The present technology provides a carboxylic acid-modified nitrile-based copolymer latex including a carboxylic acid-modified nitrile-based copolymer including a conjugated diene-based monomer-derived unit, an ethylenic unsaturated nitrile-based monomer-derived unit, and an ethylenic unsaturated acid monomer-derived unit, wherein the carboxylic acid-modified nitrile-based copolymer latex satisfies General Formula 1 and General Formula 2.

Methods and processes are described that enable the manufacture of a superior thin-walled mold from which higher-quality, less-costly disposable gloves can be more efficiently produced. The method can include creating a glove form in a sacrificial material; electroforming an electroformed master from the glove form; removing sacrificial material from the electroformed master; creating a tertiary form from the electroformed master; forming an initial copper layering on the tertiary form; and developing the initial copper layering into a thick copper plating to create a copper mold for gloves.

The present technology relates to a latex composition for dip molding comprising a carboxylic acid-modified nitrile-based copolymer latex satisfying General Formulas 1 and 2, wherein the carboxylic acid-modified nitrile-based copolymer includes a conjugated diene-based monomer-derived unit, an ethylenic unsaturated nitrile-based monomer-derived unit, and an ethylenic unsaturated acid monomer-derived unit, and a molded article.

Disclosed is a flexible barrier glove manufactured by coating a glove liner with a mixture that includes polyurethane resin and an antibacterial agent.

A crosslinking agent which is based on an aluminate complex salt of a hydroxyl group-containing organic compound, which crosslinks a carboxy group and a nitrile group. When the crosslinking agent is added to a carboxy group-denatured NBR latex, gloves having flexibility and a strength comparable to those of natural rubber gloves can be manufactured. Furthermore, the excellent creep resistance is a big characteristic. Moreover, unlike normal sulfur vulcanization gloves, the gloves do not contain sulfur and a vulcanization accelerator, and do not necessarily require addition of zinc oxide.

An elastomeric article is formed from a blend of nitrile rubber and polychloroprene rubber. The elastomeric article can be a glove, such as a medical exam glove. The elastomeric article is softer than a conventional nitrile elastomeric article. The elastomeric article is formed from a blended rubber latex emulsion of nitrile and polychloroprene. The blended rubber latex emulsion may be free of sulfur and vulcanization accelerators.

An improved glove has both anatomically correlating stress relief zones and/or reinforced zones to add support in areas opposite the stress relief zones to keep bunching or slipping of the glove from interfering with the bending of the user's joints. The glove may have corrugated relief zones over some or all of the joints and knuckles of the hand, wherein the relief zones are formed of peaks and valleys. A relief zone can also be provided over the webbing between the thumb and the palm. The vertical or longitudinal relief zones provide for improved glove quality while keeping manufacturing difficulty and costs at a minimum.

The invention provides a novel hydrophilic polymer and rubber polymer microparticles blend coating formulation and compositions thereof for rubber gloves to improve wet donning properties for easy application. More particularly, the invention relates to a novel hydrophilic polymer and rubber polymer microparticles blend coating formulation and compositions thereof, and their use on gloves to form hydrophilic and flexible coatings with durable lubricity. The gloves of the invention exhibit good donnability, tensile strength, elongation to break, and stress at 500% elongation.

The invention relates to a method to manufacture an elastomeric article includes preparing a former for shaping the elastomeric article; dipping the former into a coagulant solution which including one or more one or more polyvalent metal salt, surfactant, wetting agents, anti-tack materials, non-settling agents, and biocide; dipping the coagulant-coated former into a synthetic latex composition from 20° C. to 40° C. at least once to create the elastomeric article; pre-leaching the elastomeric article for not more than 10 times; vulcanizing the elastomeric article to enable effective crosslinking; surface treating the vulcanized elastomeric article form 60° C. to 140° C.; post-leaching the elastomeric article at temperature of 30° C. to 95° C.; applying donning aid to the elastomeric article; drying the elastomeric article; and stripping the elastomeric article from the former. The elastomeric article has a thickness of 0.001 to 5 mm, a minimum tensile strength of 7 MPa, and an elongation above 300%.

A method of making a polymer article comprises the steps of making a polymer solution by mixing a first compound containing carbodiimide groups with a second compound containing carboxylated groups, applying the polymer solution to a former, wherein the step of applying occurs within 2 hours of the making of the polymer solution, and curing the polymer solution. The polymer solution can have a pH adjuster consisting of ammonium hydroxide.