A photothermal catalytic method for production of hydrogen peroxide without a sacrificial reagent on the basis of a porphyrin-based supermolecule is provided. The method includes the following steps: uniformly mixing a porphyrin-based supermolecule photocatalyst with a concentration of 0.3-1.5 g/L with ultrapure water, conducting irradiation with a visible light for a period of time under stirring at a temperature of 40-80° C. and an O.sub.2 flow rate of 50-150 mL/min, and then filtering and concentrating a reaction liquid to obtain an aqueous hydrogen peroxide solution with a high concentration. According to the new photothermal catalytic method for preparing the hydrogen peroxide provided in the present disclosure, no organic solvent (such as ethanol, isopropanol and benzyl alcohol) is used as a sacrificial reagent, and the method is environmentally friendly and free of pollution. O.sub.2 is used as an oxygen source, sunlight is used as an energy source, and the method is low in energy consumption and high in safety (compared with an industrial anthraquinone method for synthesizing hydrogen peroxide). The method is simple in operation, mild in reaction conditions and high in production of the hydrogen peroxide.

Devices suitable for use in an advanced oxidation method for organic and inorganic pollutants deploying OH* radicals and ozone is disclosed. Optionally, a first discharge device, providing OH* radicals and second discharge device providing ozone, are combined to provide desirable chemical and biocidal characteristics. Further, efficient mixing systems for transferring the radicals to the target fluid are disclosed.

A method for converting hydrocarbon materials into a product includes receiving a hydrocarbon feedstock in a first reaction chamber, receiving a process gas in the first reaction chamber, and forming a first set of discharge conditions in the presence of energy from a microwave generator, in the first reaction chamber, to convert the hydrocarbon feedstock into an intermediate product for delivery to a second reaction chamber. The method also includes delivering the intermediate product to the second reaction chamber, forming a second set of discharge conditions, and converting the intermediate product into a final product in the second reaction chamber.

The invention provides a photoreactor assembly (1) comprising a reactor (30), wherein the reactor (30) is configured for hosting a fluid (100) to be treated with light source radiation (11) selected from one or more of UV radiation, visible radiation, and IR radiation, wherein the reactor (30) comprises a reactor wall (35) which is transmissive for the light source radiation (11), wherein: (i) the reactor (30) is a tubular reactor (130), and wherein the reactor wall (35) defines the tubular reactor (130); (ii) the tubular reactor (130) is configured in a tubular arrangement (1130); (iii) the photoreactor assembly (1) further comprises a light source arrangement (1010) comprising a plurality of light sources (10) configured to generate the light source radiation (11), wherein the reactor wall (35) is configured in a radiation receiving relationship with the plurality of light sources (10); and (iv) one or more of the tubular arrangement (1130) and the light source arrangement (1010) defines a polygon (50).

Presented in the present disclosure are nanocomposites and rechargeable batteries which are resistant to thermal runaway and are safe, reliable, and stable electrode materials for rechargeable batteries operated at high temperature and high pressure. The nanocomposites include a plurality of transition metal oxide nanoparticles, a plurality of ultrathin sheets of a first two-dimensional (2D) material, and a plurality of ultrathin sheets of a different 2D material, which act in synergy to provide an improved thermal stability, an increased surface area, and enhanced electrochemical properties to the nanocomposites. For example, rechargeable batteries that include the nanocomposites as an electrode material have an enhanced performance and stability over a broad temperature range from room temperature to high temperatures. These batteries fill an important need by providing a safe and reliable power source for devices operated at high temperatures and pressures such as downhole equipment used in the oil industry.

The invention provides a photoreactor assembly (1) comprising a reactor (30), wherein the reactor (30) is configured for hosting a fluid (100) to be treated with light source radiation (11) selected from one or more of UV radiation, visible radiation, and IR radiation, wherein the reactor (30) comprises a reactor wall (35) which is transmissive for the light source radiation (11), wherein the photoreactor assembly (1) further comprises: a light source arrangement (1010) comprising a plurality of light sources (10) configured to generate the light source radiation (11), wherein the reactor wall (35) is configured in a radiation receiving relationship with the plurality of light sources (10); one or more fluid transport channels (7) configured in functional contact with one or more of (i) the reactor (30) and (ii) one or more of the plurality of light sources (10); a cooling system (90) configured to transport a cooling fluid (91) through the one or more fluid transport channels (7).

A method for producing a purified, stable, dioxytetrahydride compressible gas from water. The gas is suitable for a variety of uses and may also be infused into water which itself is useful for a variety of purposes.

This invention relates to a production method for non-detonation synthesis nanodiamond by exposing carbonaceous feedstock to a dense plasma focus. The nucleated nanodiamond particles have characteristics that differentiate them from known forms of nanodiamond. For instance, the nucleated nanodiamond particles are substantially spherical and have a substantially smooth surface, as may be demonstrated by TEM. The nucleated nanodiamond particles are also free of graphite and detonation carbon contaminants. The identity of the nanodiamond particles has been confirmed through raman spectra, for example. The nanodiamond particles have also been found to be effective as a lubricant composition when combined with a carrier oil.

Provided is a method for producing a photocatalyst electrode for water decomposition that exhibits excellent detachability between the substrate and the photocatalyst layer and exhibits high photocurrent density. The method for producing a photocatalyst electrode for water decomposition of the invention includes: a metal layer forming step of forming a metal layer on one surface of a first substrate by a vapor phase film-forming method or a liquid phase film-forming method; a photocatalyst layer forming step of forming a photocatalyst layer by subjecting the metal layer to at least one treatment selected from an oxidation treatment, a nitriding treatment, a sulfurization treatment, or a selenization treatment; a current collecting layer forming step of forming a current collecting layer on a surface of the photocatalyst layer, the surface being on the opposite side of the first substrate; and a detachment step of detaching the first substrate from the photocatalyst layer.

A MOF production system and method of making are detailed for continuous and controlled synthesis of MOFs and MOF composites. The system can provide optimized yields of MOFs and MOF composites greater than or equal to 95%.