Patent classifications
B01J2219/0896
Microwave-Induced Non-Thermal Plasma Conversion of Hydrocarbons
A non-thermal plasma is generated to selectively convert a precursor to a product. More specifically, plasma forming material and a precursor material are provided to a reaction zone of a vessel. The reaction zone is exposed to microwave radiation, including exposing the plasma forming material and the precursor material to the microwave radiation. The exposure of the plasma forming material to the microwave radiation selectively converts the plasma forming material to a non-thermal plasma including formation of one or more streamers. The precursor material is mixed with the plasma forming material and the precursor material is exposed to the non-thermal plasma including exposing the precursor material to the one or more streamers. The exposure of the precursor material to the streamers and the microwave radiation selectively converts the precursor material to a product.
PROCESS AND APPARATUS FOR PRODUCING FLUORINATED ALKENES
Provided is a process for producing fluorinated alkenes by providing a microwave plasma in a reactor chamber, introducing a protective gas feed into the reactor chamber, and contacting a conversion feed comprising at least one fluorinated linear or branched alkane with the plasma. Also provided are an apparatus and the use of the process and the apparatus.
Reactor with cold turning plasma and stream forcing
A reactor for forming a plasma in a flowing fluid that includes a central rod belonging to a first electrode, an insulator, a tubular body belonging to a second electrode and defining a cylindrical space for the flow of the fluid between the tubular body and the insulator. The reactor further includes control disk having a front face linked to a downstream end of the central rod, and a permanent magnet juxtaposed against a back face of the control disk. One or more ribs are on a front face of the control disk according to a pattern in relief defining successive starting points for an electric arc distributed around the central axis of the reactor so as to generate electric arcs situated on a reaction cone and appearing to turn around the central axis.
Reactor for liquid and gas and method of use
A system and method for performing plasma reactions creating a plasma area in a gas adjacent to a liquid. An embodiment of the plasma reactor includes a housing with an internal reaction chamber, first and second inlet paths to the reaction chamber, and electrodes for producing an electric field. The system may optionally further include a pre-ionization electrode and pre-ionization electric field for pre-ionizing a feed gas prior to entry into a reaction chamber. The reactor uses plasma to ionize gas adjacent with the liquid. The ionized gas reacts with the liquid to form an effluent. Exemplary uses of the plasma reactor include ionic injection, gas dissociation, liquid re-formation, and liquid dissociation. An alternative embodiment provides a system and method for infusion of gaseous particles into liquid by applying an electric field at power levels lower than the voltage required to form a plasma to gas adjacent to liquid.
Reactor comprising a plasma source and a catalyst comprising a mesoporous support material for the preparation of ethene from methane
The invention relates to a reactor comprising a plasma source and a catalyst comprising a mesoporous support. The invention also relates to a process comprising feeding methane to said reactor in order to obtain one or more of ethene, hydrogen and carbon as well as downstream products derived from ethene thus obtained. The invention relates to a reactor comprising as reactor parts: a. a housing and in said housing; b. a plasma source; and c. a catalyst, wherein said catalyst comprises as catalyst parts: i) a mesoporous support; ii) a metal selected from the group Pd, Ni, Ag or at least two thereof, wherein the metal is carried by said mesoporous support; wherein at least a part of said plasma source is located in said housing upstream of said catalyst.
Reactor for the Conversion of Carbon Dioxide
The present invention concerns a reactor for the conversion of carbon dioxide or carbon monoxide into hydrocarbon and/or alcohol comprising a support made from an electrically and thermally conductive material, forming the wall or walls of at least one longitudinal channel that passes through the support and also acting as the cathode of the reactor, at least one wire electrode forming an anode of the reactor, and extending within each longitudinal channel, and being arranged at a distance from the wall or walls of the longitudinal channel, each wire electrode optionally being covered with an electrically insulating layer along the part of the wire electrode extending within the longitudinal channel, a catalyst capable of catalysing a conversion reaction for the conversion of carbon dioxide or carbon monoxide into hydrocarbon and/or alcohol, the catalyst being situated between the wire electrode and the wall or walls of each longitudinal channel.
METHOD FOR MANUFACTURING POROUS CARBON MATERIAL DOPED WITH HETEROGENEOUS ELEMENT AND POROUS CARBON MATERIAL DOPED WITH HETEROGENEOUS ELEMENT PREPARED THEREFROM
A method for manufacturing a porous carbon material doped with a heterogeneous element and a porous carbon material doped with a heterogeneous element manufactured using the method are proposed. The method includes melting carbon precursor powder that contains one or more kinds of heterogeneous elements selected from metal and nonmetal to prepare a precursor melt; disposing a pair of metal wires in the precursor melt; and applying power to the metal wires to perform plasma-discharge, thus forming and aggregating carbon nanoparticles doped with the heterogeneous element while having a micropore and thereby forming a porous carbon material having a meso-macro hierarchical pore structure. As the heterogeneous element is bound to carbon of the carbon precursor, the carbon nanoparticles are formed in an amorphous structure while being doped with the heterogeneous element, thus increasing an active site.
FUNCTIONALIZED METAL POWDERS BY SMALL PARTICLES MADE BY NON-THERMAL PLASMA GLOW DISCHARGE FOR ADDITIVE MANUFACTURING APPLICATIONS
The present invention discloses a non-thermal plasma treatment of metal powders in order to improve their processability by additive manufacturing (AM). The invention consists in bonding primary particles constituted of metals or metal alloys to a plurality of secondary particles constituted of metals, metal alloys, ceramics or polymers by the mean of a non-thermal plasma treatment. The primary particles have a larger mean diameter than the secondary. Both particles are injected through a non-thermal plasma glow discharge and/or in its afterglow region (region downstream the plasma discharge) where their surfaces are cleaned by removing contaminants and/or oxide layer and activated to react between each other. The functionalized metal powders are then collected and afterwards processed by AM leading to high quality parts. The functionalized metal powders produced by this plasma treatment improve the processability of metal by AM. Indeed, decreasing the reflectivity, removing contaminant and oxide layer, enhancing the isotropic solidification of melted materials and decreasing the sintering temperature enhance the efficiency of powder based AM processes.
FUEL-REFORMING DEVICE AND FUEL-REFORMING METHOD
Provided is a fuel-reforming device comprising: an ammonia tank (4); a reformer (5) for reforming ammonia and generating high-concentration hydrogen gas having a hydrogen content of at least 99%; a mixing tank (7) for mixing ammonia and hydrogen for temporary storage; and a control means (10) for controlling the respective supply amounts of ammonia and high-concentration hydrogen gas that are supplied to the mixing tank (7). The control means (10) calculates the combustion rate coefficient C of mixed gas with respect to a reference fuel on the basis of equation (1). Equation (1): S.sub.0=S.sub.H×C+S.sub.A×(1−C). In equation (1), S.sub.0 is the combustion rate of the reference fuel, S.sub.H is the combustion rate of hydrogen, S.sub.A is the combustion rate of ammonia, and C is the combustion rate coefficient of mixed gas. In addition, on the basis of equation (2), the control means (10) determines the volume fractions of ammonia and hydrogen that are supplied to the mixing tank. Equation (2): C=1−exp(−A×M.sub.B). In equation (2), M is the volume fraction of hydrogen in mixed gas, and A and B are constants.
Non-thermal micro-plasma conversion of hydrocarbons
Embodiments relate to generating non-thermal plasma to selectively convert a precursor to a product. More specifically, plasma forming material, a precursor material, and a plasma promoter material are provided to a reaction zone of a vessel. The reaction zone is exposed to microwave radiation, including exposing the plasma forming material, the precursor material, and the plasma promoter material to the microwave radiation. The exposure of the plasma forming material and the plasma promoter material to the microwave radiation selectively converts the plasma forming material to a micro-plasma. The precursor material is mixed with the plasma forming material and the precursor material is exposed to the micro-plasma. The exposure of the precursor material to the micro-plasma and the microwave radiation selectively converts the precursor material to a product.