Acid-functionalized copolymers of methyl methacrylate having relatively high glass transition temperatures and molecular weights may be employed to manufacture articles having high light transmission values, low haze, high heat resistance, and high environmental stability, which are useful as optical protection films, zero-zero optical retardation films, and compensation films as well as lighting pipes and optical imaging lenses.

The present invention aims to provide a heat-shrinkable polyester film roll having decreased generation of wrinkles or longitudinal shrink mark. The present invention provides a film roll of a heat shrinkable polyester film, wherein a polyester of the polyester film contains recycled raw material from a PET bottle and an acid component of the polyester comprises isophthalic acid, and the film roll satisfies a specific average value of a shrinkage, specific isophthalic acid ratio, and specific thickness unevenness.

An ultra-high molecular weight, ultra-fine particle size polyethylene has a viscosity average molecular weight (Mv) greater than 1×10.sup.6. The polyethylene is spherical or are sphere-like particles having a mean particle size of 10-100 μm, having a standard deviation of 2-15 μm and a bulk density of 0.1-0.3 g/mL. Using the polyethylene as a basic polyethylene, a grafted polyethylene can be obtained by means of a solid-phase grafting method; and a glass fiber-reinforced polyethylene composition comprising the polyethylene and glass fibers, and a sheet or pipe prepared therefrom; a solubilized ultra-high molecular weight, ultra-fine particle size polyethylene; and a fiber and a film prepared from the solubilized ultra-high molecular weight, ultra-fine particle size polyethylene may also be obtained. The method has simple steps, is easy to control, has a relatively low cost and a high repeatability, and can realize industrialisation.

An ultra-high molecular weight, ultra-fine particle size polyethylene has a viscosity average molecular weight (Mv) greater than 1×10.sup.6. The polyethylene is spherical or are sphere-like particles having a mean particle size of 10-100 μm, having a standard deviation of 2-15 μm and a bulk density of 0.1-0.3 g/mL. Using the polyethylene as a basic polyethylene, a grafted polyethylene can be obtained by means of a solid-phase grafting method; and a glass fiber-reinforced polyethylene composition comprising the polyethylene and glass fibers, and a sheet or pipe prepared therefrom; a solubilized ultra-high molecular weight, ultra-fine particle size polyethylene; and a fiber and a film prepared from the solubilized ultra-high molecular weight, ultra-fine particle size polyethylene may also be obtained. The method has simple steps, is easy to control, has a relatively low cost and a high repeatability, and can realize industrialisation.

The present disclosure relates to a polyester resin blend, a polyester film and a preparation method of the same. The polyester resin blend is capable of providing a heat shrinkable label that is transparent and has excellent shrinkage even if it contains recycled polyethylene terephthalate as well as virgin polyethylene terephthalate. In addition, the heat shrinkable label can be reused while attached to a PET container, etc., and is expected to be useful for providing continuously usable plastics that have been recently attracting attention.

The present disclosure relates to a polyester resin blend, a polyester film and a preparation method of the same. The polyester resin blend is capable of providing a heat shrinkable label that is transparent and has excellent shrinkage even if it contains recycled polyethylene terephthalate as well as virgin polyethylene terephthalate. In addition, the heat shrinkable label can be reused while attached to a PET container, etc., and is expected to be useful for providing continuously usable plastics that have been recently attracting attention.

It is provided that a method for producing a biaxially oriented polyester film that can be used for industrial and packaging applications. A method for producing a biaxially oriented polyester film, comprising: a step of feeding a polyester resin into an extruder, a step of extruding the molten polyester resin from an extruder to obtain a molten resin sheet at 250 to 310° C., a step of attaching the molten resin sheet closely to a cooling roll by an electrostatic application method to obtain an unstretched sheet, and a step of biaxially stretching the unstretched sheet, wherein the polyester resin fulfills the following (A) to (C): (A) the polyester resin comprises a polyethylene furandicarboxylate resin composed of a furandicarboxylic acid and ethylene glycol; (B) an intrinsic viscosity of the polyester resin is 0.50 dL/g or more; (C) a melt specific resistance value at 250° C. of the polyester resin is 3.0×10.sup.7 Ω.Math.cm or less.

It is provided that a method for producing a biaxially oriented polyester film that can be used for industrial and packaging applications. A method for producing a biaxially oriented polyester film, comprising: a step of feeding a polyester resin into an extruder, a step of extruding the molten polyester resin from an extruder to obtain a molten resin sheet at 250 to 310° C., a step of attaching the molten resin sheet closely to a cooling roll by an electrostatic application method to obtain an unstretched sheet, and a step of biaxially stretching the unstretched sheet, wherein the polyester resin fulfills the following (A) to (C): (A) the polyester resin comprises a polyethylene furandicarboxylate resin composed of a furandicarboxylic acid and ethylene glycol; (B) an intrinsic viscosity of the polyester resin is 0.50 dL/g or more; (C) a melt specific resistance value at 250° C. of the polyester resin is 3.0×10.sup.7 Ω.Math.cm or less.

The present invention refers to a structure comprising a biaxially oriented polypropylene (BOPP) film having at least one layer comprising a homopolymer of propylene which layer is in contact with an oil phase, the homopolymer of propylene has a) a content of isotactic pentads in the range from 95% to 98%, and b) a content of ash of not more than 30 ppm, based on the total weight of the homopolymer of propylene, characterized in that the oil phase has an absorbance value of ≤0.1, relative to the pure oil, as determined spectrophotometrically at a wavelength of 860 nm by the reduction of transmitted light intensity. The present invention further refers to the use of a biaxially oriented polypropylene (BOPP) film for making capacitors comprising said structure, wherein the oil phase has an absorbance value of ≤0.1, relative to the pure oil, as determined spectrophotometrically at a wavelength of 860 nm by the reduction of transmitted light intensity as well as the use of the homopolymer of propylene for increasing the life time of a capacitor.

To provide a method for producing a polyamide resin film by using a polyamide resin obtained through polymerization of a regenerated monomer used as a recycled material. Provided is a method for producing a polyamide resin film, including: (1) a step of producing a monomer from a raw material (A) for depolymerization, (2) a step of producing a polyamide resin (B) through polymerization using a raw material containing the monomer. (3) a step of refining the polyamide resin (B), and (4) a step of producing an unstretched film using a starting material containing the refined polyamide resin (B), and stretching the unstretched film.