An incipient wetness impregnation method for preparing a tin-containing zeolitic material having framework type BEA, a novel tin-containing zeolitic material having framework type BEA and its use.

Provided are a novel form of AEI zeolite, a novel synthesis technique for producing pure phase AEI zeolite, a catalyst comprising the AEI zeolite in combination with a metal, and methods of using the same.

A new family of a microporous crystalline metallophosphate-based materials designated SAPO-80 has been synthesized. These metallophosphate-based materials are represented by the empirical formula
R.sup.p+.sub.rM.sub.w.sup.2+E.sub.xPSi.sub.yO.sub.z
where R is a quaternary ammonium cation such as ,-bis(dimethylethylammonium)-p-xylene, E is a framework element such as aluminum or gallium and the framework may optionally contain a divalent framework metal M such as magnesium or zinc. The microporous SAPO-80 compositions are characterized by having the AFX topology and have catalytic properties for carrying out various hydrocarbon conversion processes and separating properties for separating at least one component.

The invention relates to the use of a catalyst as a passive nitrogen oxide adsorber, which has a carrier substrate, a zeolite, palladium, and platinum, wherein the palladium is provided in a quantity of 0.01 to 10 wt. %, based on the sum of the weights of zeolite, platinum, and palladium and calculated as a palladium metal, and platinum in a quantity of 0.1 to 10 wt. %, based on the weight of the palladium and calculated as a platinum metal. The invention also relates to the use of said catalyst in connection with a SCR catalyst in an exhaust gas system.

Systems and methods are provided for selective oxidation of CO and/or C.sub.3 hydrocarbonaceous compounds in a reaction environment including hydrocarbons and/or hydrocarbonaceous components. The selective oxidation can be performed by exposing the CO and/or C.sub.3 hydrocarbonaceous compounds to a catalytic metal that is encapsulated in a small pore zeolite. The small pore zeolite containing the encapsulated metal can have a sufficiently small pore size to reduce or minimize the types of hydrocarbons or hydrocarbonaceous compounds that can interact with the encapsulated metal.

It is intended to provide a novel zeolite with a rare earth element-substituted framework which has a higher amount of NOx adsorbed and a method for producing the same, and a NOx adsorption member and a catalyst for automobile exhaust gas, etc. comprising the same. The present invention provides a zeolite with a rare earth element-substituted framework, comprising at least a zeolite and at least one rare earth element selected from the group consisting of Ce, La, Nd and Pr, wherein a content ratio of the rare earth element is 1 to 15% by mass in total based on the total amount, and one or some of Al and/or Si atoms constituting the framework of the zeolite are replaced with the rare earth element.

Systems and methods are provided for selective oxidation of CO and/or C.sub.3 hydrocarbonaceous compounds in a reaction environment including hydrocarbons and/or hydrocarbonaceous components. The selective oxidation can be performed by exposing the CO and/or C.sub.3 hydrocarbonaceous compounds to a catalytic metal that is encapsulated in a small pore zeolite. The small pore zeolite containing the encapsulated metal can have a sufficiently small pore size to reduce or minimize the types of hydrocarbons or hydrocarbonaceous compounds that can interact with the encapsulated metal.

A catalyst for the carbonylation of dimethyl ether to methyl acetate. The catalyst comprises a zeolite, such as a mordenite zeolite, at least one Group IB metal, such as copper, and/or at least one Group VIII metal, such as iron, and at least one Group IIB metal, such as zinc. Such a catalyst with combined metals provides enhanced catalytic activity, improved stability, and improved selectivity to methyl acetate, and does not require a halogen promoter, as compared to a metal-free or copper only zeolite.

A method for producing a fluoride functionalized zeolite catalyst is described, having a F/Si molar ratio of 0.1:1-3:1. The method involves mixing a fluoride salt with zeolite components to form a gel, which is then hydrothermally treated and calcined. The fluoride functionalized zeolite catalyst may be used for cracking an olefin stream into ethylene, propylene, and butylene, with high selectivity towards propylene. The fluoride functionalized zeolite catalyst may be used for 50 or more hours with a stable conversion rate and low coke formation.

Disclosed is an in-situ preparation method for a catalyst for Reaction I: methanol and/or dimethyl ether with toluene are used to prepare light olefins and co-produce para-xylene, and/or Reaction II: methanol and/or dimethyl ether with benzene are used to prepare at least one of toluene, para-xylene and light olefins, comprising: contacting at least one of a phosphorus reagent, a silylation reagent and water vapor with a molecular sieve in a reactor to prepare, in situ, the catalyst for the Reaction I and/or the Reaction II, wherein the reactor is a reactor of the Reaction I and/or the Reaction II. By directly preparing a catalyst in a reaction system, the entire chemical production process is simplified, the catalyst preparation and transfer steps are saved, and the operation thereof is easy. The catalyst prepared in situ can be directly used for in situ reactions.