A bifunctional catalyst for conversion of oxygenates, said catalyst comprising zeolite, alumina binder and Zn, wherein the Zn is present at least partly as ZnAl.sub.2O.sub.4.

A carbon-platinum core-shell type catalyst for fuel cells and a method for preparing the same which includes carbon as a core and platinum as a shell which can solve durability-associated problems under proton exchange membrane fuel cells (PEMFC) operation conditions and furthermore tackle manufacturing cost-related problems and process complexity by improving acid resistance through incorporation of a carbon material rather than a transition metal into catalysts.

Methods of making a carbon nanotube material and uses thereof are described. The methods can include obtaining a carbon-containing polymeric matrix shell having a single discrete void space defined by the carbon-containing polymeric matrix shell or having an encapsulated core and subjecting the carbon-containing polymeric matrix shell to a graphitization process to form a shell having a carbon nanotube network from the matrix. The resulting carbon nanotube material includes a shell having a network of carbon nanotubes and either (i) a single discrete void space defined by the network of carbon nanotubes or (ii) the encapsulated core surrounded by the network of carbon nanotubes.

A multimetallic core/interlayer/shell nanoparticle comprises an inner core formed from a first metal. An interlayer is disposed on the first layer. The interlayer includes a plurality of gold atoms. An outer shell is disposed over the interlayer. The outer shell includes platinum and the first metal. A surface of the NP is substantially free of gold. The first metal is selected from the group consisting of nickel, titanium, chromium, manganese, iron, cobalt, copper, vanadium, yttrium, ruthenium, palladium, scandium, tin, lead and zinc.

Disclosed are a catalyst, its preparation and use in selective hydrogenation, which catalyst has a porous support grain on which are deposited palladium and silver, and at least one alkali and/or alkaline earth metal; the porous support contains a refractory silica, alumina and/or silica-alumina oxide, where at least 80 wt. % of the palladium is distributed in a crust at the periphery of the support, and at least 80 wt. % of the silver is distributed in a crust at the periphery of the support, the local content of palladium at each point along the diameter of the grain follows the same course as the local content of silver.

A heterogeneous core@shell photocatalyst having a combination of properties that include rapid adsorption and effective decomposition with respect to various substances is provided. This core@shell photocatalyst comprises a conventional photocatalyst core coated with an adsorbent surface layer (in the nanometer size range). The novel heterogeneous photocatalyst can be formed by a simple hydrothermal method.

The exhaust gas purification catalyst of the present invention includes a ceria particle as a support, and barium supported on the ceria particle, wherein the ceria particle contains lanthanum in its surface part and when the ceria particle is measured by an X-ray photoelectric spectroscopy, the value of the molar ratio of lanthanum atom to cerium atom is 0.029 or more.

A catalyst that includes heterogeneous metal carbide nanomaterials and a novel preparation method to synthesize the metal carbide nanomaterials under relatively mild conditions to form an encapsulated transition metal and/or transition metal carbide nanoclusters in a support and/or binder. The catalyst may include confined platinum carbide nanoclusters. The preparation may include the treatment of encapsulated platinum nanoclusters with ethane at elevated temperatures. The catalysts may be used for catalytic hydrocarbon conversions, which include but are not limited to, ethane aromatization, and for selective hydrogenation, with negligible green oil production.

A stereostructure includes a core portion, and a porous portion located around the core portion. The porous portion located inside a position which is inside from an outer edge of the porous portion by 3/20 of a diameter of the stereostructure in an arbitrary cross section of the stereostructure has a void ratio per unit area of less than or equal to 80%.

The present invention relates to a metal oxide coated composite comprising a core consisting of a mixture of a La stabilized Al.sub.2O.sub.3 phase and an Ce/Zr/RE.sub.2O.sub.3 mixed oxide phase, the core having a specific crystallinity, specific pore volume and a specific pore size distribution, and a method for the production of the metal oxide coated composite.