and remove a product from a bottom end of each of the one or two remaining of the at least three annulus vapor zones.
PROCESS FOR MAKING ALICYCLIC POLYCARBOXYLIC ACIDS OR THEIR DERIVATIVES
The present invention discloses a process for making alicyclic polycarboxylic acids or their derivatives, referring to a process for hydrogenating aromatic polycarboxylic acids or their derivatives in the presence of hydrogen and a catalyst to form alicyclic polycarboxylic acids or their derivatives, and the catalyst comprises at least one active metal of group VIIIB transition elements of the periodic table of elements, and a catalyst support comprising group IIA and group IIIA elements in a specific weight ratio.
PROCESS FOR MAKING ALICYCLIC POLYCARBOXYLIC ACIDS OR THEIR DERIVATIVES
The present invention discloses a process for making alicyclic polycarboxylic acids or their derivatives, referring to a process for hydrogenating aromatic polycarboxylic acids or their derivatives in the presence of hydrogen and a catalyst to form alicyclic polycarboxylic acids or their derivatives, and the catalyst comprises at least one active metal of group VIIIB transition elements of the periodic table of elements, and a catalyst support comprising group IIA and group IIIA elements in a specific weight ratio.
Process for making alicyclic polycarboxylic acids or their derivatives
The present invention discloses a process for making alicyclic polycarboxylic acids or their derivatives, referring to a process for hydrogenating aromatic polycarboxylic acids or their derivatives in the presence of hydrogen and a catalyst to form alicyclic polycarboxylic acids or their derivatives, and the catalyst comprises at least one active metal of group VIIIB transition elements of the periodic table of elements, and a catalyst support comprising group IIA and group IIIA elements in a specific weight ratio.
Process for making alicyclic polycarboxylic acids or their derivatives
The present invention discloses a process for making alicyclic polycarboxylic acids or their derivatives, referring to a process for hydrogenating aromatic polycarboxylic acids or their derivatives in the presence of hydrogen and a catalyst to form alicyclic polycarboxylic acids or their derivatives, and the catalyst comprises at least one active metal of group VIIIB transition elements of the periodic table of elements, and a catalyst support comprising group IIA and group IIIA elements in a specific weight ratio.
Curable Organopolysiloxane Composition Containing Dynamic Covalent Polysiloxane
A curable organopolysiloxane composition containing dynamic covalent organopolysiloxanes which yields, upon cure, a silicone rubber having adaptive elastomeric and viscous characteristics is claimed. The silicone may be an elastomer or foam. A method of making the silicone rubber and a shaped article made of the cured adaptive viscoelastic silicone rubber composition are also claimed.
Curable Organopolysiloxane Composition Containing Dynamic Covalent Polysiloxane
A curable organopolysiloxane composition containing dynamic covalent organopolysiloxanes which yields, upon cure, a silicone rubber having adaptive elastomeric and viscous characteristics is claimed. The silicone may be an elastomer or foam. A method of making the silicone rubber and a shaped article made of the cured adaptive viscoelastic silicone rubber composition are also claimed.
Method for producing diol
The present invention provides a method for producing a diol having a specific structure in high yields while keeping high selectivity. Provided is a method for producing a diol having a specific structure by oxidizing an olefin having a specific structure in the presence of a ruthenium compound.