B01D53/8665

Thermal power generation system and control method for same

A thermal power generation system includes: a boiler; at least one steam turbine; a generator; a condenser; at least one low-pressure feed water; a high-pressure feed water pump; at least one high-pressure feed water heater capable of heating water pumped by the high-pressure feed water pump by utilizing extracted steam; a catalyst device including at least one kind of catalyst capable of promoting reduction reaction of nitrogen oxide and oxidation reaction of metallic mercury, the nitrogen oxide and the metallic mercury both being contained in the exhaust gas; at least one mercuric oxide removing device capable of removing mercuric oxide produced by the oxidation reaction of the metallic mercury from the exhaust gas; and an exhaust gas temperature adjustment device capable of adjusting a temperature of the exhaust gas at the catalyst device, by adjusting heating of the water by the at least one high-pressure feed water heater.

SPENT ACTIVATED CARBON AND INDUSTRIAL BY PRODUCT TREATMENT SYSTEM AND METHOD
20210205866 · 2021-07-08 · ·

Methods for treating an industrial byproduct, such as spent, granular, activated carbon, dredge spoils, or contaminated soils involve integrated steps to clean, concentrate, separate and/or otherwise collect hazardous and/or desired materials from such industrial byproducts. The cleaned, concentrated, separated, or collected materials may involve sufficient quantities to be useful to subsequent processors, raw materials, additives, and the like. Other treatment methods involve retaining the clean material stream at sufficient temperatures for sufficient time to separate and concentrate desired material for recovery therefrom, such as precious metals and rare earth elements.

Catalyst for metal mercury oxidation reactions and nitrogen oxide reduction reactions, and exhaust gas purification method

A catalyst for oxidation reaction of metallic mercury and reduction reaction of nitrogen oxide, comprising an oxide of titanium, an oxide of molybdenum, an oxide of vanadium, an oxide of phosphorus and gypsum is obtained by kneading titanium dioxide, ammonium molybdate, ammonium metavanadate, phosphoric acid, gypsum dihydrate and water using a kneader to obtain a paste, applying the paste to a metal lath substrate, and then drying and calcining the resultant.

Catalyst for treating an exhaust gas, an exhaust system and a method

A catalyst for treating an exhaust gas comprising SO.sub.2, NO.sub.x and elemental mercury in the presence of a nitrogenous reductant comprises a composition containing oxides of: (i) Molybdenum (Mo) and optionally Tungsten (W); and (ii) Vanadium (V); and (iii) Titanium (Ti); and (iv) Phosphorus (P), wherein, with respect to the total metal atoms in the composition, the composition comprises: (i) Mo in an amount of less than 2 at. %, and optionally up to 9 at. % W; (ii) from 2.5 to 12 at. % V; (iii) from 85 to 96 at. % Ti, and wherein the composition comprises (iv) P in an atomic ratio to the sum of atoms of Mo, W and V of from 1:2 to 3:2. The values expressed must total 100%.

MULTI-FUNCTIONAL COMPOSITION OF MATTER FOR REMOVAL OF MERCURY FROM HIGH TEMPERATURE FLUE GAS STREAMS

A multi-functional composition of matter that is useful for injection into a flue gas stream to rapidly and efficiently remove mercury from the flue gas streams, particularly at above average flue stream temperatures of about 340 F. or higher. The multi-functional composition of matter may include a fixed carbon content of at least about 20 wt. %, a mineral content of from about 20 wt. % to about 50 wt. %, a sum of micropore plus mesopore volume of at least about 0.20 cc/g, a micropore volume to mesopore volume ratio of at least about 0.7, and a tapped density of not greater than about 0.575 g/ml. These compositions may be further characterized by number of particles per gram of the composition of matter such that the composition may have at least about 0.8 billion particles per gram, or even as many as 1.5 billion particles per gram. These physical and chemical properties may enhance (1) the oxidation reaction kinetics for the oxidation of mercury species, (2) frequency of contact events, and (3) capture and sequestration of mercury, to achieve efficient mercury capture by the composition even in high temperature flue gas streams.

Methods for the treatment of a flue gas stream using catalytically-enhanced sorbent compositions

A sorbent composition that is useful for injection into a flue gas stream of a coal burning furnace to efficiently remove mercury from the flue gas stream. The sorbent composition may include a sorbent with an associated ancillary catalyst component that is a catalytic metal, a precursor to a catalytic metal, a catalytic metal compound or a precursor to a catalytic metal compound. Alternatively, a catalytic metal or metal compound, or their precursors, may be admixed with the coal feedstock prior to or during combustion in the furnace, or may be independently injected into a flue gas stream. A catalytic promoter may also be used to enhance the performance of the catalytic metal or metal compound.

Catalyst for treating an exhaust gas, an exhaust system and a method

A catalyst for treating an exhaust gas comprising SO.sub.2, NO.sub.x and elemental mercury in the presence of a nitrogenous reductant comprises a composition containing oxides of: (i) Molybdenum (Mo) and/or Tungsten (W); (ii) Vanadium (V); (iii) Titanium (Ti), and (iv) an MFI zeolite, wherein the composition comprises, based on the total weight of the composition: (i) 1 to 6 wt % of MoO.sub.3 and/or 1 to 10 wt % WO.sub.3; and (ii) 0.1 to 3 wt % V.sub.2O.sub.5, and (iii) 48.5 to 94.5 wt % TiO.sub.2; and (iv) 35 to 50 wt % MFI zeolite.

Control of wet scrubber oxidation inhibitor and byproduct recovery

The present disclose is directed to a method for controlling iodine levels in wet scrubbers, and, in particular, recirculating wet scrubbers by removing the iodine from the scrubbing solution, such as by using ion exchange, absorption, adsorption, precipitation, filtration, solvent extraction, ion pair extraction, and an aqueous two-phase extraction.

CATALYST SUPPORT STRUCTURE AND METHOD FOR MANUFACTURING SAME
20200254424 · 2020-08-13 ·

Provided are a mercury oxidation catalyst support structure with which a mercury oxidation reaction can be carried out while inhibiting the oxidation reaction for SO.sub.2 included in exhaust gas and a method for manufacturing the same. This mercury oxidation catalyst structure is characterized by vanadium being unevenly supported on the surface of the support structure. The method for manufacturing the mercury oxidation catalyst structure includes a step of incorporating an inactive support throughout from the inside to the surface of the structure using an inactive support-containing liquid and a step of immersing the structure having been subjected to the step in a liquid containing vanadium or applying the same liquid to the surface of the same structure, followed by drying and calcinating, thereby supporting vanadium on the inactive support present in the surface of the structure.

Multi-functional composition of matter for rapid removal of mercury from a flue gas

A multi-functional composition of matter that is useful for injection into a flue gas stream to rapidly and efficiently remove mercury from the flue gas stream. The multi-functional composition of matter may include a fixed carbon sorbent and minerals, halogens in the form of halide salts, as well as other physical and chemical properties to enhance (1) the oxidation reaction kinetics for the oxidation of mercury species and (2) the mass diffusion kinetics of the mercury species.