An LED lighting fixture powered by a Metal-Organic Framework heat battery. The heat battery is formed of a canister, a MOF container comprised of a plurality of MOF tunnels, each MOF tunnel containing a powdered MOF material, a gate, and a plurality of thermoelectric devices. Below a certain adsorption activation temperature, the MOF material adsorbs a gas from the atmosphere. Above a certain desorption activation temperature, the MOF desorbs the gas. The heat from the adsorption is used to generate electrical current. The desorbed gas is captured to remove it from the atmosphere.

An LED lighting fixture powered by a Metal-Organic Framework heat battery. The heat battery is formed of a canister, a MOF container comprised of a plurality of MOF tunnels, each MOF tunnel containing a powdered MOF material, a gate, and a plurality of thermoelectric devices. Below a certain adsorption activation temperature, the MOF material adsorbs a gas from the atmosphere. Above a certain desorption activation temperature, the MOF desorbs the gas. The heat from the adsorption is used to generate electrical current. The desorbed gas is captured to remove it from the atmosphere.

The present invention provides processes for filtering undesired chemicals in streams of contaminated air for supply to confined areas. The processes provide (1) contacting air with a filter comprising by volume from about 5% to about 95% impregnated zirconium hydroxide, from about 5% to about 95% activated impregnated carbon, and optionally, up to about 50% ammonia removal material; and (2) supplying the contacted air to a confined area.

The present invention provides processes for filtering undesired chemicals in streams of contaminated air for supply to confined areas. The processes provide (1) contacting air with a filter comprising by volume from about 5% to about 95% impregnated zirconium hydroxide, from about 5% to about 95% activated impregnated carbon, and optionally, up to about 50% ammonia removal material; and (2) supplying the contacted air to a confined area.

Systems, devices and methods for submarine CO.sub.2 scrubbing are disclosed. The system may comprise an assembly including a sorbent, a scrubbing inlet configured to receive a first airflow during an adsorption mode. The first airflow may comprise air received from a cabin of a submarine. The assembly may be configured to flow the first airflow over and/or through the sorbent during the adsorption mode such that the sorbent removes a portion of CO.sub.2 entrained in the first airflow. The system may also include a scrubbing outlet configured to expel the scrubbed first airflow from the assembly into the cabin. The system may include an outside air inlet configured to receive a second airflow comprising outside air during a regeneration mode. The system may include a regeneration air outlet in configured to expel the second airflow after the second airflow has flowed over and/or through the sorbent during the regeneration mode.

Systems, devices and methods for submarine CO.sub.2 scrubbing are disclosed. The system may comprise an assembly including a sorbent, a scrubbing inlet configured to receive a first airflow during an adsorption mode. The first airflow may comprise air received from a cabin of a submarine. The assembly may be configured to flow the first airflow over and/or through the sorbent during the adsorption mode such that the sorbent removes a portion of CO.sub.2 entrained in the first airflow. The system may also include a scrubbing outlet configured to expel the scrubbed first airflow from the assembly into the cabin. The system may include an outside air inlet configured to receive a second airflow comprising outside air during a regeneration mode. The system may include a regeneration air outlet in configured to expel the second airflow after the second airflow has flowed over and/or through the sorbent during the regeneration mode.

The invention relates to regenerative, solid sorbent for adsorbing carbon dioxide from a gas mixture, with the sorbent including a modified polyamine and a nano-structured solid support. The modified polyamine is the reaction product of an amine and an aldehyde. The sorbent provides structural integrity, as well as high selectivity and increased capacity for efficiently capturing carbon dioxide from gas mixtures, including the air. The sorbent is regenerative, and can be used through multiple operations of absorption-desorption cycles.

A filtration device for an air purification appliance includes a first filtering cartridge structure containing a classic absorbent or adsorbent material selected from activated carbon or zeolite and a second, different filtering cartridge structure holding a filtering medium consisting of a specific adsorbent material which is porous and functionalized with at least one probe molecule in such a way as to trap aldehyde-type chemical contaminants.

A filtration device for an air purification appliance includes a first filtering cartridge structure containing a classic absorbent or adsorbent material selected from activated carbon or zeolite and a second, different filtering cartridge structure holding a filtering medium consisting of a specific adsorbent material which is porous and functionalized with at least one probe molecule in such a way as to trap aldehyde-type chemical contaminants.

In one embodiment, a separation membrane includes: a porous support structure; and at least one alkali metal hydroxide disposed within pores of the porous support structure. In another embodiment, a method for separating acidic gases from a gas mixture includes exposing the gas mixture to a separation membrane at an elevated temperature, where the separation membrane includes a porous support and at least one molten alkali metal hydroxide disposed within pores of the porous support.