A system for oxidizing nitrogen monoxide (NO) contained in exhaust gas injects a liquid oxidizing agent into the exhaust gas and simultaneously removes nitrogen oxides and sulfur oxides from exhaust gas using an organic catalyst. The system includes an absorption tank for storing an absorption solution containing an organic catalyst, the absorption tank communicating with an oxygen supply pipe for supplying oxygen-containing gas to the absorption tank; an absorption tower, extending upward from the absorption tank, through which the exhaust gas flows from an exhaust gas inlet duct to an exhaust gas outlet; a first injection unit to inject the absorption solution into the absorption tower; a second injection unit to inject an oxidizing agent solution into at least one of the inlet duct and the absorption tower; and an oxidizing agent supply unit for supplying the oxidizing agent solution to the second injection unit.

The present invention solves the existing problem of using very expensive oxidation reagents, such as H.sub.2O.sub.2 and ozone, in removal of NO.sub.x and SO.sub.x from flue gases, by performing simultaneous oxidation of NO.sub.x and SO.sub.x with atmospheric oxygen in a combined system for catalytic oxidation and wet-scrubbing of both NO.sub.x and SO.sub.x from a flue gas and manufacturing fertilisers. Two major configurations of the oxidation system are disclosed in the present invention. The first configuration operates on oxygen-enriched air to increase efficiency of the oxidation reaction and requires an additional oxygen concentrator unit. The second configuration operates on atmospheric air at ambient conditions and requires an additional catalyst activation unit. In the second configuration, the efficient oxidation process is carried out at low temperatures of about 30-90 C. in the presence of recovered and re-activated catalyst. This temperature is a result of the exothermic character of the reaction, and therefore, no heating is required in the process.

A NO.sub.x and SO.sub.x oxidation with atmospheric oxygen to remove NO.sub.x and SO.sub.x from flue gases. The combined system for catalytic oxidation and wet-scrubbing of NO.sub.x and SO.sub.x from a flue gas and manufacturing fertilizers includes: an air separation unit for separating atmospheric oxygen from air and producing an air stream enriched with atmospheric oxygen, an adsorption and oxidation reactor containing an oxidation catalyst and carrying out the catalytic oxidation of NO.sub.x and SO.sub.x by said oxygen to yield nitric and sulphuric acids, a separator and reactor control unit for separation of products and liquids and controlling the reaction; and a vessel containing ammonia streaming said ammonia into the reactor or into the control unit to react with the nitric and sulphuric acids and to yield the fertilizers.

The present disclosure discloses a dry desulfurizing and denitrificating agent and its preparation method and applications. The desulfurizing and denitrificating agent is made of raw materials comprising the following components based on 100 parts by weight of the desulfurizing and denitrificating agent: 30-60 parts by weight of TiO.sub.2, 10-30 parts by weight of ZrO.sub.2, 2-10 parts by weight of V.sub.2O.sub.5, 2-10 parts by weight of CoO, 1-8 parts by weight of Co.sub.2O.sub.3, 2-10 parts by weight of Fe.sub.2O.sub.3, 5-15 parts by weight of MnO.sub.2, and 2-10 parts by weight of KMnO.sub.4. The desulfurizing and denitrificating agent of the present disclosure has a good catalytic oxidation performance on sulfur dioxide and nitrogen oxides of flue gas, and a high rate of desulfurization and denitrification.

An air conditioning device is disclosed. The present air conditioning device comprises: a photocatalytic filter including a space through which air can pass and having a transition metal oxide formed in a nanotube form on the surface thereof, the transition metal oxide removing gases included in the air and including at least one of TiO.sub.2, ZnO, NiO, and WO.sub.3; and a light source for emitting light to the photocatalytic filter.

The invention discloses a method for simultaneously removing SO.sub.2 and NO.sub.x in flue gas: uniformly mixing a water-soluble ruthenium salt with ammonia water to obtain an aqueous solution of a ruthenium-amine complex; subjecting the flue gas and the aqueous solution of the ruthenium-amine complex to a countercurrent contact reaction under the temperature of 5-60 C., pH of 7.5-12 to obtain a solution A and purified gas; discharging the solution A of the step (2) into a crystallization tank to crystallize and separate an ammonium salt to obtain a solution B, returning the solution B to replace the aqueous solution of the ruthenium-amine complex. The invention utilizes the ruthenium-amine complex having a strong capability of complexing with NO as well as residual oxygen in the flue gas to carry out liquid phase catalytic oxidation to convert the NO.sub.x into ammonium nitrate, and the removal efficiency of the NO.sub.x and the SO.sub.2 is high.

Presented is a process for the regeneration of a deactivated nitrogen oxide decomposition catalyst used for the selective catalytic reduction of nitrogen oxides contained in a flue gas stream.

The present invention solves the existing problem of using very expensive oxidation reagents, such as H.sub.2O.sub.2 and ozone, in removal of NO.sub.x and SO.sub.x from flue gases, by performing simultaneous oxidation of NO.sub.x and SO.sub.x with atmospheric oxygen in a combined system for catalytic oxidation and wet-scrubbing of both NO.sub.x and SO.sub.x from a flue gas and manufacturing fertilisers. Two major configurations of the oxidation system are disclosed in the present invention. The first configuration operates on oxygen-enriched air to increase efficiency of the oxidation reaction and requires an additional oxygen concentrator unit. The second configuration operates on atmospheric air at ambient conditions and requires an additional catalyst activation unit. In the second configuration, the efficient oxidation process is carried out at low temperatures of about 30-90 C. in the presence of recovered and re-activated catalyst. This temperature is a result of the exothermic character of the reaction, and therefore, no heating is required in the process.

An ozonation-based method for producing a cementitious material comprises the steps of: (1) mixing a flue gas with an ozone-containing gas to form a mixed flue gas; and introducing the mixed flue gas into an absorption tower, where the mixed flue gas undergoes dry desulfurization and denitrification by reacting with a powdered desulfurizing and denitrificating agent and becomes a treated flue gas; (2) subjecting the treated flue gas to dust removal to generate by-products; and (3) uniformly mixing raw materials that comprise the first by-product, magnesium oxide, fly ash and an additive to give a cementitious material, wherein on the basis of 100 parts by weight of the cementitious material, the first by-product is 20-60 parts by weight, magnesium oxide is 16-33 parts by weight, the fly ash is 15-35 parts by weight, and the additive is 1-15 parts by weight.

The present disclosure discloses a dry desulfurizing and denitrificating agent and its preparation method and applications. The desulfurizing and denitrificating agent is made of raw materials comprising the following components based on 100 parts by weight of the desulfurizing and denitrificating agent: 30-60 parts by weight of TiO.sub.2, 10-30 parts by weight of ZrO.sub.2, 2-10 parts by weight of V.sub.2O.sub.5, 2-10 parts by weight of CoO, 1-8 parts by weight of Co.sub.2O.sub.3, 2-10 parts by weight of Fe.sub.2O.sub.3, 5-15 parts by weight of MnO.sub.2, and 2-10 parts by weight of KMnO.sub.4. The desulfurizing and denitrificating agent of the present disclosure has a good catalytic oxidation performance on sulfur dioxide and nitrogen oxides of flue gas, and a high rate of desulfurization and denitrification.