A solid sorbent composition including calcium oxide, calcium aluminate, and a mixed metal oxide characterized by a perovskite crystalline structure, for example, lanthanum aluminate. The solid sorbent finds utility in capturing carbon dioxide from a gaseous stream containing carbon dioxide, such as emissions streams produced in combustion processes or streams derived from closed environments including airplanes, spaceships, and submarines. A reversible carbon dioxide process is disclosed involving (a) contacting a carbon dioxide-containing gaseous stream with the solid sorbent composition in a carbonator to produce a solid mixture containing calcium carbonate and a gaseous product stream reduced in carbon dioxide concentration; and (b) heating the solid mixture containing calcium carbonate in a calcinator (decarbonator) to regenerate the solid sorbent composition and produce a gaseous stream enriched in carbon dioxide.

The present invention describes the process of preparing ceramic materials for absorption of acidic gases, mainly carbon dioxide, in exhaust systems and/or present indoors. Ceramic materials are formed by a mixture of alkali carbonate with alkaline earth metal oxide/hydroxide associated with a binding component, but non-limiting. The alkali carbonate comprises sodium, potassium carbonate, or a mixture of both. The alkaline earth metal oxide/hydroxide may be formed from magnesium oxide or magnesium hydroxide as well as calcium oxide and/or calcium hydroxide.

The present invention describes the process of preparing ceramic materials for absorption of acidic gases, mainly carbon dioxide, in exhaust systems and/or present indoors. Ceramic materials are formed by a mixture of alkali carbonate with alkaline earth metal oxide/hydroxide associated with a binding component, but non-limiting. The alkali carbonate comprises sodium, potassium carbonate, or a mixture of both. The alkaline earth metal oxide/hydroxide may be formed from magnesium oxide or magnesium hydroxide as well as calcium oxide and/or calcium hydroxide.

A mixer for recirculating ash from solid fuel combustion with hydrated lime and water and to feed the mixture into a desulfurization reactor. The mixer includes a housing having a front wall, two outer vertical sidewalls, a rear wall, a top, and a bottom, the top includes a feed chute configured for the entry and addition of product to the mixer, and the front wall includes an opening for the mixture of product to exit. The mixer also includes a rotatable vertical shaft having an impeller, the impeller having a plurality of blades disposed on the vertical shaft in the same horizontal plane and distributed equidistantly about the circumference of the vertical shaft. The mixer also includes a vertical wall disposed within the housing forming a mixing region and a feeding region that is operably connected to the opening of the front wall.

A system and method for recovering sulfur in a copper smelting process, in which fine dust is removed from high-concentration SO.sub.2 flue gas from a matte smelting furnace, the flue gas is introduced into a fluidized bed carbothermic reduction tower and reduced by a carbon-based reducing agent to obtain reducing gas, which is introduced into a high temperature separator. The separated reducing gas contains unsaturated powder coke, and the reducing gas is condensed to obtain sulfur. The saturated powder coke entrained enters a desorption tower to desorb SO.sub.2 gas, and the desorbed powder coke enters a fluidized bed sulfur reduction tower. Part of the SO.sub.2 gas discharged from the desorption tower is discharged to the fluidized bed carbothermic reduction tower to produce sulfur, and the other part is introduced into a desulfurization tower.

A system and method for recovering sulfur in a copper smelting process, in which fine dust is removed from high-concentration SO.sub.2 flue gas from a matte smelting furnace, the flue gas is introduced into a fluidized bed carbothermic reduction tower and reduced by a carbon-based reducing agent to obtain reducing gas, which is introduced into a high temperature separator. The separated reducing gas contains unsaturated powder coke, and the reducing gas is condensed to obtain sulfur. The saturated powder coke entrained enters a desorption tower to desorb SO.sub.2 gas, and the desorbed powder coke enters a fluidized bed sulfur reduction tower. Part of the SO.sub.2 gas discharged from the desorption tower is discharged to the fluidized bed carbothermic reduction tower to produce sulfur, and the other part is introduced into a desulfurization tower.

A system and a process for capturing Carbon Dioxide (CO.sub.2) from flue gases are disclosed. The process comprises feeding a flue gas comprising CO.sub.2 to at least one Rotary Packed Bed (RPB) absorber rotating circularly. A solvent may be provided through an inner radius of the RPB absorber. The solvent may move towards an outer radius of the RPB absorber. The solvent may react with the flue gas in a counter-current flow. The process further includes passing the flue gas through at least one of a water wash and an acid wash to remove traces of the solvent present in the flue gas. Finally, the solvent reacted with the CO.sub.2 may be thermally regenerated for re-utilizing the solvent back in the process.

A system and a process for capturing Carbon Dioxide (CO.sub.2) from flue gases are disclosed. The process comprises feeding a flue gas comprising CO.sub.2 to at least one Rotary Packed Bed (RPB) absorber rotating circularly. A solvent may be provided through an inner radius of the RPB absorber. The solvent may move towards an outer radius of the RPB absorber. The solvent may react with the flue gas in a counter-current flow. The process further includes passing the flue gas through at least one of a water wash and an acid wash to remove traces of the solvent present in the flue gas. Finally, the solvent reacted with the CO.sub.2 may be thermally regenerated for re-utilizing the solvent back in the process.

A system and a process for capturing Carbon Dioxide (CO.sub.2) from flue gases are disclosed. The process comprises feeding a flue gas comprising CO.sub.2 to at least one Rotary Packed Bed (RPB) absorber rotating circularly. A solvent may be provided through an inner radius of the RPB absorber. The solvent may move towards an outer radius of the RPB absorber. The solvent may react with the flue gas in a counter-current flow. The process further includes passing the flue gas through at least one of a water wash and an acid wash to remove traces of the solvent present in the flue gas. Finally, the solvent reacted with the CO.sub.2 may be thermally regenerated for re-utilizing the solvent back in the process.

Various embodiments disclosed relate to sorbents for the oxidation and removal of mercury. The present invention includes removing mercury from a mercury-containing gas using a halide-promoted and optionally ammonium-protected sorbent that can include carbon sorbent, non-carbon sorbent, or a combination thereof.