A scrubbing solution is provided having an absorbent for carbon dioxide based on amines, or ethanolamines, or amino acid salts, or potash, or a combination thereof, and an additive activating the absorption rate, wherein the activating additive is a germanium dioxide. A corresponding method for accelerating the absorption of carbon dioxide is also provided, wherein a carbon dioxide-containing gas is contacted with such a scrubbing solution, wherein the carbon dioxide is physically dissolved in the scrubbing solution and is chemically absorbed with the participation of the absorbent, and wherein the germanium dioxide acts catalytically for at least one reaction step of the chemical absorption of the carbon dioxide.

Disclosed herein is a system for recovering flash gas from an oil storage tank. In one example of the invention, the system may include a flexible storage tank that receives the flash gas and temporarily stores the flash gas; a compressor having an input receiving the flash gas from the flexible storage tank, the compressor compressing the flash gas to form compressed gas; and an oxygen reduction subsystem receiving the compressed gas, the oxygen reduction subsystem reducing an amount of oxygen from the compressed gas. In this manner, the resulting compressed oxygen-reduced gas that has been recovered can be injected into a sales gas line for use, under certain conditions.

The present disclosure relates to the technical field of industrial waste gas purification, in particular to a core-shell structured catalyst, a preparation method and use thereof. The present disclosure provides a core-shell structured catalyst including a metal oxide-molecular sieve as a core and porous silica (SiO.sub.2) as a shell, where the metal oxide-molecular sieve includes a molecular sieve and a metal oxide loaded on the molecular sieve, the metal oxide includes an oxide of a first metal and an oxide of a second metal, the first metal is Fe, Cu, Ti, Ni or Mn, and the second metal is Ce or La. The core-shell structured catalyst of the present disclosure can enable effective removal of HCN and AsH.sub.3 at the same time with a stable effect, and no secondary pollution.

An electrocatalytic process for carbon dioxide conversion includes combining a Catalytically Active Element and a Helper Polymer in the presence of carbon dioxide, allowing a reaction to proceed to produce a reaction product, and applying electrical energy to said reaction to achieve electrochemical conversion of said carbon dioxide reactant to said reaction product. The Catalytically Active Element can be a metal in the form of supported or unsupported particles or flakes with an average size between 0.6 nm and 100 nm. The reaction products comprise at least one of CO, HCO.sup.−, H.sub.2CO, (HCO.sub.2).sup.−, H.sub.2CO.sub.2, CH.sub.3OH, CH.sub.4, C.sub.2H.sub.4, CH.sub.3CH.sub.2OH, CH.sub.3COO.sup.−, CH.sub.3COOH, C.sub.2H.sub.6, (COOH).sub.2, (COO.sup.−).sub.2, and CF.sub.3COOH.

A device for decreasing hydrogen concentration of a fuel cell system is installed in an exhaust system of a fuel cell system so as to discharge exhaust gas including hydrogen and air from fuel cells to the atmosphere through an exhaust line. The device includes: a catalyst diluter that includes catalysts for diluting hydrogen in the exhaust gas by generating a catalytic reaction, the catalyst diluter being connected to the exhaust line; and an air diluter that is disposed outside the catalyst diluter and guides external air to a gas exit side of the catalyst diluter, in which the catalyst diluter may include a valve unit that opens and closes an external air channel of the air diluter in accordance with flow pressure of the exhaust gas.

The present invention provides a method including: a gas absorption step of bringing exhaust gas into contact with an aqueous solution containing alkaline carbonate, so that carbon dioxide gas in the exhaust gas is allowed to react therewith, thereby obtaining an aqueous solution containing alkaline bicarbonate; a gas recovery step of recovering a gas containing nitrogen gas and oxygen gas obtained as a result of the gas absorption step; a decomposition step of decomposing at least a part of the alkaline bicarbonate obtained in the gas absorption step into the alkaline carbonate and the carbon dioxide gas; a circulation step of circulating at least a part of the alkaline carbonate obtained in the decomposition step to the gas absorption step; and a carbon dioxide gas recovery step of bringing a gas containing the carbon dioxide gas obtained as a result of the decomposition step into contact with an aqueous solution, thereby recovering the carbon dioxide gas obtained in the decomposition step.

The invention describes a process for the photocatalytic reduction of carbon dioxide carried out in the liquid phase and/or in the gas phase under irradiation employing a photocatalyst of microporous crystalline metal sulfide type, said process being carried out by bringing a charge containing the CO.sub.2 and at least one sacrificial compound into contact with said photocatalyst, then by irradiating the photocatalyst by at least one irradiation source producing at least one wavelength lower than the bandgap width of said photocatalyst, so as to reduce the CO.sub.2 and to oxidize the sacrificial compound, so as to produce an effluent containing, at least in part, C.sub.1 or more carbon-based molecules other than CO.sub.2.

A transformational energy efficient technology using ionic liquid (IL) to couple with monoethanolamine (MEA) for catalytic CO.sub.2 capture is disclosed. [EMmim.sup.+][NTF.sub.2.sup.−] based catalysts are rationally synthesized and used for CO.sub.2 capture with MEA. A catalytic CO.sub.2 capture mechanism is disclosed according to experimental and computational studies on the [EMmim.sup.+][NTF.sub.2.sup.−] for the reversible CO.sub.2 sorption and desorption.

In accordance with the present invention, there are provided simplified systems and methods for catalytically deactivating, removing, or reducing the levels of reactive component(s) from the vapor phase of fuel storage tanks. The simple apparatus described herein can be utilized to replace complex OBIGGS systems on the market. Simply stated, in one embodiment of the invention, the vapor phase from the fuel tank is passed over a catalytic bed operated at appropriate temperatures to allow the reaction between free oxygen and the fuel vapor by oxidation of the fuel vapor, thus deactivating reactive component(s) in the gas phase.

A system and method of pre-purification of a feed gas stream is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the hydrogen, carbon monoxide, water, and carbon dioxide impurities from a feed air stream and is particularly suitable for use in a high purity or ultra-high purity nitrogen plant. The pre-purification systems and methods preferably employ two or more separate layers of hopcalite catalyst with the successive layers of the hopcalite separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layers. Alternatively, the pre-purification systems and methods employ a hopcalite catalyst layer and a noble metal catalyst layer separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layer.