An embodiment of the present invention provides a thermosensitive recording material and a method for manufacturing the same. The thermosensitive recording material includes, on a support, a thermosensitive recording layer containing a polyvinyl alcohol and a color development component; and a protective layer containing a resin component, in this order from the support side. At least one of the thermosensitive recording layer or the protective layer further contains a styrene-isoprene resin.

The invention relates to a heat-sensitive recording material, comprising a supporting substrate and a heat-sensitive color-forming layer, which contains at least one color former and at least one phenol-free color developer, characterized in that the at least one color developer is a compound of formula (I), wherein Ar is an aryl residue, a heteroaryl residue, or a benzyl residue and Y is an aryl residue, a heteroaryl residue, a benzyl residue, an aryloxy residue, a heteroaryloxy residue, a benzyloxy residue, an arylamino residue, a heteroarylamino residue, or a benzylamino residue. The invention further relates to a method for producing said heat-sensitive recording material. ##STR00001##

A method of imparting color to a plastic substrate comprising applying to the substrate, or incorporating within the substrate, a diacetylene compound of general formula (I) wherein n=1 to 20; R.sup.1=an optionally substituted C.sub.1-20 alkyl group which may contain heteroatoms; T=H, an optionally substituted C.sub.1-20 alkyl group which may contain heteroatoms or (CH.sub.2).sub.mC(O)-Q.sup.2R.sup.2; Q.sup.1=NH, CO, NHCONH, OCONH, COS, NHCSNH or NR.sup.3, wherein m, Q.sup.2 and R.sup.2 are independently selected from the same groups as n, Q.sup.1 and R.sup.1 respectively; R.sup.3 is an optionally substituted C.sub.1-20 alkyl group which may contain heteroatoms; and irradiating the substrate to impart color to the substrate is described.

A method for the secure protection of a portion of the surface of an official document bearing markings, in which: a transparent security layer (17) is selected, the layer including at least one semi-transparent printed image including at least one transparent binder and at least one thermochromic pigment (14, 13, 12, 11); the semi-transparent printed image reveals at least one semi-transparent visible pattern in a first non-activated state at least a first temperature, such that the markings can be seen through the image, the pattern not being visible in a second activated state at least a second temperature different from the first temperature. A device for the secure protection of a portion of the surface of an official document and such an official document are also described.

The invention relates to a self-adhesive, heat-sensitive recording material, comprising a carrier substrate, a heat-sensitive, color-forming layer that is applied on one side of the carrier substrate and contains at least a non-phenolic color developer in and at least one color former, a siliconized layer on the upper side of the heat-sensitive, color-forming layer that is applied on the carrier substrate, as well as an adhesive layer on the side of the carrier substrate facing away from the heat-sensitive, color-forming layer.

An aqueous dispersion resin composition contains a first polymer produced by polymerizing a first monomer component containing (meth)acrylamide and a second polymer produced by polymerizing a second monomer component containing a carboxy group-containing vinyl monomer, wherein at least a portion of the carboxy group in the second polymer is neutralized.

An object of the invention is to provide a recording material and recording sheet having excellent color-developing performance, storage stability, etc. A recording material having good color-developing performance and storage stability may be obtained by using a specific compound having a benzhydrol skeleton as an additive in a recording material employing color development through a reaction between a color former and a color-developing agent.

A heat-sensitive recording material suitable for offset printing, having a web-shaped substrate, having a front side and a reverse side opposite the front side, a heat-sensitive recording layer disposed at least on one of the two sides of the web-shaped substrate having at least one dye precursor and at least one (color) developer reactive with the dye precursor. The heat-sensitive recording layer has particles including an organic surface whose extent in the direction of the thickness of web-shaped substrate and heat-sensitive recording layer is greater than the thickness of the heat-sensitive recording layer.

A heat-sensitive recording material suitable for offset printing, having a web-shaped substrate, having a front side and a reverse side opposite the front side, a heat-sensitive recording layer disposed at least on one of the two sides of the web-shaped substrate having at least one dye precursor and at least one (color) developer reactive with the dye precursor. The heat-sensitive recording layer has particles including an organic surface whose extent in the direction of the thickness of web-shaped substrate and heat-sensitive recording layer is greater than the thickness of the heat-sensitive recording layer.

Provided are a packaging sheet and a packaging container where it is unnecessary to paste a printed label and disappearance or color development due to friction or the like after thermal printing do not occur. The packaging sheet includes a heat seal layer 10 for thermally welding by heating, a heat-sensitive layer 40 including a color developing material that develops a color by heating, and a base material layer 70 that secures the strength and protects the heat-sensitive layer 40. The heat seal layer 10, the heat-sensitive layer 40, and the base material layer 70 are provided in this order from a back surface side in a thickness direction. The packaging sheet is transparent before the heat-sensitive layer 40 develops the color.