A method of selectively catalysing the reduction of oxides of nitrogen (NO.sub.x) including nitrogen monoxide in an exhaust gas of a stationary source of NO.sub.x emissions also containing oxides of sulfur (SO.sub.x) comprising the steps of passively oxidising nitrogen monoxide to nitrogen dioxide (NO.sub.2) over an oxidation catalyst comprising a platinum group metal so that a NO.sub.2/NO.sub.x content is from 40-60%; introducing a nitrogenous reductant into the exhaust gas; and contacting exhaust gas having the 40-60% NO.sub.2/NO.sub.x content and containing the nitrogenous reductant with a selective catalytic reduction (SCR) catalyst comprising an aluminosilicate zeolite promoted with copper.

There is disclosed a highly crystalline, small crystal, ferrierite zeolite prepared from a gel containing a source of silica, alumina, alkali metal and a combination of two templating agents. The resulting material includes ferrierite crystals having a particle size of about or less than about 200 nm. The desired crystal size can be achieved by using a specific composition of the gel. The purity of the material and the crystal size was determined by using X-ray powder diffraction and scanning electron microscopy. The material has excellent surface area and micropore volume as determined by nitrogen adsorption.

There is disclosed a highly crystalline, small crystal, ferrierite zeolite prepared from a gel containing a source of silica, alumina, alkali metal and a combination of two templating agents. The resulting material includes ferrierite crystals having a particle size of about or less than about 200 nm. The desired crystal size can be achieved by using a specific composition of the gel. The purity of the material and the crystal size was determined by using X-ray powder diffraction and scanning electron microscopy. The material has excellent surface area and micropore volume as determined by nitrogen adsorption.

The present invention provides a nitrogen oxide ultra-low emission and carbon negative emission system and a control method, and the system comprises: a carbon negative emission system, a nitrogen oxide ultra-low emission system, an air supply device and a flow control module. The carbon negative emission system is used for enabling biomass to produce inorganic carbon and pyrolysis gas/gasification gas to realize negative emission of carbon; the nitrogen oxide ultra-low emission system is used for enabling fuel to be in mixed combustion with the pyrolysis gas/gasification gas to remove nitrogen oxides, which realizes ultra-low emission of the nitrogen oxides; the air supply device is in communication with biomass pyrolysis coupling partial gasification via a first pipeline, the air supply device is in communication with the carbon negative emission system and the nitrogen oxide ultra-low emission system via a second pipeline, and the pyrolysis gas/gasification gas enters the nitrogen oxide ultra-low emission system via the second pipeline; the flow control module controls a flow ratio of a pyrolysis agent/gasification agent entering the carbon negative emission system and flow of the pyrolysis gas/gasification gas and air entering the nitrogen oxide ultra-low emission system.

A flameless thermal oxidizer apparatus for a gaseous stream containing hydrogen includes a vessel containing a ceramic matrix bed; and a dip tube extending into the ceramic matrix bed, the dip tube including a first flow path for a first stream having hydrogen therein, and a second flow path for a second stream having an oxidant therein to be mixed with the first stream for introduction into the ceramic matrix bed. A related method is also provided.

A flameless thermal oxidizer apparatus for a gaseous stream containing hydrogen includes a vessel containing a ceramic matrix bed; and a dip tube extending into the ceramic matrix bed, the dip tube including a first flow path for a first stream having hydrogen therein, and a second flow path for a second stream having an oxidant therein to be mixed with the first stream for introduction into the ceramic matrix bed. A related method is also provided.

Method of treating gas and gas treatment device, the gas treatment device comprising: a first chamber, comprising a first inlet, a first outlet and a first energy supply system, allowing the gas to enter the first chamber through the first inlet; a second chamber comprising a second outlet and a second energy supply system; a third chamber comprising a third inlet in communication with the first outlet and the second outlet; and a fourth chamber comprising a fourth inlet and a scrubbing system containing a solvent comprising water molecules (H.sub.2O), wherein the third outlet of the third chamber is in communication with the fourth inlet of the fourth chamber.

One aspect of the invention relates to a method comprising a single-stage conversion of an atmospheric pollutant, such as NO, NO.sub.2 and/or SO.sub.x in a first stream to one or more mineral acids and/or salts thereof by reacting with nonionic gas phase chlorine dioxide (ClO.sub.2.sup.0), wherein the reaction is carried out in the gas phase. Another aspect of the invention relates to a method comprising first adjusting the atmospheric pollutant concentrations in a first stream to a molar ratio of about 1:1, and then reacting with an aqueous metal hydroxide solution (MOH). Another aspect of the invention relates to an apparatus that can be used to carry out the methods disclosed herein. The methods disclosed herein are unexpectedly efficient and cost effective, and can be applied to a stream comprising high concentration and large volume of atmospheric pollutants.

One aspect of the invention relates to a method comprising a single-stage conversion of an atmospheric pollutant, such as NO, NO.sub.2 and/or SO.sub.x in a first stream to one or more mineral acids and/or salts thereof by reacting with nonionic gas phase chlorine dioxide (ClO.sub.2.sup.0), wherein the reaction is carried out in the gas phase. Another aspect of the invention relates to a method comprising first adjusting the atmospheric pollutant concentrations in a first stream to a molar ratio of about 1:1, and then reacting with an aqueous metal hydroxide solution (MOH). Another aspect of the invention relates to an apparatus that can be used to carry out the methods disclosed herein. The methods disclosed herein are unexpectedly efficient and cost effective, and can be applied to a stream comprising high concentration and large volume of atmospheric pollutants.

In one embodiment, a separation membrane includes: a porous support structure, wherein the porous support structure comprises a system of continuous pores connecting an inlet of the separation membrane to an outlet of the separation membrane; and at least one alkali metal hydroxide disposed within pores of the porous support structure. Other aspects and embodiments of the disclosed inventive concepts will become apparent from the detailed description, which, when taken in conjunction with the drawings, illustrate by way of example the principles of the invention.