Compositions comprising branched C.sub.10 mercaptans selected from the group consisting of 5-methyl-1-mercapto-nonane, 3-propyl-1-mercapto-heptane, 4-ethyl-1-mercapto-octane, 2-butyl-1-mercapto-hexane, 5-methyl-2-mercapto-nonane, 3-propyl-2-mercapto-heptane, 4-ethyl-2-mercapto-octane, 5-methyl-5-mercapto-nonane, and combinations thereof. Compositions comprising C.sub.11+ mercaptans, wherein the C.sub.11+ mercaptans are characterized by structure R.sup.6—SH, wherein R.sup.6 is an alkyl group derived from one or more C.sub.11+ monoolefins, and wherein the one or more C.sub.11+ monoolefins comprise C.sub.11 internal monoolefins, C.sub.12 internal monoolefins, C.sub.13 internal monoolefins, C.sub.14 internal monoolefins, 1-tetradecene, 1-hexadecene, or combinations thereof.

The present invention relates to a process for preparing bromotrichloromethane comprising a) providing bromine in chloroform; and b) radiation of the resulting solution with light in the range of 350 to 550 nm, wherein said solution of bromine in chloroform is not radiated with radiation of a wavelength below 350 nm.

Photocatalysts and methods of using photocatalysts for producing hydrogen and oxygen from water are disclosed. The photocatalysts include an iodide modified photoactive material having an electrically conductive material attached to the iodide ions.

An apparatus for producing silicon nanoparticles using ICP includes a gas supply part in which first and second pipes for introducing a respective first and second gas into the plasma reactor therethrough are arranged alternately, the first pipes extending from an inlet of the reactor to a plasma initiation region; a plasma reaction part having an ICP coil wound therearound in which the particles are formed as the gases introduced through the respective pipes undergo a plasma reaction; and a collection part for collecting the particles. The apparatus can fully mix the gases introduced through the first gas supply pipes, thus allowing for uniform plasma reaction between the first and second gas, minimizing plasma expansion to increase plasma density within short retention time, easily controlling the size distribution by quenching and capturing nanoparticles, and improving the production yield by preventing the secondary aggregation of particles with cooling gas.

Described is a baffle comprising a continuous outer edge and an interior portion enclosed by the outer edge and connected to the outer edge. The interior portion comprises one or more teeth each having a tip directed towards the centre of the baffle, a base adjacent to the outer edge, and a tooth edge joining the tip to the base, wherein at least a portion of the tooth edge defines at least a portion of an aperture extending from a first face to a second face of the baffle.

Provided are a photoirradiation device equipped with: a first optically transparent container for covering a light-emitting body provided with light-emitting diodes; a liquid phase section provided on the outside thereof and formed from a liquid having a refractive index closer to that of the first optically transparent container than that of a gas forming a gas phase section inside the first optically transparent container; and a second optically transparent container for covering the liquid phase section, a photoreaction method using the photoirradiation device, and a method for producing lactam by using the photoreaction method. The reflection of light between a target liquid and a light-emitting diode light source is suppressed, and a desired photoirradiation can be achieved with a high optical transparency.

Provided is a photochemical reaction device wherein two partitions formed from an optically transparent material are arranged apart from each other between a light source and a reaction liquid, and an optically transparent fluid introduction/discharge means for introducing an optically transparent fluid between the partitions and discharging the fluid and a state change detection means for detecting a change in the state of the optically transparent fluid at the discharge side of the optically transparent fluid introduction/discharge means are provided. Also provided are a photochemical reaction method that uses the photochemical reaction device and a lactam production method that uses the photochemical reaction method. The present invention prevents decreases in the performance of the light source even when the optically transparent material in the photochemical reaction device is damaged, and makes it possible to reliably prevent ignition even if the reaction liquid is a flammable liquid.

A photocatalytic composition is disclosed that includes a silver halide in combination with one or more rare earth elements. The composition may be used for the photocatalytic degradation of pollutants.

A photocatalyst injection system including: a reactor primary system coolant collection section collecting a reactor primary system coolant containing a noble metal or noble metal ion from a reactor primary system; a photocatalyst addition section adding a photocatalyst to the collected reactor primary system coolant; an ultraviolet irradiation section irradiating, with ultraviolet rays, the coolant to which the photocatalyst has been added for producing, in the coolant, a noble metal-carrying photocatalyst in which the noble metal is carried on a surface of the photocatalyst; and a noble metal-carrying photocatalyst injection section injecting the coolant containing the noble metal-carrying photocatalyst into the reactor primary system.

The invention provides a lighting device (1) comprising (i) a light source (10) configured to generate light source light (11), and (ii) a light converter (100) configured to convert at least part of the light source light (11) into visible converter light (121), wherein the light converter (100) comprises a polymeric host material (110) with light converter nanoparticles (120) embedded in the polymeric host material (110), wherein the polymeric host material (110) is based on radical polymerizable monomers, wherein the polymeric host material comprises a poly acrylate polymer and wherein the light converter nanoparticles (120) comprise Ag (silver) nanoparticles having mean dimensions below 3 nm.