Patent classifications
B01J31/08
Method of catalysis for the production of bisphenol A
Provided is a process for producing 2,2-bis(4-hydroxyphenyl)propane, comprising condensing phenol with acetone in the presence of an acid catalyst; wherein the acid catalyst comprises a collection of sulfonated polymeric beads, wherein the sulfonated polymeric beads comprise (i) 75 to 99% by weight, based on the weight of the bead, polymerized units of monofunctional vinyl monomer, and (ii) 1 to 25% by weight, based on the weight of the bead, polymerized units of multifunctional vinyl monomer; wherein 90% or more of the beads by volume are uniform beads.
METHOD FOR PRODUCING CARBODIIMIDE COMPOUND
A method for producing a carbodiimide compound, comprising a carbodiimide production step of reacting an aliphatic tertiary isocyanate compound (A) in the presence of an organic alkali metal compound (B) having Lewis basicity.
METHOD FOR PRODUCING CARBODIIMIDE COMPOUND
A method for producing a carbodiimide compound, comprising a carbodiimide production step of reacting an aliphatic tertiary isocyanate compound (A) in the presence of an organic alkali metal compound (B) having Lewis basicity.
METHOD FOR PRODUCING UNSATURATED CARBOXYLIC ESTER
An object of the present invention is to provide a method for producing an unsaturated carboxylic ester, wherein the risk of polymerization blockage is reduced and the required equipment cost and workload involved are kept low while maintaining a high conversion rate in an esterification reaction of unsaturated carboxylic acid. This object can be achieved by a method for producing an unsaturated carboxylic ester, which includes performing an esterification reaction using a reactor packed with a solid catalyst, wherein unsaturated carboxylic acid and alcohol are continuously fed to the reactor from an inlet thereof to form a fluid of the reaction solution in the reactor, and the vaporized organic solvent is continuously fed to the reactor from the inlet or a part near the inlet of the reactor.
Antioxidant Protection for Ion Exchange Resins
Methods of stabilizing virgin ion exchange resin material are provided. The methods include cleansing the virgin ion exchange resin material with a preparation comprising a non-ionic detergent. The methods include cleansing the virgin ion exchange resin material with a preparation comprising an alcohol solvent. The methods include rinsing virgin ion exchange resin material with deoxygenated water. the methods include introducing the cleansed/rinsed virgin ion exchange resin material into a gas impermeable vessel and hermetically sealing the vessel. The methods include introducing an oxygen scavenging material into the gas impermeable vessel, and hermetically sealing the vessel. A method of facilitating water treatment in a site in need thereof by providing a cleansed virgin ion exchange resin material in deoxygenated water is also disclosed.
Ion exchange resin for producing bisphenol, and a method for producing bisphenol using said ion exchange resin
This invention relates to an ion exchange resin for producing bisphenol with high percent conversion and high percent selectivity to bisphenol, especially 4,4 isopropyhdenediphenol, wherein said ion exchange resin comprising aromatic polymer having sulfonic acid group modified with at least one promoter selected from compounds shown in the structure (I), (II), (III), (IV) or its amine salt: wherein R represents hydrocarbon unit with 1 to 6 carbon atoms selected from alkyl group, alkenyl group, alkynyl group, phenyl group, or optionally hydrocarbon containing carbonyl group having 1 to 6 carbon atoms; X represents heteroatom; n is an integer number from 1 to 4. ##STR00001##
Ion exchange resin for producing bisphenol, and a method for producing bisphenol using said ion exchange resin
This invention relates to an ion exchange resin for producing bisphenol with high percent conversion and high percent selectivity to bisphenol, especially 4,4 isopropyhdenediphenol, wherein said ion exchange resin comprising aromatic polymer having sulfonic acid group modified with at least one promoter selected from compounds shown in the structure (I), (II), (III), (IV) or its amine salt: wherein R represents hydrocarbon unit with 1 to 6 carbon atoms selected from alkyl group, alkenyl group, alkynyl group, phenyl group, or optionally hydrocarbon containing carbonyl group having 1 to 6 carbon atoms; X represents heteroatom; n is an integer number from 1 to 4. ##STR00001##
METHOD OF CATALYSIS
Provided is a process for producing 2,2-bis(4-hydroxyphenyl)propane, comprising condensing phenol with acetone in the presence of an acid catalyst; wherein the acid catalyst comprises a collection of sulfonated polymeric beads, wherein the sulfonated polymeric beads comprise (i) 75 to 99% by weight, based on the weight of the bead, polymerized units of monofunctional vinyl monomer, and (ii) 1 to 25% by weight, based on the weight of the bead, polymerized units of multifunctional vinyl monomer; wherein 90% or more of the beads by volume are uniform beads.
ORGANOFUNCTIONAL SILOXANES, PROCESS FOR PREPARING SAME AND THEIR USE FOR THE TREATMENT OF FILLINGS AND SURFACES
The present invention provides organofunctional siloxane coupling agents, dipodal siloxanes, siloxane block copolymers and a specific method for preparing these organofunctional siloxanes through an addition reaction of hydrido alkoxysilane and organofunctional disiloxanes to an organocyclosiloxane with a catalyst. The addition reaction of the current invention does not result in polymerization and therefore the novel siloxane couplings agents are free of cyclosiloxanes and polymeric siloxanes. This makes them apt for adhesives, coatings and sealant applications. The present invention also relates to the use of these organofunctional siloxane compounds for the treatment of fillers and surfaces.
ORGANOFUNCTIONAL SILOXANES, PROCESS FOR PREPARING SAME AND THEIR USE FOR THE TREATMENT OF FILLINGS AND SURFACES
The present invention provides organofunctional siloxane coupling agents, dipodal siloxanes, siloxane block copolymers and a specific method for preparing these organofunctional siloxanes through an addition reaction of hydrido alkoxysilane and organofunctional disiloxanes to an organocyclosiloxane with a catalyst. The addition reaction of the current invention does not result in polymerization and therefore the novel siloxane couplings agents are free of cyclosiloxanes and polymeric siloxanes. This makes them apt for adhesives, coatings and sealant applications. The present invention also relates to the use of these organofunctional siloxane compounds for the treatment of fillers and surfaces.