B01J35/695

Method for preparing a sodium faujasite catalyst and its use in producing acrylic acid

The invention relates generally to a sodium faujasite catalyst, and in particular the use of the sodium faujasite catalyst in producing acrylic acid. In particular, the invention relates to the use of the sodium faujasite catalyst in catalytic dehydration of lactic acid and 3-hydroxypropionic acid (3-HP) to produce acrylic acid.

Manufacturing method of honeycomb structure

The manufacturing method includes a step of mixing a coarse particle zeolite, a fine particle zeolite, and a raw material of an inorganic bonding material to prepare a zeolite raw material; a step of forming the prepared zeolite raw material into a honeycomb shape to prepare a honeycomb formed body; and a step of firing the prepared honeycomb formed body to prepare the honeycomb structure. In the step of preparing the zeolite raw material, as the coarse particle zeolite, a chabazite type zeolite having a specific average particle diameter, the fine particle zeolite having a specific average particle diameter, the raw material of the inorganic bonding material which includes at least basic aluminum lactate is used.

CATALYST AND METHOD FOR SYNTHESIS OF AROMATIC HYDROCARBONS THROUGH DIRECT CONVERSION OF SYNTHESIS GAS
20190031575 · 2019-01-31 ·

Synthesis of aromatic hydrocarbons from synthesis gas in a fixed bed or a moving bed reactor loaded with a composite catalyst comprising Catalyst Component A and Catalyst Component B mixed via a mechanical mixing mode, wherein the active ingredient of the Catalyst Component A is active metal oxides; and the Catalyst Component B is one or both of ZSM-5 zeolite and metal modified ZSM-5; the pressure of the synthesis gas is 0.1-6 MPa; the reaction temperature is 300-600 C.; and the space velocity is 500-8000 h.sup.1. The reaction process has a high product yield and selectivity, with the selectivity of aromatics reaching 50-85%, while the selectivity of the methane byproduct is less than 15%.

CATALYTIC PROPPANT AND METHODS FOR MAKING AND USING SAME

A catalytic proppant and methods for making and using same are disclosed herein. The catalytic proppant can include a proppant support containing silica and alumina. The proppant support can have a macropore concentration of about 15% to about 45%, a mesopore concentration of about 20% to 50%, and a micropore concentration of about 8% to about 30% based on the total pore volume of the proppant support. The proppant support can also have a surface area of about 0.5 m.sup.2/g to about 50 m.sup.2/g. The catalytic proppant can have a long term permeability at 7,500 psi of at least about 10 D in accordance with ISO 13503-5.

Extruded Titania-Based Materials Comprising Quaternary Ammonium Compounds and/or Prepared Using Quaternary Ammonium Compounds

Porous, extruded titania-based materials further comprising one or more quaternary ammonium compounds and/or prepared using one or more quaternary ammonium compounds, Fischer-tropsch catalysts comprising them, uses of the foregoing, processes for making and using the same and products obtained from such processes.

Catalyst for producing ethylene oxide by gas-phase oxidation

A shaped catalyst body for producing ethylene oxide by gas-phase oxidation of ethylene, comprising silver deposited on a porous refractory support, the shaped catalyst body having a first face side surface, a second face side surface and a circumferential surface, characterized by a content of at least 20 wt.-% of silver, relative to the total weight of the shaped catalyst body; a multilobe structure; a plurality of passageways extending from the first face side surface to the second face side surface, outer passageways being arranged around a central passageway with one outer passageway being assigned to each lobe, wherein neighboring outer passageways are arranged essentially equidistantly to each other and the outer passageways are arranged essentially equidistantly to the central passageway; a minimum wall thickness A between two neighboring passageways in the range of 0.6 to 1.3 mm; a minimum wall thickness B between each outer passageway and the circumferential surface in the range of 1.1 to 1.8 mm; and a BET surface area in the range of 1.6 to 3.0 m.sup.2/g. The shaped catalyst bodies allow for a favorable balance between mechanical stability, pressure drop and selectivity. The invention also relates to a process for producing ethylene oxide by gas-phase oxidation of ethylene, comprising reacting ethylene and oxygen in the presence of a shaped catalyst body as defined above. The invention further relates to a process for preparing a shaped catalyst body as above, comprising i) impregnating a refractory support having a BET surface area in the range of 1.4 to 2.5 m.sup.2/g with a silver impregnation solution; and ii) subjecting the impregnated refractory support to a calcination process; wherein steps i) and ii) are optionally repeated.

CATALYST AND METHOD OF PREPARING LIGHT OLEFIN DIRECTLY FROM SYNTHESIS GAS BY ONE-STEP PROCESS
20180194700 · 2018-07-12 ·

The present invention discloses catalyst and method for producing light olefins directly from synthesis gas by a one-step process, and particularly relates to method and catalyst for directly converting synthesis gas into light olefins by a one-step process. The provided catalysts are composite materials formed of multicomponent metal oxide composites and inorganic solid acids with hierarchical pore structures. The inorganic solid acids have a hierarchical pore structure having micropores, mesopores and macropores. The metal composites can be mixed with or dispersed on surfaces or in pore channels of the inorganic solid acid and can catalyze the synthesis gas conversion to a C.sub.2-C.sub.4 light hydrocarbon product containing two to four carbon atoms. The single pass conversion of CO is 10%-60%. The selectivity of light hydrocarbon in all hydrocarbon products can be up to 60%-95%, wherein the selectivity of light olefins (C.sub.2.sup.?-C.sub.4.sup.?) is 50%-85%.

CATALYST WITH A MESOPOROUS AND MACROPOROUS CO-MIXED NICKEL ACTIVE PHASE HAVING A MEDIAN MACROPORE DIAMETER IN THE RANGE 50 TO 300 NM, AND ITS USE IN HYDROGENATION

A catalyst comprising a calcined oxide matrix which is mainly alumina and an active phase comprising nickel, said active phase being at least partially co-mixed within said calcined oxide matrix which is mainly alumina, the nickel content being in the range 5% to 65% by weight of said element with respect to the total mass of catalyst, said active phase not comprising any metal from group VIB, the nickel particles having a diameter of less than 15 nm, said catalyst having a median mesopore diameter in the range 12 nm to 25 nm, a median macropore diameter in the range 50 to 300 nm, a mesopore volume, measured by mercury porosimetry, of 0.40 mL/g or more and a total pore volume, measured by mercury porosimetry, of 0.45 mL/g or more. The process for the preparation of said catalyst, and its use in a hydrogenation process.

1,3-BUTADIENE SYNTHESIS CATALYST, METHOD FOR PRODUCING SAME, AND METHOD FOR PRODUCING 1,3-BUTADIENE

A catalyst according to an embodiment is a catalyst for synthesizing 1,3 -butadiene from ethanol. The catalyst contains a porous silica support made of crystalline silica, Zn, and Zr, and has a multimodal pore size distribution with a peak pore size (D.sub.micro) of 2 in or less and a peak pore size (D.sub.meso+macro) of more than 2 nm.

Suspended-Bed Hydrogenation Catalyst and Regeneration Method Therefor

A suspended-bed hydrogenation catalyst and a regeneration method are disclosed. A composite support comprises a semi-coke pore-expanding material, a molecular sieve and a spent catalytic cracking catalyst. The hydrogenation catalyst for heavy oil is obtained through mixing the semi-coke pore-expanding material, the molecular sieve and the spent catalytic cracking catalyst, followed by molding, calcining and activating, and then loading an active metal oxide to the composite support. According to the composite support, a macropore, mesopore and micropore uniformly-distributed structure is formed, so that full contact between all ingredients in the heavy oil and active ingredients in a hydrogenation process is facilitated, and the conversion ratio of the heavy oil is increased. The hydrogenation catalyst integrates adsorption, cracking and hydrogenation properties. According to a regeneration method, the loading performance of an active-metal-loaded support in a spent hydrogenation catalyst cannot be destroyed.