Patent classifications
B01D69/14111
COMPOSITE PALLADIUM-BASED ALLOY MATERIAL, PREPARATION METHOD THEREFOR, AND USE THEREOF
A composite palladium-based alloy material, a preparation method therefor, and a use thereof are provided. The composite palladium-based alloy material includes Pd and a group IB metal. In an XRD graph of the composite palladium-based alloy material, the full width at half maximum of at least one characteristic peak for 2 within the range of 5-90 is less than or equal to 0.1745. The composite palladium-based alloy material has a lower activation energy for hydrogen permeation, a higher hydrogen permeation efficiency, higher stability and carbon deposition resistance, and has a longer service life as a composite membrane (especially in hydrogen production via steam reforming).
COVALENT ORGANIC FRAMEWORKS ON HOLLOW FIBRE SUBSTRATES WITH JANUS-LIKE CHARACTERISTICS FOR SOLVENT SEPARATION
The precise molecular sieving architectures with Janus-like characteristics via an interpenetrating polymer network combining the hydrophilic cPI polymer and hydrophobic microporous covalent organic framework (COF) exhibit super-high permeances for both polar and nonpolar solvents. A unidirectional diffusion and convection process significantly speeds up chemically stable COFs with uniform and tailorable channels growing on polymeric hollow fibre that can efficiently separate organic solvents under ultrafiltration conditions.
GRAPHENE OXIDE COMPOSITE MEMBRANES
A system involves interleaving high aspect ratio, rod-like aldehyde-modified cellulose nanomaterials (ACN) between graphene oxide (GO) sheets and utilizing crosslinkers to create a dense, crosslinked network that is highly permeable and selective to a molecule of interest, especially water and water vapor, and does not delaminate in water. This system, especially when combined with oxidative surface treatment of a membrane support substrate, leads to improved adhesion of the membrane on the substrate.
NECKLACE-SHAPED NANOFIBER HYBRID MEMBRANE FOR SIMULTANEOUS REMOVAL OF PARTICULATE MATTER AND SULFIDES AND METHOD FOR PREPARING THE SAME
A necklace-type nanofiber hybrid membrane is disclosed. ZIF-67 (Zeolite imidazolate framework-67), a type of metal-organic framework (MOF), is formed surrounding surface of the nanofibers to possess a necklace-type structure. The combination of ZIF-67 and nanofibers enables simultaneous removal of fine dust and sulfides while exhibiting excellent stability.
Preparation method of Ti.SUB.3.C.SUB.2.T.SUB.X .MXene quantum dot (MQD)-modified polyamide (PA) reverse-osmosis (RO) membrane
The present disclosure belongs to the technical field of membrane separation, and discloses a preparation method of a Ti.sub.3C.sub.2T.sub.x MXene quantum dot (MQD)-modified polyamide (PA) reverse osmosis (RO) membrane. The preparation method includes the following steps: subjecting a Ti.sub.3C.sub.2T.sub.x MXene material to liquid nitrogen intercalation and interlayer expansion to obtain a Ti.sub.3C.sub.2T.sub.x MQD nanomaterial; preparing an aqueous phase solution with the Ti.sub.3C.sub.2T.sub.x MQD nanomaterial and an organic phase solution; soaking an ultrafiltration (UF) base membrane in the aqueous phase solution, and removing the aqueous phase solution on a surface of the UF base membrane through blow-drying; soaking the second UF base membrane in the organic phase solution to allow interfacial polymerization to form an active layer; and allowing a composite membrane obtained after the interfacial polymerization to stand, followed by a heat treatment to further promote the interfacial polymerization.