The producing method includes: (I) providing an active energy ray curable resin composition for mold surface release treatment between a mold having uneven microstructure on its surface and a substrate, and after curing the resin composition by irradiation with an active energy ray, peeling off the substrate together with a cured article of the active energy ray curable resin composition from the surface of the mold, thereby performing a release treatment to the surface of the mold; and (II), after step (I), providing an active energy ray curable resin composition for shaping between the substrate and the mold, the surface of which has been treated by the release treatment, and after curing the resin composition by an active energy ray, peeling off the substrate together with a cured article of the active energy ray curable resin composition for shaping from the surface of the mold.

The producing method includes: (I) providing an active energy ray curable resin composition for mold surface release treatment between a mold having uneven microstructure on its surface and a substrate, and after curing the resin composition by irradiation with an active energy ray, peeling off the substrate together with a cured article of the active energy ray curable resin composition from the surface of the mold, thereby performing a release treatment to the surface of the mold; and (II), after step (I), providing an active energy ray curable resin composition for shaping between the substrate and the mold, the surface of which has been treated by the release treatment, and after curing the resin composition by an active energy ray, peeling off the substrate together with a cured article of the active energy ray curable resin composition for shaping from the surface of the mold.

This application provides a coating film having excellent durability and wear resistance that, when applied to a mold surface, has excellent releasability (non-adhesiveness) over a long period of time, and a fluoropolymer coating composition that is able to form such a coating film. The fluoropolymer coating composition contains a fluoropolymer and a fluoro oil, where the decomposition temperature of the fluoro oil is higher than the melting point of the fluoropolymer.

This application provides a coating film having excellent durability and wear resistance that, when applied to a mold surface, has excellent releasability (non-adhesiveness) over a long period of time, and a fluoropolymer coating composition that is able to form such a coating film. The fluoropolymer coating composition contains a fluoropolymer and a fluoro oil, where the decomposition temperature of the fluoro oil is higher than the melting point of the fluoropolymer.

Provided is a release agent for vulcanized rubber molding, the release agent exhibiting good mold releasability between a mold and a rubber after vulcanization and capable of being easily removed after production. The release agent for vulcanized rubber molding contains a polyoxyalkylene glyceryl ether (A). The polyoxyalkylene glyceryl ether (A) contains 50% to 95% by mass of oxyethylene groups in 100% by mass of oxyalkylene groups. The polyoxyalkylene glyceryl ether (A) preferably has a number-average molecular weight of 2,000 to 20,000.

Provided is a release agent for vulcanized rubber molding, the release agent exhibiting good mold releasability between a mold and a rubber after vulcanization and capable of being easily removed after production. The release agent for vulcanized rubber molding contains a polyoxyalkylene glyceryl ether (A). The polyoxyalkylene glyceryl ether (A) contains 50% to 95% by mass of oxyethylene groups in 100% by mass of oxyalkylene groups. The polyoxyalkylene glyceryl ether (A) preferably has a number-average molecular weight of 2,000 to 20,000.

Disclosed is an emulsion formed using, as an emulsifier, 0.01 to 30 parts by weight of a perfluoroalkylethyl phosphonic acid salt represented by the general formula: C.sub.nF.sub.2n+1CH.sub.2CH.sub.2P(O)(OM.sup.1)(OM.sup.2) [III] (M.sup.1: a hydrogen atom, ammonium salt, or organic amine salt, M.sup.2: an ammonium salt or organic amine salt, n: 1 to 6), based on 100 parts by weight of a perfluoropolyether oil represented by the general formula: RfO(C.sub.3F.sub.6O).sub.p(C.sub.2F.sub.4O), (CF.sub.2O), Rf [I] (Rf and Rf: C.sub.1-C.sub.5 perfluoroalkyl groups, p+q+r: 2 to 200) or the general formula: F(CF.sub.2CF.sub.2CF.sub.2O).sub.nCF.sub.2CF.sub.3 [II](n: 2 to 100), or a perfluorocarbon compound. In spite of using, as an emulsifier, a compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, the emulsion exhibits excellent emulsification stability, and therefore can be effectively used as a surface-treating agent, such as a mold-releasing agent.

Disclosed is an emulsion formed using, as an emulsifier, 0.01 to 30 parts by weight of a perfluoroalkylethyl phosphonic acid salt represented by the general formula: C.sub.nF.sub.2n+1CH.sub.2CH.sub.2P(O)(OM.sup.1)(OM.sup.2) [III] (M.sup.1: a hydrogen atom, ammonium salt, or organic amine salt, M.sup.2: an ammonium salt or organic amine salt, n: 1 to 6), based on 100 parts by weight of a perfluoropolyether oil represented by the general formula: RfO(C.sub.3F.sub.6O).sub.p(C.sub.2F.sub.4O), (CF.sub.2O), Rf [I] (Rf and Rf: C.sub.1-C.sub.5 perfluoroalkyl groups, p+q+r: 2 to 200) or the general formula: F(CF.sub.2CF.sub.2CF.sub.2O).sub.nCF.sub.2CF.sub.3 [II](n: 2 to 100), or a perfluorocarbon compound. In spite of using, as an emulsifier, a compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, the emulsion exhibits excellent emulsification stability, and therefore can be effectively used as a surface-treating agent, such as a mold-releasing agent.

The invention provides a method for producing ophthalmic lenses, preferably contact lenses, more preferably silicone hydrogel contact lenses. This method involves applying a coat of catanionic vesicles onto the molding surfaces of a mold. By having a coat of catanionic vesicles on the molding surfaces of a mold, mold separation force and lens defects generated during mold opening and de-molding process can be substantially reduced.

The invention provides a method for producing ophthalmic lenses, preferably contact lenses, more preferably silicone hydrogel contact lenses. This method involves applying a coat of catanionic vesicles onto the molding surfaces of a mold. By having a coat of catanionic vesicles on the molding surfaces of a mold, mold separation force and lens defects generated during mold opening and de-molding process can be substantially reduced.