The present invention provides a method of manufacturing a three-dimensional product having uniform mechanical properties using an SLS 3D printer including the steps of: preparing a mixed powder material by mixing resin powder and glass bubbles, wherein the specific gravity of the glass bubbles is from about 0.8 to about 1.2 times that of the resin powder; supplying the mixed powder material to the 3D printer using a roller; and selectively sintering the mixed powder material by irradiating the powder material using a laser based on 3D data of the product to be manufactured.

A manufacturing process, which includes: (i) preparing a preform; (ii) laying the preform within a mold; (iii) heating the mold to a predetermined temperature; and (iv) injecting a modified resin system, wherein the modified resin system is formulated to have a viscosity below a threshold viscosity at a specific temperature and a high level of toughness. In one embodiment, the modified resin system contains a combination of epoxies, a curing agent, core-shell rubber particles, a thermoplastic material in an amount of less than 7% by weight, wherein in a cured condition, the thermoplastic material is separated into aggregate domains from the base resin, each aggregate domain having an island-like morphology.

In accordance with one aspect of the presently disclosed inventive concepts, a product includes a porous three-dimensional (3D) printed polymer structure having elastomeric shape memory, where the structure includes a material comprising a plurality of gas-filled microballoons. The 3D printed polymer structure has hierarchical porosity.

A resin composition containing heat-expandable microspheres including a thermoplastic resin shell and a thermally vaporizable blowing agent encapsulated therein and at least one base resin selected from rubbers, olefin resins and thermoplastic elastomers. The thermoplastic resin is a polymer of a polymerizable component containing N-substituted maleimide and a nitrile monomer containing methacrylonitrile. Also disclosed are molded articles manufactured by molding the resin composition.

The invention provides a method of connecting together two unit elements (4, 4) of a fluid transport pipe, each unit pipe element being made of metal alloy and being covered in an outer insulating coating (6, 6) made of a thermoplastic material, with the exception of an end portion that does not have an outer insulating coating, the method comprising a step of butt-welding together two unit pipe elements at their end portions having no outer insulating coating, a step of mechanically assembling at least two rigid shells (14, 16) made of a thermoplastic material on the end portions of the unit pipe elements not having an outer insulating coating, and a step of keeping the shells sealed against the outer insulating coating of the two unit pipe elements.

A composite containing hollow ceramic spheres and a preparation method are provided. The composite includes an impact-resistant gradient complex part containing a hollow ceramic sphere complex, prepared by using a 3D printing method and a hollow ceramic sphere-high polymer complex dielectric material obtained in a blending and fusing way. The obtained composite has the characteristics of relatively low density and high strength. The impact-resistant gradient complex part is a layered complex, the composition and properties of the complex may be regulated in a direction vertical to a layer according to a design, for example, mechanical properties of the complex are transitioned from soft to hard to form gradient change by regulating the change of the composition, and meanwhile, the thickness among layers with different properties is accurately controlled as required. The dielectric, heat conducting and mechanical properties of the hollow ceramic sphere-high polymer complex dielectric material are greatly improved.

A rubber composition for vulcanization molding which can be manufactured into a rubber product with good dimensional stability, good appearance and sufficiently light weight, a process for manufacturing the same, and applications thereof. A rubber composition for vulcanization molding containing hollow particles and a base rubber, wherein the hollow particles are composed of a thermoplastic resin shell and a thermally vaporizable blowing agent encapsulated therein and have a specified further expansion ratio, and the base rubber has a Mooney viscosity ML (1+4) ranging from 5 to 90 at 100 C. Also disclosed is a process for manufacturing the rubber composition, hollow particles used for manufacturing the rubber composition, a masterbatch including the hollow particles and a rubber product manufactured from the rubber composition.

A composite panel for use in applications such as mobile homes, boats, buses, RVs, or other panels used typically in transportation applications, where a single piece, water resistant, lightweight panel with patterned high-strength areas is needed. The composite panel generally includes internal preforms made of low-density material such as urethane foam, which create patterned structural portions of the panel during the molding process. The patterned structural portions are formed by a maze-like region within a mold, into which composite matrix material is infused. The patterned structural portions have high strength compared to the other regions of the panel, and can be used for structural support or for retaining fasteners for appliances, walls, etc.

The present disclosure is drawn to material sets for 3-dimensional printing, 3-dimensional printing systems, and 3-dimensional printed parts. A material set can include a powder bed material of composite particles including glass beads coated with polyamide-12 polymer. The composite particles can have an average particle size from 20 m to 200 m, and the polyamide-12 polymer can include greater than 80 meq/g carboxylic end groups and less than 40 meq/g amino end groups. The fusing agent can include an energy absorber capable of absorbing electromagnetic radiation to produce heat.

The invention relates to a composition that includes a polyolefin, hollow glass microspheres, a polar semicrystalline thermoplastic additive, and at least one of an impact modifier or a compatibilizer. Articles made from the composition, a method of making such an article by melt processing the composition, and the use of the composition are also disclosed.