Primary, secondary (1°,2°) alkylethylenediamine- and alkylpropylenediamine-appended variants of metal-organic framework are provided for CO.sub.2 capture applications. Increasing the size of the alkyl group on the secondary amine enhances the stability to diamine volatilization from the metal sites. Two-step adsorption/desorption profiles are overcome by minimzing steric interactions between adjacent ammonium carbamate chains. For instance, the isoreticularly expanded framework Mg.sub.2(dotpdc) (dotpdc.sup.4−=4,4″-dioxido-[1,1′:4′,1″-terphenyl]-3,3″-dicarboxylate), yields diamine-appended adsorbents displaying a single CO.sub.2 adsorption step. Further, use of the isomeric framework Mg-IRMOF-74-II or Mg.sub.2(pc-dobpdc) (pc-dobpdc.sup.4−=3,3-dioxidobiphenyl-4,4-dicarboxylate, pc=para-carboxylate) also leads to a single CO.sub.2 adsorption step with bulky diamines. By relieving steric interactions between adjacent ammonium carbamate chains, these frameworks enable step-shaped CO.sub.2 adsorption, decreased water co-adsorption, and increased stability to diamine loss. Variants of Mg.sub.2(dotpdc) and Mg.sub.2(pc-dobpdc) functionalized with large diamines such as N-(n-heptyl)ethylenediamine have utility as adsorbents for carbon capture applications.

Primary, secondary (1°,2°) alkylethylenediamine- and alkylpropylenediamine-appended variants of metal-organic framework are provided for CO.sub.2 capture applications. Increasing the size of the alkyl group on the secondary amine enhances the stability to diamine volatilization from the metal sites. Two-step adsorption/desorption profiles are overcome by minimzing steric interactions between adjacent ammonium carbamate chains. For instance, the isoreticularly expanded framework Mg.sub.2(dotpdc) (dotpdc.sup.4−=4,4″-dioxido-[1,1′:4′,1″-terphenyl]-3,3″-dicarboxylate), yields diamine-appended adsorbents displaying a single CO.sub.2 adsorption step. Further, use of the isomeric framework Mg-IRMOF-74-II or Mg.sub.2(pc-dobpdc) (pc-dobpdc.sup.4−=3,3-dioxidobiphenyl-4,4-dicarboxylate, pc=para-carboxylate) also leads to a single CO.sub.2 adsorption step with bulky diamines. By relieving steric interactions between adjacent ammonium carbamate chains, these frameworks enable step-shaped CO.sub.2 adsorption, decreased water co-adsorption, and increased stability to diamine loss. Variants of Mg.sub.2(dotpdc) and Mg.sub.2(pc-dobpdc) functionalized with large diamines such as N-(n-heptyl)ethylenediamine have utility as adsorbents for carbon capture applications.

Electronic device processing assemblies including an equipment front end module (EFEM) with at least one side storage pod attached thereto are described. The side storage pod has a side storage container. In some embodiments, an exhaust conduit extends between the chamber and a pod plenum that can contain a chemical filter proximate thereto. A supplemental fan may draw purge gas from the pod plenum through the chemical filter and route the gas through a return duct to an upper plenum of the EFEM. Methods and side storage pods in accordance with these and other embodiments are also disclosed.

Systems and methods use bimetallic alloy particles for converting hydrogen sulfide (H.sub.2S) to hydrogen (H.sub.2) and sulfur (S), typically during multiple operations. In a first operation, metal alloy composite particles can be converted to a composite metal sulfide. In a second operation, composite metal sulfide from the first operation can be regenerated back to the metal alloy composite particle using an inert gas stream. Pure, or substantially pure, sulfur can also be generated during the second operation.

Systems and methods use bimetallic alloy particles for converting hydrogen sulfide (H.sub.2S) to hydrogen (H.sub.2) and sulfur (S), typically during multiple operations. In a first operation, metal alloy composite particles can be converted to a composite metal sulfide. In a second operation, composite metal sulfide from the first operation can be regenerated back to the metal alloy composite particle using an inert gas stream. Pure, or substantially pure, sulfur can also be generated during the second operation.

A thermochemical energy storage system and method of storing thermal energy are described. The energy storing system described herein comprises a reactor comprising: a) a reactor with a CO.sub.2 sorbent including MgO; and b) a supercritical CO.sub.2 source with supercritical CO.sub.2 and H.sub.2O, wherein the supercritical CO.sub.2 source is in fluid communication with the reactor and the CO.sub.2 sorbent including MgO to allow flow of the supercritical CO.sub.2 and H.sub.2O between the supercritical CO.sub.2 source and the reactor, thereby allowing contact of CO.sub.2 with the CO.sub.2 sorbent comprising MgO.

A thermochemical energy storage system and method of storing thermal energy are described. The energy storing system described herein comprises a reactor comprising: a) a reactor with a CO.sub.2 sorbent including MgO; and b) a supercritical CO.sub.2 source with supercritical CO.sub.2 and H.sub.2O, wherein the supercritical CO.sub.2 source is in fluid communication with the reactor and the CO.sub.2 sorbent including MgO to allow flow of the supercritical CO.sub.2 and H.sub.2O between the supercritical CO.sub.2 source and the reactor, thereby allowing contact of CO.sub.2 with the CO.sub.2 sorbent comprising MgO.

A food waste disposer including a housing, a container disposed inside the housing and provided to accommodate food waste, an exhaust duct communicating with the container and provided to allow exhaust gas generated in the container to flow therein, a filter device including a catalytic filter part configured to filter the exhaust gas passed through the exhaust duct, and a deodorizing filter part configured to filter the exhaust gas passed through the catalytic filter part and communicating with an outside of the housing, and a condensation chamber configured to remove moisture in the exhaust gas flowing from the exhaust duct into the catalytic filter part of the filter device.

An ultraviolet air sterilizer for disinfecting bacterium and virus includes a shell, a sandwich activated carbon cloth filter element, a nanometer titanium dioxide screen filter, an ultraviolet light source, a heat sinking kit, and a fan. The shell includes a shell body and a cover plate. The shell body is provided with an air inlet and an opening. The cover plate is provided with an air outlet. The sandwich activated carbon cloth filter element, the nanometer titanium dioxide screen filter, the heat sinking kit and the fan are arranged sequentially along an air path from the air inlet to the air outlet. The ultraviolet light source is configured for emitting ultraviolet light to the nanometer titanium dioxide screen filter. The air sterilizer has a compact small-sized structure and effectively removes ambient gaseous as well as particulate pollutants and kills micro-organisms harmful to health and well being.

A secondary air system for an aircraft engine comprises an air flow path communicating between a source of pressurized cooling air and an air consuming component. A filter is disposed in the air flow path upstream from the air consuming component. The filter has at least one of: openings of a size selected for capturing suspended particles; and a filter surface material for binding with chemical contaminants.