A multi-functional composition of matter that is useful for injection into a flue gas stream to rapidly and efficiently remove mercury from the flue gas streams, particularly at above average flue stream temperatures of about 340 F. or higher. The multi-functional composition of matter may include a fixed carbon content of at least about 20 wt. %, a mineral content of from about 20 wt. % to about 50 wt. %, a sum of micropore plus mesopore volume of at least about 0.20 cc/g, a micropore volume to mesopore volume ratio of at least about 0.7, and a tapped density of not greater than about 0.575 g/ml. These compositions may be further characterized by number of particles per gram of the composition of matter such that the composition may have at least about 0.8 billion particles per gram, or even as many as 1.5 billion particles per gram. These physical and chemical properties may enhance (1) the oxidation reaction kinetics for the oxidation of mercury species, (2) frequency of contact events, and (3) capture and sequestration of mercury, to achieve efficient mercury capture by the composition even in high temperature flue gas streams.

The present disclose is directed to a method for controlling iodine levels in wet scrubbers, and, in particular, recirculating wet scrubbers by removing the iodine from the scrubbing solution, such as by using ion exchange, absorption, adsorption, precipitation, filtration, solvent extraction, ion pair extraction, and an aqueous two-phase extraction.

A sorbent composition for removing mercury from flue gas is provided. The sorbent composition contains at least a powdered sorbent, an oxidant and a catalyst. Methods of cleaning flue gas are also provided, which includes injecting the sorbent composition into the flue gas, wherein the powdered sorbent has a fifty percent distribution particle size of from about 25 micrometers to about 75 micrometers.

A sorbent composition that is useful for injection into a flue gas stream of a coal burning furnace to efficiently remove mercury from the flue gas stream. The sorbent composition may include a sorbent with an associated ancillary catalyst component that is a catalytic metal, a precursor to a catalytic metal, a catalytic metal compound or a precursor to a catalytic metal compound. Alternatively, a catalytic metal or metal compound, or their precursors, may be admixed with the coal feedstock prior to or during combustion in the furnace, or may be independently injected into a flue gas stream. A catalytic promoter may also be used to enhance the performance of the catalytic metal or metal compound.

A sorbent composition that is useful for injection into a flue gas stream of a coal burning furnace to efficiently remove mercury from the flue gas stream. The sorbent composition may include a sorbent with an associated ancillary catalyst component that is a catalytic metal, a precursor to a catalytic metal, a catalytic metal compound or a precursor to a catalytic metal compound. Alternatively, a catalytic metal or metal compound, or their precursors, may be admixed with the coal feedstock prior to or during combustion in the furnace, or may be independently injected into a flue gas stream. A catalytic promoter may also be used to enhance the performance of the catalytic metal or metal compound.

The present invention relates to activated carbon sorbents including nitrogen. In various embodiments, the present invention provides an activated carbon sorbent including a halogen- or halide-promoted activated carbon, the activated carbon sorbent particles including nitrogen in a surface layer of the sorbent particles. In various embodiments, the present invention provides a method of reducing the pollutant content in a pollutant-containing gas using the activated carbon sorbent. In various embodiments, the activated carbon sorbent can remove mercury from a mercury-containing gas that includes sulfur(VI) such as SO.sub.3 more efficiently than other sorbents.

A magnetic adsorbent, including an admixture of an adsorbent and a magnetic material. A system for removing mercury from a fluid stream, the system including, a magnetic adsorbent injection unit for injecting an admixture of powdered activated carbon and magnetic material into the fluid stream; and a particulate removal unit. Also included are methods for removing mercury from a fluid stream and methods for producing a magnetic sorbent.

A system and method for cleaning, conditioning, and/or rejuvenating carbon-based sorbents is disclosed where a chemical cleaning process is used to separate contaminants from the sorbent. The contaminants can be disposed of or recycled for industrial uses. The cleaned and/or rejuvenated carbon-based sorbent is recycled back into a reverse venturi shaped fluidized bed apparatus for later use. Spent carbon-based sorbent can be routed for appropriate disposal. The carbon-based sorbents include, but are not limited to, activated carbon sorbent and biochar sorbent. Optionally, the sorbents can be processed through the system prior to exposure to contaminated emissions to enhance and increase the porosity of the outer surface of the sorbents.

An emissions control system including a fluidized bed apparatus containing a reactive sorbent material is disclosed for gaseous and non-gaseous contaminated emissions. The reactive sorbent material may be CZTS, CZTS-Alloy, or a CZTS-Mixture sorbent material. The fluidized bed apparatus is configured with one or more closed loop sorbent recycling subsystems. The sorbent recycling subsystems include the capability to separate sorbents from each other, separate contaminates from sorbents for disposal and/or recycling, clean and/or rejuvenate sorbents for return to the fluidized bed apparatus, dispose of spent and exhausted sorbents, and replace the spent and exhausted sorbents with new sorbent to maintain consistent sorbent function in the fluidized bed apparatus. Monitoring sensors provide information useful in a method for establishing and maintaining consistent process parameter controls.

A flow-through solid catalyst formed by coating a zeolite material on a metal or ceramic solid substrate. In some embodiments, the solid substrate is formed as flat plates, corrugated plates, or honeycomb blocks.