An integrated system and method for conversion of carbon oxides to carbon containing products are disclosed. Pre-purification of a carbon oxide gas by electrodialysis, and subsequent electrochemical reduction of the purified gas with a carbon oxide electrolyzer equipped with a polymer electrolyte membrane yields carbon containing products.

A liquid desiccant regeneration system comprises an electrodialysis apparatus having first and second reservoirs, wherein concentration of an input solution in the first reservoir increases to a threshold concentration and concentration of the input solution decreases in the second reservoir during an operation mode. A first redox-active electrolyte chamber comprises a first electrode and a first solution of a redox-active electrolyte material and has a reversible redox reaction with the first electrolyte material to drive an ion into the first reservoir. A second redox-active electrolyte chamber comprises a second electrode and a second solution of a redox-active electrolyte material and has a reversible redox reaction with the second electrolyte material to accept an ion from the second reservoir. A first type of membrane is disposed between the first and second reservoirs, and a second type of membrane, different from the first, is disposed between the respective electrode chambers and reservoirs.

A system comprises an electrodialysis apparatus, which includes first and second reservoirs, wherein a salt concentration in the first reservoir reduces below a threshold concentration, and salt concentration in the second reservoir increases during an operation mode. A first electrode comprises a first solution of a first redox-active electrolyte material, and a second electrode comprises a second solution of a second redox-active electrolyte material. In a first reversible redox reaction between the first electrode and first electrolyte material at least one ion is accepted from the first reservoir, and in a second reversible redox reaction between the second electrode and second electrolyte material at least one ion is driven into the second reservoir. A first type of ion exchange membrane is disposed between the first and second reservoirs, and a second type of ion exchange membrane, different from the first type, is disposed between the respective electrodes and reservoirs.

A system for recovering organic acid products from a multicomponent feed solution includes: a first electrode; a second electrode positioned in opposition to the first electrode; a cation exchange membrane and an anion exchange membrane disposed between the first and second electrodes, thereby defining a feed channel extending between the cation and anion exchange membranes for delivery of a multicomponent feed solution including an organic acid and an inorganic salt; a functionalized membrane disposed between the cation or anion exchange membrane and the first or second electrode, thereby defining an accumulating channel extending between the cation or anion exchange membrane and the functionalized membrane for collecting charged organic species separated from the multicomponent feed solution; and a redox channel containing the first and second electrodes and being separated from the feed and accumulating channels by the cation or anion exchange membrane and the functionalized membrane.

A device for the electrodeionization of a sample liquid. The device has an anode chamber having two openings and an anode, a cathode chamber having two openings and a cathode, and a treatment chamber, that is arranged between the anode chamber and the cathode chamber and has two openings and ion exchanger. The anode chamber and the cathode chamber are separated from the treatment chamber in each case by a permselective membrane and an energy source is operatively connected to the anode and the cathode. In addition, a method for the electrodeionization of a sample liquid is provided.

Membrane cell stack arrangement comprising a housing, a stack of membranes defining flow compartments and a fluid manifold system, wherein the direction of flow through the flow compartments is different to the direction of flow through entry and exit openings and the width of the entry and exit openings are each larger than 45% of the width of the flow compartment.

Between two juxtaposed similar ion exchange membranes (AEMs or CEMs), an ion depletion zone and ion enrichment zone are generated under an electric field. As cations are selectively transferred through the CEMs, for example, anions are relocated in order to achieve electro-neutrality, resulting in the concentration drop (increase) in ion depletion (enrichment) zone. The use of a sacrificial metal anode allows electrocoagulation (EC) concurrently with ICP thereby permitting concentration of both ionic and non-ionic impurities to occur at the same time within the same cell or device.

An electrodialysis module includes at least one base unit. The base unit includes a working tank, a first ion-exchange membrane, a second ion-exchange membrane, at least one first electrode, and at least two second electrodes. The first ion-exchange membrane and the second ion-exchange membrane are located in the working tank. The first ion-exchange membrane and the second ion-exchange membrane together divide the working tank into two electrode compartments and a desalination compartment therebetween. The at least one first electrode is disposed in the desalination compartment. The at least two second electrodes are disposed in each of the electrode compartments, respectively, in which the at least two second electrodes and the at least one first electrode have different polarities.

Processes, systems, and techniques for multivalent ion desalination of a feed water use an apparatus that has a cathode, an anode, and an electrodialysis cell located between the cathode and anode. The cell has a product chamber through which the feed water flows, a multivalent cation concentrating chamber on a cathodic side of the product chamber through which the concentrated multivalent cation solution flows, and a multivalent anion concentrating chamber on an anodic side of the product chamber through which the concentrated multivalent anion solution flows. The product chamber and the multivalent cation concentrating chamber are each bounded by and share a cation exchange membrane, and the product chamber and the multivalent anion concentrating chamber are each bounded by and share an anion exchange membrane. A monovalent ion species is added to at least one of the concentrated multivalent cation solution and the concentrated multivalent anion solution.

Between two juxtaposed similar ion exchange membranes (AEMs or CEMs), an ion depletion zone and ion enrichment zone are generated under an electric field. As cations are selectively transferred through the CEMs, for example, anions are relocated in order to achieve electro-neutrality, resulting in the concentration drop (increase) in ion depletion (enrichment) zone. The use of a sacrificial metal anode allows electrocoagulation (EC) concurrently with ICP thereby permitting concentration of both ionic and non-ionic impurities to occur at the same time within the same cell or device.